Engineering Commons^™

Upgrading Biomass To Bio-Oil: Catalytic Hydrodeoxygenation And Pyrolysis Of Vanillin And Anisole Biomass Model Compounds, Ahmad J. Yaghi

Theses

The purpose of this project is to investigate capacity of selected formulations of catalysts toward the hydrodeoxygenation (HDO) of biomass model compounds in the gas phase with the underlying aim to produce hydrocarbon cuts that can be directly used as transportation fuels. The first part of this project is to devoted to illustrate procedures for the synthesis of potent (HDO) catalysts. Synthesized catalysts encompass nickel (Ni), cobalt (Co) and palladium (Pd) supported on zeolite, cerium oxide (CeO₂) or alumina (Al₂O₃). Various characterization techniques such as X-ray Diffraction (XRD), Temperature Programmed Reduction (TPR) were deployed …

Use Of Photo Isomers To Enhance The Removal Of Lignin From Woody Biomass Hydrolysate, Dipesh J. Karki

Electronic Theses and Dissertations

In this investigation we propose a novel method to enable precipitation of desired solutes using photo-isomers in the extraction solvent. This photo-switchable solvent would enable dissolution or precipitation of desired components using alternating UV or visible light to modify the solubility of the compounds of interest. Three photo-isomers namely native azobenzene, diethoxy azobenzene and diethylamino azobenzene were studied in three different organic solvents: medium chain length alcohol, ethanol and acetone. It was found that among the different combinations of solvent and photo-isomer, acetone and the 4,4’-diethoxy azobenzene solution was most efficient at precipitating dissolved lignin in response to UV light …

Investigation Of Cyclic Gaseous Solvent Injection For Enhanced Oil Recovery In Unconventional Formations, Samuel Asante Afari

Theses and Dissertations

Unconventional resources have been known to hold vast quantities of hydrocarbons. However, exploiting the oil and gas they hold was previously challenging due to their low permeabilities. Recent advances in horizontal well drilling and hydraulic fracturing have enabled oil and gas production from these reservoirs, leading to significant increases in energy supply to meet the growing energy demand. However, despite the relative technological success, considerable obstacles persist; oil production from unconventional wells often declines by more than 20% of their initial production rate within the first two years, leaving significant volumes of residual oil trapped in the formations. This overarching …

Novel Investigation Of Catalytic Hydrogenation And Oxidation Of 1,3-Butadiene, Ali M. Alabedkhalil

Theses

The hydrogenation of 1,3 Butadiene (BD) is an important industrial process that is generally used to generate butene, which is a key feedstock to produce a variety of chemicals such as polymers, plastic, and synthetic rubber. This process involves reacting BD with hydrogen using different metallic Ni-based catalysts. In this study, Ni/Al₂O₃ and Ni/Nb₂O5 catalysts were used and investigated to perform the hydrogenation reaction because of their commercial availability, effective hydrogenation activity, and affordability compared to Platinum Group Metal (PGM) catalysts.

The catalytic reactions were conducted using a quartz tube reactor between a temperature range …

Integrated Experimental And Dft Study Of Palladium And Nickel Metals Supported On Reducible Metallic Oxides For Selective Hydrogenation Of Alkynes And Dienes Bonds, Toyin Daniel Shittu

Dissertations

This dissertation investigates the capacity of ceria (CeO₂) to serve as a stand-alone reactive catalyst, and to act as catalyst support for different catalyst configurations. Experimental and density functional theory (DFT) approach were used to critically predict and to design ceria-containing catalysts. Ceria owes the catalytic propensity to the ability to undergo switch in the oxidation state from the +4 to +3 states. Motivated by experimental studies involving CeO₂ catalysts, defects CeO₂ surface with an oxygen vacancy (CeO2(111)_Vo) was used to explore the decomposition chemistry of methanethiol based on DFT. The potential formation pathways revealed that …

Comparative Analysis Of Artificial Intelligence And Numerical Reservoir Simulation In Marcellus Shale Wells, Arya Maher Sattari

Graduate Theses, Dissertations, and Problem Reports

This dissertation addresses the limitations of conventional numerical reservoir simulation techniques in the context of unconventional shale plays and proposes the use of data-driven artificial intelligence (AI) models as a promising alternative. Traditional methods, while providing valuable insights, often rely on simplifying assumptions and are constrained by time, resources, and data quality. The research leverages AI models to handle the complexities of shale behavior more effectively, facilitating accurate predictions and optimizations with less resource expenditure.

Two specific methodologies are investigated for this purpose: traditional numerical reservoir simulations using Computer Modelling Group's GEM reservoir simulation software, and an AI-based Shale Analytics …

Machine Learning Assisted Framework For Advanced Subsurface Fracture Mapping And Well Interference Quantification, Mohammad Faiq Adenan

Graduate Theses, Dissertations, and Problem Reports

The oil and gas industry has historically spent significant amount of capital to acquire large volumes of analog and digital data often left unused due to lack of digital awareness. It has instead relied on individual expertise and numerical modelling for reservoir development, characterization, and simulation, which is extremely time consuming and expensive and inevitably invites significant human bias and error into the equation. One of the major questions that has significant impact in unconventional reservoir development (e.g., completion design, production, and well spacing optimization), CO2 sequestration in geological formations (e.g., well and reservoir integrity), and engineered geothermal systems (e.g., …

The Effect Of Different Fracturing Fluids On The Productivity Of Multi-Staged Fractured Marcellus Shale Horizontal Wells, Vida Gyaubea Matey-Korley

Graduate Theses, Dissertations, and Problem Reports

While hydraulic fracturing has undeniably improved the production from oil and gas reservoirs, this technology is not without limitations. The primary hurdles lie in the areas of proppant transport, fluid rheology, and stress management. Despite the extensive research conducted in this domain, there remains a considerable amount of work to be done for comprehensive solutions that account for the complex interactions among fracturing fluid, proppant distribution, and geomechanical conditions. Achieving this will then make room for a holistic and efficient hydraulic fracturing strategy.

