Engineering Commons^™

Fabrication And Modification Of Titania Nanotube Arrays For Harvesting Solar Energy And Drug Delivery Applications, Ahmed El Ruby Abdel Rahman Mohamed

Electronic Thesis and Dissertation Repository

The fast diminishing of fossil fuels in the near future, as well as the global warming caused by increasing greenhouse gases have motivated the urgent quest to develop advanced materials as cost-effective photoanodes for solar light harvesting and many other photocatalytic applications. Recently, titania nanotube arrays (TNTAs) fabricated by anodization process has attracted great interest due to their excellent properties such as: high surface area, vertically oriented, highly organized, one-dimensional, nanotubular structure, photoactivity, chemical stability and biocompatibility. This unique combination of excellent properties makes TNTAs an excellent photoanode for solar light harvesting. However, the relatively wide band gap energy of …

Development Of High-Performing Polydimethylsiloxane-Based Membranes For Carbon Dioxide Separation, Tao Hong

Doctoral Dissertations

Membrane separation is highlighted as one of the most promising approaches to mitigate the excessive CO₂ [carbon dioxide] emission, due to its significant reduction of energy cost compared with many conventional separation techniques. Unfortunately, the separation performance of current membranes does not meet the practical CO₂/N₂ [nitrogen] separation requirements. And due to the huge volume of industrial flue gas, membranes with exceptionally high permeability are needed for practical reasons.

Currently, the separation mechanism of most polymeric membranes is based on size-sieving. However, this method is not sufficient for CO₂/N₂ separations due to the …

Investigation Of Setting Time And Compressive Strength Of Ready-Mixed Concrete Blended With Returned Fresh Concrete, Negasi Niguse Gebremichael

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Center for Sustainable Transportation Infrastructure (CSTI), in its 2012 study, estimated that out of all the concrete leaving the plant, between 2% and 7% of concrete returns to the plant unused as a returned fresh concrete (RFC). Disposal of both the truck wash water and RFC is a growing concern for the industry. Most industry personnel contacted during the investigation, agree that reusing is superior to recycling of this substantial RFC economically and environmentally. This study will determine if the reuse of RFC in subsequent batches compromises the quality of newly blended concrete.

The effect of RFC on fresh …

Sustainability Of Community-Managed Rural Water Supply Systems In Amazonas, Peru: Assessing Monitoring Tools And External Support Provision, Jacob E. Mangum

USF Tampa Graduate Theses and Dissertations

Globally, there is still a large number of people without access to safe drinking water; a known health risk. In rural areas of countries like Peru, when potable water systems are built the responsibility for maintaining these systems is given to volunteer water committees. Despite its prevalence as a management model, there is a consensus that community management alone cannot ensure sustainable water service. Therefore, the overall goal of this research is to assess the sustainability of community-managed water systems in rural areas of the department of Amazonas, Peru. Specifically, this research examines two mechanisms that have been shown to …

Torrefaction Kinetics Of Hemp Hurds, An Emerging Agricultural Byproduct, In A Small Retort, Tel Jensen

Civil and Environmental Engineering Undergraduate Honors Theses

As knowledge concerning the consequences of unsustainable energy sources and agricultural practices grows, development of low-impact alternatives to both becomes more important. Sustainable sources of biomass offer solutions to both problems. This study characterized the reaction kinetics of torrefying an agricultural byproduct, the woody interior of hemp stems, or hurds. Torrefaction was carried out at 250 °C in small and simple retorts made of galvanized steel pipe. A first-order model most closely approximated the reaction. A sensitivity analysis was performed and the data was adjusted to correct for three potential sources of error, and regressed to find the best fit …

Window Inserts And The People Adopting Them: Building Sustainable Communities In Maine, Daniel Sean Mistro

Electronic Theses and Dissertations

Residents of Maine face a large monetary expense to heat their homes in the winter. In Maine it takes 540 gallons of heating oil each year to heat a typical home [1]. Interior window inserts may be a practical solution to improve comfort, save money, and consume less environmentally harmful fossil fuels during cold winter months. The window inserts discussed in this paper are custom measured to fit into a window and consist of a wooden frame that is wrapped in two layers of polyolefin film and weather stripped for a snug fit. Commercial inserts cost $20-$36/square foot, or approximately …

A Comparative Analysis Of Feed And Environmental Factors On Broiler Growth In The United States, Alexandra Gulli

Graduate Theses and Dissertations

Broiler production in the United States has become an important industry within the last half century. As the demand for poultry continues to increase and the concern of climate change also increases, it will become an important part of the industry to become more sustainable. This study uses a feed optimization model, a broiler growth model, and a life cycle assessment (LCA) to determine how feed ingredients and the barn environment can affect the broiler’s growth and production emissions. A multi-criteria ration optimization model is used to produce feeds based on carbon footprint and cost. A growth model is used …

Modeling The Economic And Environmental Performance Of Offshore Wind Energy, Alexana Cranmer

Doctoral Dissertations

Offshore wind is a growing source of energy globally. Like any energy technology, it has impacts on the environment. In the case of renewable energy, we need a way to consider the environmental benefits as well as the environmental costs. This dissertation develops a set of models to examine the economic and environmental costs and benefits and the trade-offs between them. We ask how much offshore wind energy should be sited, and where should that offshore wind energy be located? The first model estimates the economic impact of wake interactions between wind farms. Wind farm sites are chosen through a …

