Engineering Commons^™

Corrosion Related To The Nuclear Waste Containers, Ali Ebrahimzadeh Pilehrood

Corrosion Research

The disposal of nuclear waste is a demanding topic, and the existing methods, whether it is temporary storage in spent fuel pools or storage in geological repositories, both face the risk of corrosion-related problems. Any failure in these storage methods can potentially lead to the release of radioactive materials into the environment. To avert such catastrophic scenarios, people in the nuclear industry consistently monitor and maintain these storage facilities endlessly and attempt to improve the plans designed to store nuclear waste. Here, I will examine the nuclear waste management organization (NWMO) plan in Canada. Choosing an appropriate location for the …

Corrosion Case Study On Pipeline, Kangze Ren

Corrosion Research

The Kashagan pipeline leaks were likely caused by sulfur stress corrosion cracking, a combined corrosion mechanism developed by the presence of high pressure, the high level of hydrogen sulfide(the main "ingredient" of sour gas), and poor metallurgical choice. Improper welding and poor metallurgical examination were blamed for causing the leaking issue. The purpose of the current review is to raise the alarm about the inappropriate corrosion management of Kashagan oil production and its societal and environmental consequences.

Corrosion Case Study On Automobile, Grace Ajayi, Xinran Pan, Geethu Sasikala, Marshall S. Yang

Chemistry Publications

No abstract provided.

Novel And Fast Peridynamic Models For Material Degradation And Failure, Siavash Jafarzadeh

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Fracture is one of the main mechanisms of structural failure. Corroded surfaces with chemically-induced damage are, notably, potential sites for crack initiation and propagation in metals, which can lead to catastrophic failure of structures. Despite some progress in simulating fracture and damage using classical models, realistic prediction of complex damage progression and failure has been out of reach for many decades. Peridynamics (PD), a nonlocal theory introduced in 2000, opened up new avenues in modeling material degradation and failure. Existing numerical methods used to discretize PD equations, however, are quite expensive as the PD nonlocal interactions make them unaffordable for …

Assessment Of Cu(In, Ga)Se₂ Solar Cells Degradation Due To Water Ingress Effect On The Cds Buffer Layer, Deewakar Poudel, Benjamin Belfore, Shankar Karki, Grace Rajan, Sina Soltanmohammad, Angus Rockett, Sylvain Marsillac

Electrical & Computer Engineering Faculty Publications

The effect of water ingress on the surface of the buffer layer of a Cu(In, Ga)Se2 (CIGS) solar cell was studied. Such degradation can occur either during the fabrication process, if it involves a chemical bath as is often the case for CdS, or while the modules are in the field and encapsulants degrade. To simulate the impact of this moisture ingress, devices with a structure sodalime glass/Mo/CIGS/CdS were immersed in deionized water. The thin films were then analyzed both pre and post water soaking. Dynamic secondary ion mass spectroscopy (SIMS) was performed on completed devices to analyze impurity diffusion …

A Data-Driven Method For Online Monitoring Tube Wall Thinning Process In Dynamic Noisy Environment, Chen Zhang, Jun Long Lim, Ouyang Liu, Aayush Madan, Yongwei Zhu, Shili Xiang, Kai Wu, Rebecca Yen-Ni Wong, Jiliang Eugene Phua, Karan M. Sabnani, Keng Boon Siah, Wenyu Jiang, Yixin Wang, Emily Jianzhong Hao, Hoi, Steven C. H.

Research Collection School Of Computing and Information Systems

Tube internal erosion, which corresponds to its wall thinning process, is one of the major safety concerns for tubes. Many sensing technologies have been developed to detect a tube wall thinning process. Among them, fiber Bragg grating (FBG) sensors are the most popular ones due to their precise measurement properties. Most of the current works focus on how to design different types of FBG sensors according to certain physical laws and only test their sensors in controlled laboratory conditions. However, in practice, an industrial system usually suffers from harsh and dynamic environmental conditions, and FBG signals are affected by many …

Corrosion Protection Afforded By Praseodymium Conversion Film On Mg Alloy Aznd In Simulated Biological Fluid Studied By Scanning Electrochemical Microscopy, Seyed S. Jamali, Simon E. Moulton, Dennis E. Tallman, Maria Forsyth, Jan Weber, Azadehsadat Mirabedini, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Surface passivation of AZNd Mg alloy with Pr(NO₃)₃ is studied using scanning electrochemical microscopy (SECM) in surface generation/tip collection (SG/TC) and AC modes. Corrosion protection afforded by the Pr treatment and the degradation mechanism in a simulated biological environment was examined on a local scale and compared with non-treated AZNd. SG/TC mode results revealed a drastic decrease in H2 evolution due to the Pr treatment. Mapping the local insulating characteristics using AC-SECM showed higher conductivity of the surface where H₂ evolution was most favorable.

