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Sodium Borohydride Hydrazinates: Synthesis, Crystal Structures, And Thermal Decomposition Behavior, Jianfeng Mao, Qinfen Gu, Zaiping Guo, Hua-Kun Liu
Sodium Borohydride Hydrazinates: Synthesis, Crystal Structures, And Thermal Decomposition Behavior, Jianfeng Mao, Qinfen Gu, Zaiping Guo, Hua-Kun Liu
Faculty of Engineering and Information Sciences - Papers: Part A
Metallic borohydride hydrazinates are novel boron- and nitrogen-based materials that appear to be promising candidates for chemical hydrogen storage. Herein, sodium borohydride hydrazinates, including NaBH4·N2H4 and NaBH4·2N2H4, were synthesized via a facile solution synthesis approach based on the solid-liquid reaction between NaBH4 and hydrazine in tetrahydrofuran (THF) solution. The crystal structure of NaBH4·2N2H4 was solved to a monoclinic structure with unit cell parameters a = 8.4592(2) Å, b = 11.7131(2) Å, c = 6.4584(1) Å, and β = 100.0777(14)°, with space group A1a1 (9). Each …
Facile Synthesis Of Coaxial Cnts/Mnox-Carbon Hybrid Nanofibers And Their Greatly Enhanced Lithium Storage Performance, Zunxian Yang, Jun Lv, Haidong Pang, Wenhuan Yan, Kun Qian, Tailiang Guo, Zaiping Guo
Facile Synthesis Of Coaxial Cnts/Mnox-Carbon Hybrid Nanofibers And Their Greatly Enhanced Lithium Storage Performance, Zunxian Yang, Jun Lv, Haidong Pang, Wenhuan Yan, Kun Qian, Tailiang Guo, Zaiping Guo
Faculty of Engineering and Information Sciences - Papers: Part A
Carbon nanotubes (CNTs)/MnOx-Carbon hybrid nanofibers have been successfully synthesized by the combination of a liquid chemical redox reaction (LCRR) and a subsequent carbonization heat treatment. The nanostructures exhibit a unique one-dimensional core/shell architecture, with one-dimensional CNTs encapsulated inside and a MnOx-carbon composite nanoparticle layer on the outside. The particular porous characteristics with many meso/micro holes/pores, the highly conductive one-dimensional CNT core, as well as the encapsulating carbon matrix on the outside of the MnOx nanoparticles, lead to excellent electrochemical performance of the electrode. The CNTs/MnOx-Carbon hybrid nanofibers exhibit a high initial reversible capacity of …