Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 3 of 3
Full-Text Articles in Engineering
Strategies For Controlling Bulk Heterojunction Morphology, Zach Daniel Seibers
Strategies For Controlling Bulk Heterojunction Morphology, Zach Daniel Seibers
Doctoral Dissertations
Organic photovoltaic devices have been extensively studied as a means to produce sustainable energy. However, the performance of organic-photovoltaic (OPV) devices is dependent upon a number of factors including the morphology of the active layer, device architecture, and processing conditions. Recent research has indicated that fullerenes in the bulk heterojunction are entropically driven to the silicon and air interfaces upon crystallization of P3HT, which occurs during thermal annealing. The first chapter of this research focuses on investigating the structure and function of end-tethered poly(3-hexylthiophene) chains to a transparent electrode as an anode buffer layer. Neutron reactivity reveals that these P3HT …
Magnetic, Optical And Electrical Properties Of Electron-Hole Pairs In Polymer And Organo-Metal Halide Perovskite Photovoltaic Cells, Yu-Che Hsiao
Doctoral Dissertations
Organic polymer and organo-metal halide perovskite (OMHP) materials have attracted extensive attention during the past decade due to their various applications, like solar cells, light emitting diode, even lasing action (OMHP). Especially, the organo-metal halide perovskite solar cell shows a remarkable power conversion efficiency of about 20%, which is comparable to the amorphous silicon solar cell. Therefore, OMHP solar cell had been considered as a promising substitution for the next generation of renewable energy source. The OMHP materials contain both advantages of organic and inorganic semiconductors, like solution processable thin film fabrication, long-range ambipolar transport characteristics, high dielectric constants, low …
Synthesis Of Acceptors For Use In Donor-Acceptor Copolymers And Characterization Of These Polymers, William D. Walker
Synthesis Of Acceptors For Use In Donor-Acceptor Copolymers And Characterization Of These Polymers, William D. Walker
Honors Theses
In this thesis, a selenium-derivatized acceptor was synthesized to examine the heavy atom effects of selenium on the position of the frontier molecular orbitals (HOMO/LUMO band gap) as opposed to sulfur in a donor-acceptor copolymer for use in light harvesting and detection applications. Over the course of this research, standard operating protocols for ultraviolet-visible (UV-Vis-NIR) and Fourier transform infrared (FT-IR) spectroscopies, as well as cyclic voltammetry (CV) characterization techniques were established. Once synthesized, the polymers were characterized through use of the established characterization protocols. The selenium-derivatized polymer exhibited a bathochromic shift compared to the sulfur analogue, with a solid-state absorption …