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Full-Text Articles in Engineering
Chance Constrained Optimization For Petrochemical Supply Chain With The Validation Technique, Kan Rungphanich
Chance Constrained Optimization For Petrochemical Supply Chain With The Validation Technique, Kan Rungphanich
Chulalongkorn University Theses and Dissertations (Chula ETD)
Nowadays, the profit is more concern in industry due to high business competition. Therefore, reducing the cost is needed to survive competition. Stochastic optimization had been interesting method to reduce opportunity and over-demand loss in the supply chain under uncertainties. Chance constrained optimization is one of the approaches to stochastic optimization. The uncertainties are included in chance constraint of event under level of confidence. This method is used to design the realistic supply chain giving more stabilities than deterministic optimization. The two case studies have been used to show the effectiveness of chance constrained optimization: the simple supply chain network …
Novel (Cu-Sn) And (Ni-Sn) Catalysts Prepared By Mechanical Alloying, Sakollapath Pithakratanayothin
Novel (Cu-Sn) And (Ni-Sn) Catalysts Prepared By Mechanical Alloying, Sakollapath Pithakratanayothin
Chulalongkorn University Theses and Dissertations (Chula ETD)
This research was aimed to synthesize intermetallic catalysts using mechanical alloying (Ma) technique. Copper (Cu) and nickel (Ni) were chosen to study since not only their properties are closed to the noble metal properties, e.g. platinum and palladium, but also they are not expensive. However, as also found in noble metals, both Cu and Ni metals are oxidized easily in air. To overcome this problem, either Cu or Ni was mixed with tin (Sn) to obtain bimetallics, viz. CuSn or NiSn, respectively. Therefore, this research was focused on finding the optimal conditions to synthesize both CuSn and NiSn bimetallics using …
Novel Microemulsion Formation By The Hydrophilic- Lipophilic Deviation Concept Using Carboxylate Extended Surfactants For Eor Application, Suchawadee Kumkhuntod
Novel Microemulsion Formation By The Hydrophilic- Lipophilic Deviation Concept Using Carboxylate Extended Surfactants For Eor Application, Suchawadee Kumkhuntod
Chulalongkorn University Theses and Dissertations (Chula ETD)
The Winsor type III (middle phase) microemulsion formation is widely used for enhanced oil recovery (EOR) application. A novel carboxylate surfactant has been an attractive surfactant for the oil recovery due to high chemical stability in harsh reservoir conditions (i.e., high brine concentration and high temperature). This study aims to formulate the middle phase microemulsion in order to obtain the minimum IFT and high solubilization capacity with binary anionic surfactant system using sodium dioctyl sulfosuccinate (AOT) and carboxylate extended surfactants with varying the polyethylene oxide number (EO = 2, 4 and 6) at three mixing molar ratios of 5:5, 7:3 …
Green Composites Of Polylactic Acid Filled With Natural Fiber For Biodegradation Application, Chamaiporn Yamoum
Green Composites Of Polylactic Acid Filled With Natural Fiber For Biodegradation Application, Chamaiporn Yamoum
Chulalongkorn University Theses and Dissertations (Chula ETD)
This research focuses on how to use natural fibers available from agricultural residues to produce biodegradable materials such as mulch films. Green composites were prepared from natural fibers (peanut shell and bagasse fiber) and polylactic acid (PLA) together with plasticizers. The presence of plasticizers improved PLA molecular mobility as seen by the reduction of glass transition, cold crystallization, and melting temperatures. The addition of natural fibers into PLA brought down decomposition temperature when compared to PLA. The morphological study of the composites showed poor interfacial adhesion between natural fibers and PLA matrix. Moreover, the loading of plasticizers improved distribution of …
Production Of Biojet Fuel From Palm Fatty Acid Distillate Over Ni/Hzsm-12 Catalyst, Chayanee Hiranyasiri
Production Of Biojet Fuel From Palm Fatty Acid Distillate Over Ni/Hzsm-12 Catalyst, Chayanee Hiranyasiri
Chulalongkorn University Theses and Dissertations (Chula ETD)
Generally, jet fuels are mainly derived from the refining of petroleum feedstock which exhaust greenhouse gases. Therefore, biojet fuel is introduced as an alternative way to solve the problem. Moreover, jet fuel must have a freezing point about -47 °C or below so iso-paraffins which have low freezing point are required. In this study, the hydroprocessing of palm fatty acid distillate (PFAD) over synthesized Ni/HZSM-12 and conventional Ni/HY catalysts which have different morphology and pore size for producing biojet fuel (hydrocarbon in a range of C9-C14) was studied in a continuous flow fixed-bed reactor under conditions of 350-400 °C, 10-30 …
