Engineering Commons^™

Coupled Electrical And Magnetic Properties In (La,Sr)Feo3-Δ, X.-D. Zhou, Qingsheng Cai, Jinbo Yang, M. S. Kim, William B. Yelon, William Joseph James, Y.-W. Shin, B. J. Scarfino, Harlan U. Anderson

Materials Science and Engineering Faculty Research & Creative Works

This article is aimed at studying the temperature dependence oxygen nonstoichiometry, magnetic moments, Fe³⁺ fraction, Néel temperature and conductivity of (La,Sr)FeO_3-δ. It is found that the magnetic properties in La_0.60 Sr_0.40 Fe_3-δ is determined by Fe³⁺ and its concentration, and the conductance is resulted from Fe⁴⁺ ions, which act as electron holes. Both of magnetic and electrical properties were directly governed by oxygen nonstoichiometry (δ). when δ=0.2, the compound has maximum Fe³⁺, the saturation magnetic moments and Néel temperature are 3.8 µB and 410 °C, both at the highest level, …