Engineering Commons^™

Ambient Ammonia Synthesis Via Microwave-Catalytic Materials And Plasma Chemistry, Siobhan Brown

Graduate Theses, Dissertations, and Problem Reports

Ammonia is critical to supporting human life on earth because of its use as fertilizer. The Haber-Bosch process to produce ammonia has been practiced for over 100 years. This process operates at high pressure and temperature to overcome the thermodynamic and kinetic limitations of the ammonia synthesis reaction thus researchers have tried to overcome it for decades. At present this process represents 1% of global energy usage and 2.5% of global CO₂ emissions. The proposed chemical looping ammonia synthesis approach seeks to reduce the environmental impact of this critical process and to elucidate microwave-catalytic principles.

This research aims to …

Ultrashort Pulse Laser Filamentation Electrical And Optical Diagnostic Comparison, James E. Wymer

Optical Science and Engineering ETDs

Results presented here examine the effect of changing gas pressure on the radio frequency (RF) emissions of an ultrashort pulse laser filament plasma and how those emissions vary longitudinally in the laser focal region. We use a WR284 rectangular waveguide with a 1.5 cm hole that allows the beam through. A 3.2 GHz microwave signal is emitted in the waveguide, and signals are received through a waveguide-to-coax antenna connected to an HP8470B Schottky diode. By enabling and disabling the 3.2 GHz signal, we measure both the self-emitted RF from a USPL filament and subsequently the degree of attenuation a filament …

Impurity Production And Transport In The Prototype Material Plasma Exposure Experiment, Clyde J. Beers

Doctoral Dissertations

The Prototype Material Plasma Exposure eXperiment (Proto-MPEX) is a linear pulse plasma device at Oak Ridge National Laboratory with the purpose of doing the research and development for the heating concepts on the planned full MPEX device. The goal of MPEX is to perform material studies at fusion relevant conditions. To understand the conditions at the material target for performing plasma-material interaction studies the ion temperature and density, the electron temperature and density, and the particle flux and fluence must be known. Impurities within Proto-MPEX can alter the desired conditions at the material target and need to be understood for …

Plasma Aerodynamics: Experimental Quantification Of The Lift Force Generated On An Airfoil Using Plasma Actuation To Estimate Power Requirements In Small Uav Applications, Getachew Ashenafi

UNLV Theses, Dissertations, Professional Papers, and Capstones

This research addressed the amount of electric power required to induce specific changes in lift force using a NACA 2127 airfoil with a chord length of ~28 mm, connected to a micro load cell, in a wind tunnel of 103 square centimeter cross-section. A DBD plasma actuator supplied by a ZVS driven high voltage pulsed DC circuit, operating at a frequency of 17.4 kHz, was utilized for voltages of up to 5000 V. Two configurations of electrode gapping were compared to determine the efficient use of power. The configuration with a gap of ~1 mm between the upstream and downstream …

Electrical And Chemical Characterization Of A Helium-Air Non-Thermal Atmospheric Pressure Plasma Jet, Adam Zandani

Seton Hall University Dissertations and Theses (ETDs)

Plasma is one of the most complicated, yet promising fields in physics due to its high efficiency and multitude of crucial applications such as biological sterilization, polymer modification, surface treatments, etching, agriculture, and facilitation of selective catalytic processes to name a few. With these advantages, mysteries still remain. With this in mind, in order to accurately gauge the total influence of the plasma applied in various processes, understanding what is being produced and how the production occurs is vital. To understand this, optical emission spectroscopy was used to gauge how the species generated are influenced by operation parameters such as …

Characterization Of A Plasma Source Simulating Solar Wind Plasma In A Vacuum Chamber, Blake Anthony Folta

Masters Theses

"The United States has set an aggressive time line to not only return to the Moon, but also to establish a sustained human presence. In the Apollo missions dust was a significant factor, but the duration of those missions was short so dust and surface charging were problems, but they did not pose an immediate threat. For a long-term mission, these problems instead become incredibly detrimental. Because of this, research needs to be conducted to investigate these phenomena so that mitigation techniques can be developed and tested. To this end, this thesis serves to demonstrate the Gas and Plasma Dynamics …

Investigation Of Pyrolysis Gas Chemistry In An Inductively Coupled Plasma Facility, Corey Tillson

Graduate College Dissertations and Theses

The pyrolysis mechanics of Phenolic Impregnated Carbon Ablators (PICA) makes it a valued material for use in thermal protection systems for spacecraft atmospheric re-entry. The present study of the interaction of pyrolysis gases and char with plasma gases in the boundary layer over PICA and its substrate, FiberForm, extends previous work on this topic that has been done in the UVM 30 kW Inductively Coupled Plasma (ICP) Torch Facility. Exposure of these material samples separately to argon, nitrogen, oxygen, air, and carbon dioxide plasmas, and combinations of said test gases provides insight into the evolution of the pyrolysis gases as …

Intensity Control Of Dielectric Barrier Discharge Filaments, Matthew Crawford Paliwoda

