Engineering Commons^™

The Study Of Corrosion On Additive-Manufactured Metals., Braydan Daniels

Electronic Theses and Dissertations

The purpose of this study was to investigate and compare the corrosion mechanisms between wrought and additive-manufactured (3D-printed) copper and stainless steel. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, Tafel analysis, surface topology, and scanning electron microscopy for each metal within salt water, tap water, sulfuric acid, and synthetic body fluid (excluding copper in synthetic body fluid).

Overall, printed stainless steel was more corrosion-resistant than wrought stainless steel in tap water and synthetic body fluid based on OCP, LSV, and surface topology results. Additionally, printed copper was more corrosion-resistant than wrought …

Enhanced Kinetics And Modeling Of Pan-Based Carbon Felt Anodes In Vanadium Redox Flow Batteries, Michael Cyrus Daugherty

Doctoral Dissertations

All-vanadium redox flow batteries (VRFBs) are a promising technology for grid-level energy storage, however, there are still several limitations in the forms of durability, efficiency, and overall costs, which are barriers to its commercial viability. With both bulk electrolyte flowing through its porous matrix and species flux at the solid-electrolyte interface, electrodes are the component of VRFB systems which host electrochemical reactions and facilitate contact between the liquid phase electrolyte and the electronically conductive solid phase. While the more limiting electrode in VRFB systems is dependent on the material, for polyacrylonitrile (PAN)-based carbon felts, the anode constitutes a larger portion …

An Experimental And Numerical Investigation Of Flow Accelerated Flibe Corrosion, David B. Weitzel

Nuclear Engineering ETDs

Renewed interest in molten salt reactor technology has brought to light the need for a better understanding of FLiBe corrosion. To this end a flowing FLiBe corrosion test loop was designed to test the flow effects of FLiBe corrosion. The loop consists of a pump, melt tank, and stainless-steel tubing assembly that heats the molten salt to high temperatures and circulates it over test specimens. The experiment has been constructed and has completed initial shakedown testing.

To support the flowing FLiBe experiment, a numerical corrosion model that couples FLiBe electrochemistry, solid metal diffusion, and mass transport was implemented. The model …

An Efficient Electrochemical–Thermal Model For A Lithium-Ion Cell By Using The Proper Orthogonal Decomposition Method, Long Cai, Ralph E. White

Faculty Publications

The proper orthogonal decomposition method was applied to develop an efficient, reduced order electrochemical–thermal model for a lithium-ion cell. This model was validated for discharge simulations over a wide range of C rates and various cooling conditions of the cell. The reduced order model agrees well with the COMSOL model, a commercial finite element method solver, and requires times less computation time than the COMSOL model. The model predictions indicate that the discharge time or percent of capacity removed from the cell at an end of discharge voltage of 3.0 V depends on the rate of the discharge and heat …

Simulation Of The Oxygen Reduction Reaction At An Rde In 0.5 M H2So4 Including An Adsorption Mechanism, Qingbo Dong, Shriram Santhanagopalan, Ralph E. White

Faculty Publications

Oxygen reduction on the surface of a rotating disk electrode (RDE) in 0.5 M H₂SO₄ is simulated by including mass transfer, adsorption, and charge transfer. A generalized model for the adsorption and reaction of several species is introduced. The oxygen reduction reaction is simulated as a limiting case where oxygen is the only species adsorbed, and oxygen reduction is the only reaction that takes place on the surface of the electrode. The model is based on the Nernst–Planck equations for mass transfer and the Butler–Volmer equation for electrochemical kinetics. The simulated polarization curves capture the change in …

A Nonisothermal Nickel‐Hydrogen Cell Model, Pauline De Vidts, Javier Delgado, B. Wu, D. M. See, K. Kosanovich, Ralph E. White

Faculty Publications

No abstract provided.