Carbon And Nutrient Balances In Microalgal Bioenergy System, Eunyoung Lee

USF Tampa Graduate Theses and Dissertations

This research investigated life cycle environmental impacts and benefits of an integrated microalgae system with wastewater treatment system using an integrated process modeling approach combined with experimentation. The overall goal of this research is to understand energy, carbon and nutrient balances in the integrated system and to evaluate the environmental impacts and benefits of the integrated system from a carbon, nutrient, and energy perspective. In this study, four major research tasks were designed to contribute to a comprehensive understanding of the environmental and economic sustainability of the integrated system, which included development of an integrated co-limitation kinetic model for microalgae …

Comprehensive Silica Removal With Ferric Compounds For Industrial Wastewater Reuse, Ehren D. Baca

Civil Engineering ETDs

Cooling towers, integrated circuit (IC) manufacture and reverse osmosis (RO) generate copious amounts of wastewater high in colloidal and reactive silica inhibiting on-site or synergistic reuse. Silica present in cooling water can reach solubility limits via evaporation and form impervious scale on heat transfer surfaces that decreases efficiency. When water is treated by RO operating at high rejection, silica forms difficult-to-remove scale on the membrane feed side in the form of glassy patches and communities of aggregate particles, inhibiting aspirations for zero liquid discharge. Current methods for silica scale mitigation include abundant dosing with chemical antiscalents or complex operating schemes. …

Tailings Dust Emissions, Emily Degner, Sam Horn, Zakary Galligan, Ryan Bernard, Julie Jameson, Josh Mueller, Natalie Tucker, Joe Griffin

Chemical Engineering Undergraduate Honors Theses

Fugitive dust emissions from the storage and handling of mine tailings presents environmental and safety concerns, which must be addressed to promote the land sustainability and the health and safety of individuals around a tailings storage facility (TSF). The investigated dust control methods were agglomeration, binder slurry injection, and topical spray.

The Dust Busters determined that pelletizing was the most practical method of agglomeration. In order to produce durable pellets from the mine tailings, which consist primarily of silica, a binder must be added. A variety of binders were considered including magnesium and calcium chloride, bentonite, barite, cement, vinyl polymers, …

Design Of 3d Macroporous Inverse Opal Tio2 Binary And Ternary Composites Sensitized With Gold Nanoparticles And Cds Quantum Dots For Photocatalysis, Daniel A. Corella

Master of Science in Chemical Sciences Theses

Materials composed of titanium (IV) oxide (TiO₂) have received enormous scientific interest due to titania’s abundance, non-toxicity, and photocatalytic proficiency, however its large band gap limits its applicability under ambient conditions. Various attempts have been made to incorporate titania into composite systems to sensitize it for activity under a broader range of wavelengths. One such method includes utilizing narrow band gap semiconductors to form an electron transfer process analogous to photosynthesis referred to as a Z-scheme. Z-scheme systems can catalyze the decomposition of aqueous pollutants via generation of reactive oxygen species after input of sunlight. This work reports …

Development Of A Dynamic Cfd Model For Offshore Oscillating Water Columns With Non-Linear Interactions, Ken O'Connell

Theses

This thesis focuses on the development of a state of the art modelling technique for offshore Oscillating Water Column (OWC) type Wave Energy Converters (WEC) using Computational Fluid Dynamics (CFD). Current literature indicates a limited amount of work has been completed on studying these devices containing non-linear time dependent flow phenomenon. Initially, a 2D Numerical Wave Tank (NWT) is studied to reduce discretisation error in order to reproduce accurately propagating waves. Further development into a 3D domain permits the geometrical requirements of an OWC type spar buoy to be included.

In parallel, a single Degree of Freedom (DOF) model is …

Environmental Hazard Identification, Assessment And Control For A Sustainable Maritime Transportation System, Lizzette Marie Pérez Lespier

Doctoral Dissertations

"A demand exists to contribute towards the widening awareness of the need for sustainable maritime development and for coordinated maritime policies worldwide. Maritime shipping is considered the most eco-efficient mean of transportation and yet, is responsible for negative environmental impacts.

This dissertation focuses on developing data-driven decision support tools to evaluate the sustainable performance of MTS by focusing on the elements of the MTS that place stress on the environment. The first research contribution is a System Dynamics simulation model that examines the MTS resiliency after an extreme event and determines the sequence needed to restore the ocean-going port to …

Modeling Dynamic Community Acceptance Of Mining Using Agent-Based Modeling, Mark Kofi Boateng

Doctoral Dissertations

"This research attempts to provide fundamental understanding into the relationship between perceived sustainability of mineral projects and community acceptance. The main objective is to apply agent-based modeling (ABM) and discrete choice modeling to understand changes in community acceptance over time due to changes in community demographics and perceptions. This objective focuses on: 1) formulating agent utility functions for ABM, based on discrete choice theory; 2) applying ABM to account for the effect of information diffusion on community acceptance; and 3) explaining the relationship between initial conditions, topology, and rate of interactions, on one hand, and community acceptance on the other …

Smart Home Energy Management: An Analysis Of A Novel Dynamic Pricing And Demand Response Aware Control Algorithm For Households With Distributed Renewable Energy Generation And Storage, Jamal Abushnaf

Theses: Doctorates and Masters

Home energy management systems (HEMS) technology can provide a smart and efficient way of optimising energy usage in residential buildings. One of the main goals of the Smart Grid is to achieve Demand Response (DR) by increasing end users’ participation in decision making and increasing the level of awareness that will lead them to manage their energy consumption in an efficient way. This research presents an intelligent HEMS algorithm that manages and controls a range of household appliances with different demand response (DR) limits in an automated way without requiring consumer intervention. In addition, a novel Multiple Users and Load …