Engineering Commons^™

Nanomechanical And Scaling Behavior Of Nanoporous Gold, Nicolas J. Briot

Theses and Dissertations--Chemical and Materials Engineering

Nanoporous metals have recently been drawn significant interest in various fields of research. Their high surface-to-volume ratio present a strong potential for applications in sensing, catalysis, micro-electromechanical systems (MEMS) and even in the medical field. However, the mechanical properties of nanoporous metals have not yet been well determined, as conducting mechanical tests was found to be challenging. Scaling relations linking the mechanical properties of porous materials to those of their dense counterparts are successfully and widely used for many porous metals. However, their applicability to nanoporous metals have recently been questioned, as estimations from the classic scaling relations were found …

Microindentation Of Bi57in26sn17 Lead-Free Alloy, Ruiting Zhao

Theses and Dissertations--Chemical and Materials Engineering

There is great need to understand the mechanical properties of lead-free alloys—an alternative of lead-based alloys—to address the environmental problems associated with the use of lead-based materials in microelectronics. In this work, the microstructures of Bi57In26Sn17 lead-free alloy were examined using Optical Microscopy and Energy Dispersive X-ray Spectroscopy analysis. The micro-indentation technique was used to study the mechanical properties of Bi57In26Sn17 lead-free alloy. The experimental results of the hardness and contact modulus were presented and discussed. Local creep during the indentation was observed from the load-displacement curves. The Vickers hardness (HV) increases with the decrease of the indentation depth, suggesting …

Commercialization Of A Small, Lightweight, Low-Cost Seismic Borehole Receiver, Rachel Adams

Theses and Dissertations--Civil Engineering

Herein, conceptualization of a recently patented seismic borehole receiver and its components is developed for commercialization. The device is significantly cheaper, lighter, and smaller than existing technologies on the market. Additionally, it has the potential to achieve better seismic readings than its competitors via patented sensor-to-borehole coupling mechanism. It is the hope that the commercialization of this device will not only provide a more affordable alternative to engineers and geophysicists in the existing market, but the significant cost difference may open new seismic measurement opportunities in the developing world. Its compact size and light weight will increase mobility, allowing investigators …

Life-Cycle Cost Analysis Of Reinforced Concrete Bridges Rehabilitated With Cfrp, Jeffrey L. Smith

Theses and Dissertations--Civil Engineering

The deterioration of highway bridges and structures and the cost of repairing, rehabilitating, or replacing deteriorated structures is a major issue for bridge owners. An aging infrastructure as well as the need to upgrade structural capacity for heavier trucks adds to problem. Life-cycle cost analysis (LCCA) is a useful tool for determining when the deployment of fiber-reinforced polymer (FRP) composite components is an economically viable alternative for rehabilitating deteriorated concrete bridges.

The use of LCCA in bridge design and rehabilitation has been limited. The use of LCCA for bridges on a project level basis has often been limited to the …

A Network Path Advising Service, Xiongqi Wu

Theses and Dissertations--Computer Science

A common feature of emerging future Internet architectures is the ability for applications to select the path, or paths, their packets take between a source and destination. Unlike the current Internet architecture where routing protocols find a single (best) path between a source and destination, future Internet routing protocols will present applications with a set of paths and allow them to select the most appropriate path. Although this enables applications to be actively involved in the selection of the paths their packets travel, the huge number of potential paths and the need to know the current network conditions of each …

Alternate Models For Natural Gas Transportation System Performance Optimization, Gnana Shekaran Arumugam

Theses and Dissertations--Manufacturing Systems Engineering

The Natural Gas market in the U.S is growing rapidly with evidence that the nation has enough shale reserves to power the country for the next century. To ensure continued economic benefits through the use of this environmentally desired energy source, it becomes important to optimize the transportation network system design. Transportation through pipelines is one of the most common methods used to distribute Natural Gas from source to destination. This transportation system, consisting of pipelines, compressors and other supporting equipment, must be optimized, considering all relevant parameters to minimize cost and increase profit. The research presented here improves on …

Layered, Flexible Drug Delivery Films For The Prevention Of Fibrotic Scar Tissue Formation, Cheryl L. Rabek

Theses and Dissertations--Biomedical Engineering

Open wounds account for about 50% of military injuries and 10% of non‐fatal traffic injuries. Scar tissue formation in these wounds may be reduced or prevented if treated with a combination of molecules whose release is tuned to the healing phases. The goal of this research was to develop flexible, layered drug delivery films for sequential, localized release of anti‐inflammatory, anti‐oxidant, and anti‐fibrotic molecules to soft tissue.

