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Full-Text Articles in Engineering

Light-Emitting Nanocomposites And Novel Amorphous Polymers For Optical Applications, Kyle Gipson Dec 2011

Light-Emitting Nanocomposites And Novel Amorphous Polymers For Optical Applications, Kyle Gipson

All Dissertations

Polymeric optical materials generally are comprised of amorphous polymers that are transparent in at visible wavelengths but exhibit strong absorption bands in the near-infrared making them less useful for many optical applications. Attenuation, which is the absorption per unit length, largely results from the high vibrational energy associated with carbon-hydrogen bonds contained in the polymer backbone. Attenuation can be mitigated by optical amplification utilizing light emitting additives. Investigated in this dissertation are synthesis techniques for the fabrication of light-emitting polymer nanocomposites and their resultant thermal and rheological characteristics for potential use as polymer optical fibers or films.
Inorganic nanocrystals doped …


Adsorption And Diffusion Of Light Hydrocarbons In Ddr Zeolite, Adam Vidoni Dec 2011

Adsorption And Diffusion Of Light Hydrocarbons In Ddr Zeolite, Adam Vidoni

Electronic Theses and Dissertations

This thesis reports the results of an experimental study aimed at characterizing the transport properties of DDR crystals (a pure silica zeolite analog) by the “zero length column” technique. This material is potentially useful as a size selective molecular sieve adsorbent for separation of CH4 – CO2 in the upgrading of low grade natural gas (or biogas) as well as for the separation of C3H6 - C3H8 for production of polypropylene. In both these applications pure silica zeolites (such as DDR) have important practical advantages over the traditional cationic zeolites since they …


Functional Coatings: Superhydrophopbic And Conductive Coatings, Seyed Amirhossein Seyedmehdi Jun 2011

Functional Coatings: Superhydrophopbic And Conductive Coatings, Seyed Amirhossein Seyedmehdi

Electronic Thesis and Dissertation Repository

The natural world has many superhydrophobic and self-cleaning surfaces such as butterfly wings and lotus plant leaves, both well known examples of self-cleaning surfaces. Water droplets on these surfaces can pick up dirt particles and remove contamination. The significant self-cleaning ability of these surfaces has inspired many researchers to attempt to fabricate these superhydrophobic coatings, mimicking their self-cleaning properties, using different methods. Most of the superhydrophobic coatings described in current literature need to be cured in ovens and thus difficult to be applied and/or be maintained in the work place. Therefore, there is a need to develop room temperature curing …


Determining A Method For Rendering Low Cost Cdse(Zns) Core(Shell) Quantum Dots Aqueous Soluble Via Amphiphilic Polymer Wrapping, Patrick Mcbride Jun 2011

Determining A Method For Rendering Low Cost Cdse(Zns) Core(Shell) Quantum Dots Aqueous Soluble Via Amphiphilic Polymer Wrapping, Patrick Mcbride

Materials Engineering

Herein is described the procedure of two amphiphilic polymer wrapping techniques that may be employed for obtaining aqueous soluble quantum dots (QDs) for use in biological fluorescent imaging applications. The advent of QDs has led to new nanoscale fluorescent materials that exhibit unparalleled quantum yields (QYs), high resistance to photobleaching, tunable emissions, and
absorption over a large optical range. However, the QD synthesis employed here at Cal Poly to obtain bright, photostable CdSe(ZnS) core(shell) QDs involves the use of organic solvents and surfactants, leading to hydrophobic QDs. Since all of biology relies on aqueous solubility, this hydrophobicity creates a major …


Design Of Equipment For The Study Of Non-Isothermal Flow In Polymer Fluid, Opeoluwa Oluwaseun Kolawole May 2011

Design Of Equipment For The Study Of Non-Isothermal Flow In Polymer Fluid, Opeoluwa Oluwaseun Kolawole

Masters Theses

The polymer industry is an ever growing industry, and, as it grows, companies are continuously looking for ways to study and understand the behaviors of polymers in relation to the processing and production. This is to ensure the production of high quality products and to improve existing products.
An important parameter during polymer processing is temperature. Temperature control affects several rheological parameters such as viscosity, and in turn the quality of the final products. Frictional or viscous heating is a very important part of polymer processing and occurs in almost every polymer processing operation.
The objective of this research is …


Mechanical Evaluation Methods For Polymer And Composite Systems, Donna Theresa Wrublewski Feb 2011

Mechanical Evaluation Methods For Polymer And Composite Systems, Donna Theresa Wrublewski

Open Access Dissertations

This dissertation describes the development and application of various mechanical characterization techniques to four types of polymer composite materials. The composite nature of these materials ranges from molecular to macro-scale, as do the size scales probed by the techniques chosen. The two main goals of this work are to evaluate the suitability of existing characterization methods to new composite materials (and augment the methods as needed), and to use these methods to determine optimal composite system parameters to maximize the desired mechanical response. Chapter 2 employs nondestructive ultrasonic spectroscopy for characterizing the stiffness response of both micron-scale woven composites and …