This study addresses the above-mentioned problem by examining the impact of fluid type on proppant transport and …

Leveraging Artificial Intelligence And Geomechanical Data For Accurate Shear Stress Prediction In Co2 Sequestration Within Saline Aquifers (Smart Proxy Modeling), Munirah Alawadh

Graduate Theses, Dissertations, and Problem Reports

This research builds upon the success of a previous project that used a Smart Proxy Model (SPM) to predict pressure and saturation in Carbon Capture and Storage (CCS) operations into saline aquifers. The Smart Proxy Model is a data-driven machine learning model that can replicate the output of a sophisticated numerical simulation model for each time step in a short amount of time, using Artificial Intelligence (AI) and large volumes of subsurface data. This study aims to develop the Smart Proxy Model further by incorporating geomechanical datadriven techniques to predict shear stress by using a neural network, specifically through supervised …

Investigation Of Recrosslinkable Preformed Particle Gels For Natural Gas Conformance Control, Ali Abdulmohsen Al Brahim

Doctoral Dissertations

"Recross linkable Preformed Particle Gel (RPPG) is a novel type of preformed particle gel in which particles can bond together to form a strong bulk gel system after being placed in the target formation. In this research, I systematically evaluated the feasibility of using this product to improve gas flooding conformance for mature reservoirs with conduits or fractures. Two RPPG systems were used for the experiment: a CO₂- resistant RPPG (CR-RPPG) synthesized using acrylamide (AM) and 2-acrylamide-2- methylpropane sulfonate acid (AMPS), designed for CO2 flooding; and an acrylamide-co-acrylic acid-based RPPG (LT-RPPG), designed for water flooding. Different experimental apparatuses …

Data Analytics Of Wettability Alteration With Surfactants In Carbonate Reservoirs, Ya Yao

Doctoral Dissertations

"Wettability alteration with surfactants has been widely applied to improve oil recovery in carbonate reservoirs. An effective surfactant huff-puff application design requires comprehensive guidelines about where, how, and when this method could be applied. Besides, traditional methods to design an effective application and optimize surfactant performance are dependent on extensive experiments and are time-consuming. This study is to assist in the design of surfactant huff-puff via statistical methods and machine learning techniques.

In this study, a dataset including 402 effective surfactant imbibition tests is established by collecting information from nearly 50 publications. The dataset provides a foundation for further data …

An Artificial Neural Network Approach To Predicting Formation Stress In Multi-Stage Fractured Marcellus Shale Horizontal Wells Based On Drilling Operations Data, Moudhi Alawadh

Graduate Theses, Dissertations, and Problem Reports

The distribution of the anisotropic minimum horizontal stress, both in horizontal and vertical directions, is necessary for effective hydraulic fracture treatment design in Marcellus Shale horizontal wells. Typically, the minimum horizontal stress can be estimated sonic logs. However, sonic log data is not commonly available for the horizontal Marcellus shale wells due to the complexity and cost. The objective of this research is to predict the anisotropic minimum horizontal stress by utilizing drilling parameters including depth, weight-on-bit (WOB), revolution per minute (RPM), standpipe pressure, torque, pump flow rate, and the rate of penetration (ROP). More specifically, artificial neural network (ANN) …

Experimental Investigation Of The Interface And Wetting Characteristics Of Rock-H2-Brine Systems For H2 Geological Storage, Mirhasan Hosseini

Theses: Doctorates and Masters

The projected rise in demand for hydrogen (H2) production is a response to several factors, including greenhouse gas emissions caused by burning fossil fuels, depletion of fossil fuel reserves, and their uneven distribution around the earth. Thus, increased requirement for large-scale hydrogen storage solutions is anticipated to overcome imbalance between energy demand and supply. Deep underground formations such as salt caverns and porous reservoir rocks (e.g., depleted hydrocarbon reservoirs and deep saline aquifers) are necessary to achieve such volumes in practice. This process is known as underground hydrogen storage (UHS) which is technically very similar to underground natural gas storage. …

Analysis Of Plastic Pyrolysis Oil Separation Using Chemcad, Brian Berish, Juliana Mcgaffic

Williams Honors College, Honors Research Projects

Excessive plastic waste is a massive global issue. Plastic pyrolysis is a process of melting plastic in the absence of oxygen to create an wax-oil type substance called pyrolysis oil. This project will use a ChemCAD simulation to perform a distillation of a predetermined plastic pyrolysis oil into usable products. Heat integration will be used to construct a heat exchanger network and estimate utility usage. Sizing and costing of all equipment will be calculated and an overall cost analysis of the completed simulation will be performed to determine the economic viability of plant construction. Market research for potential products will …

Investigations Of A Surrogate Fuel Based On Fischer-Tropsch Gtl And Ctl In Cvcc, Idi And Di Compression Ignition Engines, Amanda C. Weaver

Electronic Theses and Dissertations

With the increase in availability, feedstocks, and properties of alternative fuels, compatibility issues emerge between current engine platforms often requiring a limit on the blend percentage of alternative fuel in conventional fuel or alteration to the engine platform. Two key metrics were identified, autoignition quality and lubrication characteristics, as vital for the proper function of a compression ignition engine, and if the blend of alternative fuels matches these two criteria for the diesel standard, then the resulting blend percentage can be considered as a viable alternative for complete replacement of conventional petroleum ULSD. Autoignition quality was matched using blends S-8, …