Films were composed of cellulose acetate phthalate (CAP) and Pluronic F‐127 (Pluronic). To impart flexibility, plasticizers, triethyl citrate (TEC) or tributyl citrate (TBC), were added. Mechanical analysis was performed on films as prepared …

Diffuse Optical Measurements Of Head And Neck Tumor Hemodynamics For Early Prediction Of Chemo-Radiation Therapy Outcomes, Lixin Dong

Theses and Dissertations--Biomedical Engineering

Chemo-radiation therapy is a principal modality for the treatment of head and neck cancers, and its efficacy depends on the interaction of tumor oxygen with free radicals. In this study, we adopted a novel hybrid diffuse optical instrument combining a commercial frequency-domain tissue oximeter (Imagent) and a custom-made diffuse correlation spectroscopy (DCS) flowmeter, which allowed for simultaneous measurements of tumor blood flow and blood oxygenation. Using this hybrid instrument we continually measured tumor hemodynamic responses to chemo-radiation therapy over the treatment period of 7 weeks. We also explored monitoring dynamic tumor hemodynamic changes during radiation delivery. Blood flow data analysis …

Compensation Methods For Demand Response, Zhaofeng Wang

Theses and Dissertations--Electrical and Computer Engineering

Recently, more and more disputations about how demand response should be compensated have arisen. Moreover, the court is about to rehear the Order 745. It probably will have significant impact on the whole working system used to be built for demand response before. Nowadays, some power companies and utilities think that they will endure profits leakage while demand response resources still are compensated.

In this research, knowledge of demand response, local marginal price, Order 745 and other related concept will be explained in detail in case of misunderstanding. Associated with all these knowledge, a possible compensation method will be proposed. …

The Effect Of Cholesterol On The Osteoblast Responsiveness To Hydrodynamic Pressure Stimulation, Kristen Lough

Theses and Dissertations--Biomedical Engineering

Hypercholesterolemia is a risk factor for osteoporosis but the underlying mechanism is unknown. Previous evidence suggests that osteoporosis results from an impaired regulation of osteoblasts by fluid pressure fluctuations in the bone matrix. Recently, our laboratory showed that enhanced cholesterol in the cell membrane, due to hypercholesterolemia, alters leukocyte mechanosensitivity. We predict a similar link between osteoblasts and hypercholesterolemia leading to osteoporosis. Specifically, we hypothesize that extracellular cholesterol modifies the osteoblast sensitivity to pressure. MC3T3-E1 cells were exposed to hydrodynamic pressures regimes (mean=40mmHg, amplitude=0-20mmHg, frequency=1Hz) for 1-12 hours. To assess the impact of membrane cholesterol enrichment, cells were pre-treated with …

Body Armor Induced Changes In The Trunk Mechancial And Neuromuscular Behavior, Rebecca Leigh Tromp

Theses and Dissertations--Biomedical Engineering

While military body armor is used among warfighters for protection on and off the battlefield, it has been suggested to impede performance and act as a risk factor for the development of musculoskeletal disorders, especially low back pain. Apart from personal suffering, low back pain in soldiers is a great economic burden on the US economy. The objective of this study was to quantify the changes in trunk mechanical and neuromuscular behavior following prolonged exposure to body armor compared to exposure without. A crossover study design was used where 12 sex-balanced participants completed a series of tests before and after …

Misfit: Mining Software Fault Information And Types, Billy R. Kidwell

Theses and Dissertations--Computer Science

As software becomes more important to society, the number, age, and complexity of systems grow. Software organizations require continuous process improvement to maintain the reliability, security, and quality of these software systems. Software organizations can utilize data from manual fault classification to meet their process improvement needs, but organizations lack the expertise or resources to implement them correctly.

