Open Access. Powered by Scholars. Published by Universities.®
- File Type
Articles 1 - 2 of 2
Full-Text Articles in Engineering
Flexible Free-Standing Graphene-Silicon Composite Film For Lithium-Ion Batteries, Jiazhao Wang, Chao Zhong, Shulei Chou, Hua Liu
Flexible Free-Standing Graphene-Silicon Composite Film For Lithium-Ion Batteries, Jiazhao Wang, Chao Zhong, Shulei Chou, Hua Liu
Shulei Chou
Flexible, free-standing, paper-like, graphene-silicon composite materials have been synthesized by a simple, one-step, in-situ filtration method. The Si nanoparticles are highly encapsulated in a graphene nanosheet matrix. The electrochemical results show that graphene-Si composite film has much higher discharge capacity beyond 100 cycles (708 mAh g− 1) than that of the cell with pure graphene (304 mAh g− 1). The graphene functions as a flexible mechanical support for strain release, offering an efficient electrically conducting channel, while the nanosized silicon provides the high capacity.
Enhanced Reversible Lithium Storage In A Nanosize Silicon/Graphene Composite, Shulei Chou, Jiazhao Wang, Mohammad Choucair, Hua Liu, John Stride, S Dou
Enhanced Reversible Lithium Storage In A Nanosize Silicon/Graphene Composite, Shulei Chou, Jiazhao Wang, Mohammad Choucair, Hua Liu, John Stride, S Dou
Shulei Chou
Si/graphene composite was prepared by simply mixing of commercially available nanosize Si and graphene. Electrochemical tests show that the Si/graphene composite maintains a capacity of 1168 mAh g-1 and an average coulombic efficiency of 93% up to 30 cycles. EIS indicates that the Si/graphene composite electrode has less than 50% of the charge-transfer resistance compared with nanosize Si electrode, evidencing the enhanced ionic conductivity of Si/graphene composite. The enhanced cycling stability is attributed to the fact that the Si/graphene composite can accommodate large volume charge of Si and maintain good electronic contact.