Methane And Carbon Dioxide Adsorption On Al-Based And Zr-Based Mofs: Effects Of Amino-Functionalization, Orawee Lamoonkit
Methane And Carbon Dioxide Adsorption On Al-Based And Zr-Based Mofs: Effects Of Amino-Functionalization, Orawee Lamoonkit
Chulalongkorn University Theses and Dissertations (Chula ETD)
For natural gas storage, adsorbed natural gas (ANG) technology has attracted great attention. There is a wide range of porous materials for ANG, but the most promising porous adsorbents for natural gas are metal organic frameworks (MOFs). This study examined adsorption of carbon dioxide and methane gases on aluminium (Al) based MOFs and zirconium (Zr) based MOFs including MIL-53(Al), MIL-53(Al)-NH₂, UiO-66, UiO-66-NH₂ 25%, UiO-66-NH₂ 50%, UiO-66-NH₂ 75%, and UiO-66-NH₂. Experiments were carried out in a static system at 33°C and pressures up to 100 psi. Characterization and structural analysis of the adsorbents were investigated by Fourier transform infrared spectroscopy (FTIR), …
The Combined Material Flow Analysis And Life Cycle Assessment For Integrated End-Of-Life Of Mercury Contaminated Petroleum Waste Management, Putthita Chongchongprasert
The Combined Material Flow Analysis And Life Cycle Assessment For Integrated End-Of-Life Of Mercury Contaminated Petroleum Waste Management, Putthita Chongchongprasert
Chulalongkorn University Theses and Dissertations (Chula ETD)
Now a day, the waste management generated by offshore petroleum operation (including drilling and production) located in the Gulf of Thailand seem to be a great challenge. Because of their unique characteristic in terms of hazardous properties, petroleum waste requires particular treatments to reduce potential impacts to the environment and human life. This study, the petroleum waste by their disposal code, and waste code was sorted. The Hg-contaminated petroleum waste flow starting from waste generation towards to final disposal was conducted by Material Flow Analysis (STAN, 2.6.601) and Life Cycle Assessment (SimaPro 8.3.0.0) was conducted as tools for evaluating the …
Detergency Of Mixed Oily And Particulate Soils By Single And Mixed Surfactant Systems, Thanawan Teerasathittham
Detergency Of Mixed Oily And Particulate Soils By Single And Mixed Surfactant Systems, Thanawan Teerasathittham
Chulalongkorn University Theses and Dissertations (Chula ETD)
This research studies the detergency performance of mixed surfactants of (anionic and nonionic surfactants) for mixed oily and particulate soils on polyester/cotton blend fabric, and compares with a commercial liquid detergent. Palm oil and kaolinite are used as representatives of oily soil and particulate soil, respectively. The anionic surfactants used in this study are methyl ester sulfonate (MES), linear alkyl benzene sulfonate (LAS) and sodium dodecyl sulfate (SDS). The nonionic surfactants are alcohol ethoxylate 7EO (AE7) and alcohol ethoxylate 9EO (AE9). The effect of surfactant concentrations, NaCl concentration, and mixing ratios of the selected surfactant formulations on detergency performance are …
Green-House Gas Storage Through Enhanced Hydrate Formation, Thiphakorn Absuwan
Green-House Gas Storage Through Enhanced Hydrate Formation, Thiphakorn Absuwan
Chulalongkorn University Theses and Dissertations (Chula ETD)
The CO₂ hydrate formation in the presence of different tetrahydrofuran (THF), sodium dodecyl sulfate (SDS), and methyl ester sulfonate (MES) concentrations was investigated in terms of kinetics and thermodynamics. The formation experiment was conducted in the quiescent condition and close system at 3 MPa and 3 °C. The results showed that the CO₂ hydrates formed in the presence of 10 mol% THF, while it did not form with 5.56 mol% THF. The presence of SDS or MES did not promote the hydrate formation. However, the hydrates formed in the presence of a mixture of SDS or MES with 5.56 mol% …
Optimization Algorithm Study : Mixed Integer Linear Programming, Tittawat Fongchantuk
Optimization Algorithm Study : Mixed Integer Linear Programming, Tittawat Fongchantuk
Chulalongkorn University Theses and Dissertations (Chula ETD)
In the present, many petrochemical and petroleum products (engine fuel, solvent, plastic and synthetic rubber. etc.) are important. They are transported by ship, pipe line or train every day. So, minimizing transportation cost and time or maximizing profit is an important key of every company. In this optimization process, the optimal supply chain must be well developed in mathematical programming with the objective function of minimum cost or maximum profit and be solved by using optimization solvers. Objective functions and their constraints are solved by suitable types of optimization solvers: Linear programming (LP) and mixed integer linear programming (MILP). MILP …
Evaluation Of Environmental Impacts For Non-Metallic Part In Waste Printed Circuit Boards (Pcbs) Using Combined Material Flow Analysis (Mfa) And Life Cycle Assessment (Lca), Warisara Rungsitikul