This dissertation addresses the need for the automation of software fault classification. Validation results show that automated fault classification, as implemented in the MiSFIT tool, can group faults of similar nature. The resulting classifications result in good agreement for common software faults …

Pilot Scale Demonstration And Evaluation Of Innovative Non-Deslimed Non-Classified Gravity-Fed Hm Cyclone, Yumo Zhang

Theses and Dissertations--Mining Engineering

Coal preparation plants are required in some cases to produce a high-grade product using a low specific gravity cut-point. For these situations, a second higher gravity separation would be desirable to generate a mid-grade product that can be utilized for electricity generation thereby maximizing coal recovery. A study was conducted to evaluate the potential of achieving efficient separations at two different density cut-points in a single stage using a three-product dense medium cyclone. Variations in density cut-point and process efficiency values were quantified as a function of the feed medium density, feed medium-to-coal ratio, and feed pressure using a three-level …

Collagen Crosslinking Reagent Utilized To Modify The Mechanical Properties Of The Soft Palate In Equine Snoring And Apnea Applications, Stephanie L. Hunt

Theses and Dissertations--Biomedical Engineering

Snoring is a sleep disruption that can lead to obstructive sleep apnea (OSA), which interrupts breathing by obstructing the airway. Injecting a protein crosslinker, such as genipin, into the soft palate could decrease the severity of snoring and OSA by stiffening the soft palate. Equine soft palates modeled human palates due to a high incidence of awake snoring and apnea.

The pilot in vivo study treated six horses with two 100 mM injections of the buffered genipin reagent. The efficacy phase horses underwent respiratory audio recordings to document snoring changes using Matlab and ImageJ in the time and frequency domains. …

Determination Of Explosive Energy Partition Values In Rock Blasting Through Small-Scale Testing, Joshua Calnan

Theses and Dissertations--Mining Engineering

Blasting is a critical part of most mining operations. The primary function of blasting is to fragment and move rock. For decades, attempts have been made at increasing the efficiency of blasting to reduce costs and increase production. Most of these attempts involve trial and error techniques that focus on changing a single output. These techniques are costly and time consuming and it has been shown that as one output is optimized other outputs move away from their optimum level. To truly optimize a blasting program, the transfer of explosive energy into individual components must be quantified. Explosive energy is …

Mechanical Behavior Of Grouted Sands, Ryan C. Ortiz

Theses and Dissertations--Civil Engineering

Grouting techniques have been in used for many years, but several new grout materials have surfaced in recent decades that have re-defined the boundaries of the limitations of grouting programs. Typically these applications are used for seepage control in earthen impoundments, but strength of these earthen impoundments should be considered where there is potential for movement in the grouted soil mass. This study investigated initial conditions that could affect grout application effectiveness. The initial conditions in question were soil grain size and in situ moisture content. Two grouts were used, ultrafine and acrylate, and variations in pure grout properties were …

Prediction Of Strength And Shear Modulus Of Compacted Clays Within An Unsaturated Critical State Framework, Corrie Walton-Macaulay

Theses and Dissertations--Civil Engineering

The objective of this research study is to determine whether the soil stiffness, from which the small-strain shear modulus is determined, can be used to predict the shearing resistance of compacted clay soil, which are invariably under conditions of partial saturation. The research program developed for this objective included three major soil testing programs of matric suction, shear modulus, and strength.

A method to estimate matric suction of field compacted clay soil was presented and it is based on the quantified effect of change in initial void ratio on the soil water characteristic behaviors. With the use of a non-nuclear …

The Applicability Of Western Management In The Middle East, Zamaan Al-Shabbani

Theses and Dissertations--Civil Engineering

The Middle Eastern construction industry is still suffering from cost overruns, delays, and disputes. Inefficient management practices and lack of management are frequently reported reasons for such problems. Researchers attribute such problems to the traditional management practices that are utilized in the Middle East. However, International companies who practice their best management strategies are still suffering from the same problems. These issues become more significant in joint ventures when two different management styles work together. Therefore, it becomes crucial to understand the characteristics of Middle Eastern construction environment in terms of the management practices and regulations that are used and …

Sediment Organic Carbon Fate And Transport In A Fluviokarst Watershed In The Bluegrass Region, Admin Husic