Applications Of Scanning Electrochemical Microscopy (Secm) For Local Characterization Of Az31 Surface During Corrosion In A Buffered Media, Sina S. Jamali, Simon E. Moulton, Dennis E. Tallman, Maria Forsyth, Jan Weber, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

Different modes of scanning electrochemical mapping (SECM) such as surface generation/tip collection (SG/TC), amperometry, AC-SECM and potentiometry were employed to characterize the active/passive domains, hydrogen gas (H2) evolution and local pH on a corroding surface of AZ31 in simulated biological fluid (SBF). It was found that the main domains of H2 evolution are associated with lower insulating properties of the surface as well as higher local pH. The near surface pH was found to be highly alkaline indicating that, even in a buffered solution such as SBF, the local pH on a corroding AZ31 surface can be significantly different to …

In Vitro Studying Corrosion Behaviour Of Biocorrodible Mg Alloys, Sina S. Jamali, Simon Moulton, Maria Forsyth, Gordon G. Wallace

Australian Institute for Innovative Materials - Papers

The idea of bioabsorbable/biocorrodible stents has gained increasing attention in the last decade. Permanent coronary stents, traditionally made from 316L grade stainless steel, are routinely used for the treatment of blocked arteries. However, these stents can cause complications such as restenosis, thrombosis and the need for the patient to undergo prolonged antiplatelet therapy. Biodegradable metal stents provide an opportunity for the stent to remain in place for a period to ensure restoration of function and then degrade through a carefully controlled bio-corrosion process. Among the number of potentially suitable materials, Magnesium alloys have shown great promise as a stent material …

Nondestructive Electrothermal Detection Of Corrosion, Brittany Ambeau, Harris Enniss, Stefan Schnake

Mathematical Sciences Technical Reports (MSTR)

Nondestructive testing and imaging plays an important role in many industries, e.g., the monitoring and maintenance of corrosion in aircraft. The general technique is to input energy in some form into an object, observe the object’s response, and from this input-output information determine the internal structure. New techniques are always being explored, and recently there has been much interest in methods that use multiple forms of energy. In this vein, we examine a new technique for imaging corrosion or material loss in an object by combining electrical and thermal measurements on some accessible portion of the object’s outer boundary. The …

Electrical Impedance Imaging Of Corrosion On A Partially Accessible 2-Dimensional Region, Court Hoang, Katherine Osenbach

Mathematical Sciences Technical Reports (MSTR)

In this paper we examine the inverse problem of determining the amount of corrosion on an inaccessible surface of a two-dimensional region. Using numerical methods, we develop an algorithm for approximating corrosion profile using measurements of electrical potential along the accessible portion of the region. We also evaluate the effect of error on the problem, address the issue of ill-posedness, and develop a method of regularization to correct for this error. An examination of solution uniqueness is also presented.

Influence Of Magnesium Nitrate On The Corrosion Performance Of Sol-Gel Coated Aa2024-T3 Aluminium Alloy, Rajath Varma, Brendan Duffy, John Cassidy

Articles

Traditional anti-corrosion technology has relied heavily on using reducible metal species, predominantly hexavalent chromium (Cr(VI)), for protecting reactive metal alloys such as aluminium which is extensively used in the aerospace sector. However, the impending changes in the use of Cr(VI) in Europe and the United States have forced aerospace manufacturers to examine alternative materials for protecting aluminium. One of the most promising alternatives being investigated are organosilane based sol-gels containing anticorrosion additives. In this work the anti-corrosion properties of magnesium (II) nitrate (Mg(NO3)2) as a inhibitor was investigated at different concentrations (0.1% - 1.0 wt %) in a methyltriethoxysilane (MTEOS) …

Localised Galvanic Corrosion Processes In Thermal Spray Coated/Cast Aluminium Alloy Systems, David Culliton, Tony Betts, David Kennedy

Conference Papers

Cast Aluminium Alloys, because of the propensity of aluminium to react with impurities and alloying elements, are prone to developing IM impurities during the solidification process. These IM phases can act, in some fluids, as initiation sites for localised corrosion processes, resulting in degradation phenomena, such as pitting. Whilst Thermal Spray coatings can improve the wear resistance of Cast Aluminium Alloys, their corrosion performance may be hampered by the presence of through porosity within the coating.

The present work details some preliminary studies of the localised corrosion processes occurring at the interface area between a Thermal Spray coating and a …