Evaluation Of Environmental Impacts For Non-Metallic Part In Waste Printed Circuit Boards (Pcbs) Using Combined Material Flow Analysis (Mfa) And Life Cycle Assessment (Lca), Warisara Rungsitikul
Chulalongkorn University Theses and Dissertations (Chula ETD)
Printed circuit boards (PCBs) have become common components in most electric and electronic equipment. Because of their wide ranges of application, waste PCBs is becoming one of the most rapidly growing wastes. Recycling of waste PCBs is an important subject not only for the protection of the environment but also for the recovery of valuable metals. This study aimed to evaluate the waste PCBs management strategies using the combination of material flow analysis (MFA, STAN v.2.6.801) and life cycle assessment (LCA, SimaPro v.8.3.0.0) methods. The waste management scenario was considered for three different options; disposal of the waste PCBs (Option …
Light Responsive With Metallo-, And Hydrogen Bonded Benzoxazine Dimer-Based Supramolecular Structure, Sorapat Niyomsin
Light Responsive With Metallo-, And Hydrogen Bonded Benzoxazine Dimer-Based Supramolecular Structure, Sorapat Niyomsin
Chulalongkorn University Theses and Dissertations (Chula ETD)
The present work focuses on multi-responsive molecule based on supramolecular chemistry of benzoxazine dimer as a benzoxazine supramolecular crosslinker, fluorescent labelling benzoxazine conjugated with rotaxane system and benzoxazine pendant group block copolymer. The use of azobenzene derivatives in benzoxazine synthesis provides light responsive behaviour. The remained hydroxyl group from aminoalcohol allows benzoxazine to conjugate with desired functional group. The dihydroxyl benzoxazine acts as molecular crosslinker for poly(acrylic acid) by conjugation. The ring-opening reaction brings benzoxazine dimeric unit on the crosslinker which also showed metal ion complexation. The complexation strengthens the cross-linked polymer network. The complex can reversely form by treating …
Catalytic Applications Of Cuo Loaded Mesoporous Ceo₂ And Cuo Loaded Mesoporous Ceo₂-Zro₂ Catalyst, Sureerat Jampa
Catalytic Applications Of Cuo Loaded Mesoporous Ceo₂ And Cuo Loaded Mesoporous Ceo₂-Zro₂ Catalyst, Sureerat Jampa
Chulalongkorn University Theses and Dissertations (Chula ETD)
Copper oxide (CuO) loaded mesoporous ceria (CeO₂) and Copper oxide (CuO) loaded mesoporous ceria-zirconia (CeO₂-ZrO₂) catalysts are successfully synthesized for preferential oxidation of CO (CO-PROX) and autothermal steam reforming of methanol (ASRM). Mesoporous CeO₂ and mesoporous CeO₂-ZrO₂ as catalyst supports with high specific surface area and ordered structure are prepared via a nanocasting process by using MCM-48 as template. Deposition-precipitation technique is chosen to load various Cu contents (1 to 9 wt.%) on the synthesized mesoporous supports. The synthesized CuO loaded mesoporous CeO₂ (Cu-C) and CuO loaded mesoporous CeO₂-ZrO₂ (Cu-CZ) catalysts are characterized by N₂ adsorption-desorption, X-ray diffraction, transmission electron …
Development Of Composite Polyelectrolyte Complex Membrane For Cationic Dye And Heavy Metal Sorption, Wanwanut Chueasupcharoen
Development Of Composite Polyelectrolyte Complex Membrane For Cationic Dye And Heavy Metal Sorption, Wanwanut Chueasupcharoen
Chulalongkorn University Theses and Dissertations (Chula ETD)
The sorption process is most useful in water treatment because it provides high sorption efficiency, low cost and rapid method. Polyelectrolyte complex (PECs) is a novel polymeric membrane prepared by mixing between oppositely charged polyelectrolyte solution of PDADMAC and PSS. Activated carbon (ACs) is used to improved adsorption efficiency in PECs. Non-stoichiometric PDADMAC/PSS membrane were prepared by mixing excess PSS concentration to get the negative charges on the membrane surface. Sorption efficiency was evaluated by methylene blue, cationic dye and heavy metal ions based on the same material, the difference sorption mechanism were observe. In the cationic dye, the adsorption …
Thermomechanical Behavior And Chemical Sensing Cationic Poly(Diallyldimethylammonium Chloride) And Anionic Poly(Sodium 4-Styrene Sulfonate) Assembled Into Composite Polyelectrolyte Multilayer Thin Films And Complex Membranes, Rateeya Saikaew
Chulalongkorn University Theses and Dissertations (Chula ETD)
Polyelectrolyte composite membranes of cationic PDADMAC and anionic PSS assembled into polyelectrolyte multilayer (PEM) thin film and polyelectrolyte complex (PEC) membranes were used as matrix embedded with several additive molecules. Nano-scale PEM films fabricated using the layer-by-layer deposition method and the loading and release of a hydrophobic model drug curcumin (Cur) was studied for drug delivery and sensing applications. Interestingly, it was found that the loading and release of Cur could be triggered by solvent composition and temperature. In a parallel study, the alternative to the nanoscale PEM was studied in the form of PEC, which were used as stand-alone …