Theses and Dissertations--Civil Engineering

Mature karst topography is well recognized within the hydrology and geology communities to include subterranean fluid pathways that act as turbulent conduits conveying fluid from surface stream sinks called swallets to sources called springs. However, we find that little knowledge has been reported with regards to the transport and fate of terrestrially-derived sediment organic carbon (SOC) within karst watersheds. This study investigated the hypothesis that karst pathways could act as biologically active conveyors of SOC that temporarily store sediment, turnover carbon at higher rates than otherwise considered, and recharge depleted SOC back to the surface stream within the fluvial system. …

Design Of A Scalable Path Service For The Internet, Mehmet O. Ascigil

Theses and Dissertations--Computer Science

Despite the world-changing success of the Internet, shortcomings in its routing and forwarding system have become increasingly apparent. One symptom is an escalating tension between users and providers over the control of routing and forwarding of packets: providers understandably want to control use of their infrastructure, and users understandably want paths with sufficient quality-of-service (QoS) to improve the performance of their applications. As a result, users resort to various “hacks” such as sending traffic through intermediate end-systems, and the providers fight back with mechanisms to inspect and block such traffic.

To enable users and providers to jointly control routing and …

Noncontact Diffuse Correlation Tomography Of Breast Tumor, Lian He

Theses and Dissertations--Biomedical Engineering

Since aggressive cancers are frequently hypermetabolic with angiogenic vessels, quantification of blood flow (BF) can be vital for cancer diagnosis. Our laboratory has developed a noncontact diffuse correlation tomography (ncDCT) system for 3-D imaging of BF distribution in deep tissues (up to centimeters). The ncDCT system employs two sets of optical lenses to project source and detector fibers respectively onto the tissue surface, and applies finite element framework to model light transportation in complex tissue geometries. This thesis reports our first step to adapt the ncDCT system for 3-D imaging of BF contrasts in human breast tumors. A commercial 3-D …

Long Term Blood Oxygenation Membranes, Joseph V. Alexander

Theses and Dissertations--Biomedical Engineering

Hollow fiber membranes are widely used in blood oxygenators to remove carbon dioxide and add oxygen during cardiopulmonary bypass operations. These devices are now widely used off-label by physicians to perform extracorporeal blood oxygenation for patients with lung failure. Unfortunately, the hollow fiber membranes used in these devices fail prematurely due to blood plasma leakage and gas emboli formation.

This project formed ultrathin (~100nm) polymer coatings on polymer hollow fiber membranes. The coatings were intended to “block” existing pores on the exterior surfaces while permitting high gas fluxes. This coating is synthesized using surface imitated control radical polymerization.

The coating …

Experimental-Computational Analysis Of Vigilance Dynamics For Applications In Sleep And Epilepsy, Farid Yaghouby

Theses and Dissertations--Biomedical Engineering

Epilepsy is a neurological disorder characterized by recurrent seizures. Sleep problems can cooccur with epilepsy, and adversely affect seizure diagnosis and treatment. In fact, the relationship between sleep and seizures in individuals with epilepsy is a complex one. Seizures disturb sleep and sleep deprivation aggravates seizures. Antiepileptic drugs may also impair sleep quality at the cost of controlling seizures. In general, particular vigilance states may inhibit or facilitate seizure generation, and changes in vigilance state can affect the predictability of seizures. A clear understanding of sleep-seizure interactions will therefore benefit epilepsy care providers and improve quality of life in patients. …

Nanoindentation Of A Zinc Metal Soap Mixture For Use In A Laser Printer, George A. Nimick

Theses and Dissertations--Chemical and Materials Engineering

At the start of this project, the possible choices of metal soaps had already been narrowed to include some of the zinc soaps used in this project. These zinc soaps are mixtures of zinc stearate and zinc palmitate of varying ratios purchased from a supplier. Zinc soap was chosen as result of its common use in various industries as a lubricant and mold release, which implied potential benefits in an electrophotographic printing system. These potential benefits include, but are not limited to, a more efficient transfer from a photoconductive drum and protection of the drum from mechanical and chemical degradation. …

Engineered Surface Properties Of Porous Tungsten From Cryogenic Machining, Julius M. Schoop

