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Electrohydrodimerization Of Fumarodinitrile On Liquid Gallium Electrode, He Wei, Huang Ying
Electrohydrodimerization Of Fumarodinitrile On Liquid Gallium Electrode, He Wei, Huang Ying
Journal of Electrochemistry
Electrohydrodimerization(EHD) of fumarodinitrile on liquid gallium electrode can take place not only in hydrotropic solution of tetraethylammonium p_toluenesulphonate(TEA_PTS), but also in aqueous solution containing low concentration of strong surfactants, such as TritonX_100. In solution without organic surfactant, FDN yields a single two_electron reduction wave corresponding to the formation of a saturated monomer called as butanedinitrile. If some TEA_PTS or TritonX_100 is added into the solution, the original two_electron wave is splitted into two continuous single_electron reduction wave and corresponding EHD of fumarodinitrile is obtained.