Masters Theses

"When operated in a filamentary mode, a volume dielectric barrier discharge (DBD) is known to produce patterned plasma structures. These structures are currently being explored for reconfigurable metamaterial applications. In this work the presence and intensity of a single filament, within an array of filaments, was controlled by adjusting the voltage to that filament's individual needle electrode. The current, voltage, and time-averaged normalized light intensity were measured while varying the voltage of the needle through a self-biasing resistance. For a 7.5 kV, 3.2 kHz DBD in air, the needle-controlled filament intensity varies from that of the surrounding filaments to zero …

High Resolution Time-Resolved Imaging System In The Vacuum Ultraviolet Region, Yuseong Jang

Electronic Theses and Dissertations

High-power debris-free vacuum ultraviolet (VUV) light sources have applications in several scientific and engineering areas, such as high volume manufacturing lithography and inspection tools in the semiconductor industry, as well as other applications in material processing and photochemistry. For the past decades, the semiconductor industry has been driven by what is called "Moore's Law". The entire semiconductor industry relies on this rule, which requires chip makers to pack transistors more tightly with every new generation of chips, shrinking the size of transistors. The ability to solve roadmap challenges is, at least partly, proportional to our ability to measure them. The …

Fully Coupled Fluid And Electrodynamic Modeling Of Plasmas: A Two-Fluid Isomorphism And A Strong Conservative Flux-Coupled Finite Volume Framework, Richard Joel Thompson

Doctoral Dissertations

Ideal and resistive magnetohydrodynamics (MHD) have long served as the incumbent framework for modeling plasmas of engineering interest. However, new applications, such as hypersonic flight and propulsion, plasma propulsion, plasma instability in engineering devices, charge separation effects and electromagnetic wave interaction effects may demand a higher-fidelity physical model. For these cases, the two-fluid plasma model or its limiting case of a single bulk fluid, which results in a single-fluid coupled system of the Navier-Stokes and Maxwell equations, is necessary and permits a deeper physical study than the MHD framework. At present, major challenges are imposed on solving these physical models …

Basic Research On The Characteristics Of A Constricted Pulsed Glow Discharge, Sean Daniel Andersen

UNLV Theses, Dissertations, Professional Papers, and Capstones

In certain plasma discharge experiments, it has been observed that under specific conditions a plasma glow discharge column tends to seek the central location of the discharge electrodes away from the electrode edges and chamber walls. Further, the column appears to have the properties of a stabilized equilibrium plasma pinch in a glow (non-arc-like) state. This is unusual since, normally field enhancements occur on edges resulting in arc-like discharge breakdown. Also, the column of plasma that protrudes from the anode emits highly intense, non-uniform light that is uncharacteristically bright for a glow discharge.

The main purpose of this thesis is …

Use Of Ultra High Vacuum Plasma Enhanced Chemical Vapor Deposition For Graphene Fabrication, Shannen Adcock

Graduate Theses and Dissertations

Graphene, what some are terming the "new silicon", has the possibility of revolutionizing technology through nanoscale design processes. Fabrication of graphene for device processing is limited largely by the temperatures used in conventional deposition. High temperatures are detrimental to device design where many different materials may be present. For this reason, graphene synthesis at low temperatures using plasma-enhanced chemical vapor deposition is the subject of much research. In this thesis, a tool for ultra-high vacuum plasma-enhanced chemical vapor deposition (UHV-PECVD) and accompanying subsystems, such as control systems and alarms, are designed and implemented to be used in future graphene growths. …

Characterization Of Microwave Cavity Discharges In A Supersonic Flow, Dareth Janette Drake

Physics Theses & Dissertations

A partially ionized gas is referred to as either a plasma or a discharge depending on the degree of ionization. The term discharge is usually applied to a weakly ionized gas, i.e. mostly neutrals, where as a plasma usually has a larger degree of ionization. To characterize a discharge the plasma parameters, such as the rotational temperature, vibrational temperature, and electron density, must be determined. Detailed characterization of supersonic flowing discharges is important to many applications in aerospace and aerodynamics. One application is the use of plasma-assisted hydrogen combustion devices to aid in supersonic combustion. In conditions close to the …

The Effects Of Electrode Geometry On Current Pulse Caused By Electrical Discharge Over An Ultra-Fast Laser Filament, Matthew Bubelnik

Electronic Theses and Dissertations

The time-resolved electrical conductivity of a short-pulse generated plasma filament in air was studied. Close-coupled metal electrodes were used to discharge the stored energy of a high-voltage capacitor and the resulting microsecond-scale electrical discharge was measured using fast current sensors. Significant differences in the time dependence of the current were seen with the two electrode geometries used. Using sharp-tipped electrodes additional peaks in the time-resolved conductivity were seen, relative to the single peak seen with spherical electrodes. We attribute these additional features to secondary electron collisional ionization brought about by field enhancement at the tips. Additional discrepancies in the currents …