Theses and Dissertations--Chemical and Materials Engineering

Porous tungsten is used to manufacture dispenser cathodes due to it refractory properties. Surface porosity is critical to functional performance of dispenser cathodes because it allows for an impregnated ceramic compound to migrate to the emitting surface, lowering its work function. Likewise, surface roughness is important because it is necessary to ensure uniform wetting of the molten impregnate during high temperature service. Current industry practice to achieve surface roughness and surface porosity requirements involves the use of a plastic infiltrant during machining. After machining, the infiltrant is baked and the cathode pellet is impregnated. In this context, cryogenic machining is …

Fundamental Studies Of Surfactant Templated Metal Oxide Materials Synthesis And Transformation For Adsorption And Energy Applications, Saikat Das

Theses and Dissertations--Chemical and Materials Engineering

This work addresses fundamental aspects of designing templates and curing conditions for the synthesis of mesoporous metal oxide thin films. The first section addresses selection of cationic-carbohydrate surfactant mixtures to synthesize templated silica thin films for selective adsorption of simple carbohydrates based on molecular imprinting. Nuclear magnetic resonance and fluorescence spectroscopy results suggest a novel structure for mixtures of alkyl glucopyranosides or xylopyranosides with cationic (trimethylammonium) surfactants. Despite thermodynamically favorable mixing, the carbohydrate headgroups in the mixed micelle adopt an inverted configuration with their headgroups in the micelle core, and therefore are inaccessible for molecular imprinting. This orientation occurs even …

Biomimetic Oral Mucin From Polymer Micelle Networks, Sundar Prasanth Authimoolam

Theses and Dissertations--Chemical and Materials Engineering

Mucin networks are formed by the complexation of bottlebrush-like mucin glycoprotein with other small molecule glycoproteins. These glycoproteins create nanoscale strands that then arrange into a nanoporous mesh. These networks play an important role in ensuring surface hydration, lubricity and barrier protection. In order to understand the functional behavior in mucin networks, it is important to decouple their chemical and physical effects responsible for generating the fundamental property-function relationship. To achieve this goal, we propose to develop a synthetic biomimetic mucin using a layer-by-layer (LBL) deposition approach. In this work, a hierarchical 3-dimensional structures resembling natural mucin networks was generated …

Evaluation Of The Performance Of Flocculation To Enhance Sediment Trap Efficiency, Derek Scott

Theses and Dissertations--Biosystems and Agricultural Engineering

Weathered sandstone materials have seen increased use in reclamation due to the wide-spread adoption of the Forest Reclamation Approach (FRA) in Appalachia. Runoff from these newly FRA reclaimed sites has the potential to adversely impact aquatic environments without fine sediment retention. To reduce the size and capital investment of settling ponds, flocculant utilization was investigated. Preliminary jar tests were conducted using composite weathered mine spoil samples acquired from a surface coal mine in eastern Kentucky. Four flocculants from the Magnafloc family of products were investigated during the initial screening-level testing. Experiments were conducted at three initial sediment concentrations (500 mg/L, …

Total Cost Optimization For Contour Blasting In The Appalachia Region, Brett Christopher Jackson

Theses and Dissertations--Mining Engineering

This thesis recounts the study of contour blasting practices in the Appalachia coal region. Contour blasting practices vary widely and problems are often encountered. Several different sites were visited and contour blasting practices at each were studied. Based on the information gathered, a comprehensive plan was developed for blasting operations to follow and then was tested and compared to an example of blasting practices without use of the plan. The blasting practices were compared by examining monthly production rates as well as a time study to measure the efficiency a contour blast could be loaded and hauled away and a …

Analysis Of The Armps Database Using Flac3d; A Pillar Stability Comparison For Room And Pillar Coal Mines During Development, Ali Soltani

Theses and Dissertations--Mining Engineering

Designing a safe and economical mining activity is the main goal of every mine design engineer. With the rise of computer modeling in mine design there is a need for a standardized method to use geologic characterization of rocks in engineering design. In this research, first a review of empirical methods will be conducted and after that a step-by-step method is presented to adequately use FLAC3D, for development pillars, in room and pillar mine in development stage. ARMPS database is used to evaluate the FLAC3D model results. ARMPS database consists of 645 case study in room and pillar mines. 170 …