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Chemical Engineering

Ali Dhinojwala

Spider silk

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Full-Text Articles in Engineering

How Super Is Supercontraction? Persistent Versus Cyclic Responses To Humidity In Spider Dragline Silk, Todd Blackledge, Cecilia Bountry, Shing-Chung Wong, Avinash Baji, Ali Dhinojwala, Vasav Sahni, Ingi Agnarsson Jul 2014

How Super Is Supercontraction? Persistent Versus Cyclic Responses To Humidity In Spider Dragline Silk, Todd Blackledge, Cecilia Bountry, Shing-Chung Wong, Avinash Baji, Ali Dhinojwala, Vasav Sahni, Ingi Agnarsson

Ali Dhinojwala

Spider dragline silk has enormous potential for the development of biomimetic fibers that combine strength and elasticity in low density polymers. These applications necessitate understanding how silk reacts to different environmental conditions. For instance, spider dragline silk ;supercontracts' in high humidity. During supercontraction, unrestrained dragline silk contracts up to 50% of its original length and restrained fibers generate substantial stress. Here we characterize the response of dragline silk to changes in humidity before, during and after supercontraction. Our findings demonstrate that dragline silk exhibits two qualitatively different responses to humidity. First, silk undergoes a previously unknown cyclic relaxation-contraction response to …


Supercontraction Forces In Spider Dragline Silk Depend On Hydration Rate, Ingi Agnarsson, Cecilia Boutry, Shing-Chung Wong, Avinash Baji, Ali Dhinojwala, Andrew Sensenig, Todd Blackledge Jul 2014

Supercontraction Forces In Spider Dragline Silk Depend On Hydration Rate, Ingi Agnarsson, Cecilia Boutry, Shing-Chung Wong, Avinash Baji, Ali Dhinojwala, Andrew Sensenig, Todd Blackledge

Ali Dhinojwala

Spider dragline silk is a model biological polymer for biomimetic research due to its many desirable and unusual properties. 'Supercontraction' describes the dramatic shrinking of dragline silk fibers when wetted. In restrained silk fibers, supercontraction generates substantial stresses of 40-50 MPa above a critical humidity of approximately 70% relative humidity (RH). This stress may maintain tension in webs under the weight of rain or dew and could be used in industry for robotics, sensor technology, and other applications. Our own findings indicate that supercontraction can generate stress over a much broader range than previously reported, from 10 to 140 MPa. …