Open Access. Powered by Scholars. Published by Universities.®

Engineering Commons

Open Access. Powered by Scholars. Published by Universities.®

PDF

University of South Florida

USF Tampa Graduate Theses and Dissertations

2018

MoS2

Articles 1 - 2 of 2

Full-Text Articles in Engineering

Synthesis And Characterization Of Alpha-Hematite Nanomaterials For Water-Splitting Applications, Hussein Alrobei Jul 2018

Synthesis And Characterization Of Alpha-Hematite Nanomaterials For Water-Splitting Applications, Hussein Alrobei

USF Tampa Graduate Theses and Dissertations

The recent momentum in energy research has simplified converting solar to electrical energy through photoelectrochemical (PEC) cells. There are numerous benefits to these PEC cells, such as the inexpensive fabrication of thin film, reduction in absorption loss (due to transparent electrolyte), and a substantial increase in the energy conversion efficiency. Alpha-hematite ([U+F061]-Fe2O3) has received considerable attention as a photoanode for water-splitting applications in photoelectrochemical (PEC) devices. The alpha-hematite ([U+F061]-Fe2O3) nanomaterial is attractive due to its bandgap of 2.1eV allowing it to absorb visible light. Other benefits of [U+F061]-Fe2O3 include low cost, chemical stability and availability in nature, and excellent photoelectrochemical …


Photocatalytic Carbon Dioxide Conversion To Fuel For Earth And Mars, Anne J. Meier Jul 2018

Photocatalytic Carbon Dioxide Conversion To Fuel For Earth And Mars, Anne J. Meier

USF Tampa Graduate Theses and Dissertations

As far as we know, we only have one planet to live on, with a delicate atmospheric system providing us safety and life. Global CO2 emissions continue to plague the environment of Earth, primarily due to the processing of fossil fuels, deforestation, and industrialization. There are several avenues of pursuing CO2 reutilization, each having their own benefits and limitations. Direct and indirect thermochemical approaches of CO2 conversion boast of efficient CO2 conversion rates but have limitations associated with the use of renewable hydrogen and high temperatures of operation. The work in this dissertation investigates low temperature photocatalytic CO2 conversion, a …