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Petroleum Engineering

Theses/Dissertations

2018

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Full-Text Articles in Engineering

Temperature Transient Analysis For Reservoir Characterization, Yilin Mao Dec 2018

Temperature Transient Analysis For Reservoir Characterization, Yilin Mao

LSU Doctoral Dissertations

Recent developments in downhole temperature measurements open new alternatives contributing to reservoir characterization. In this dissertation, novel forward and inverse models to analyze production- and injection-induced temperature signals are developed for conventional and unconventional reservoir applications. Important limitations of the proposed models are addressed by accounting for fluid property variations and complex production strategies.

Forward modeling approaches involve making relevant assumptions that allow rigorous analytical solutions to be constructed using Laplace transform, Method of Characteristics, and control volume analysis. Our results of the analytical models are benchmarked with those from commercial numerical simulation software. Multiple possible scenarios of conventional reservoirs …


An Improved Method To Calculate Gas-Lift Valve Set Pressure And Valve Performance Curves, Khadhr A Kh Altarabulsi Dec 2018

An Improved Method To Calculate Gas-Lift Valve Set Pressure And Valve Performance Curves, Khadhr A Kh Altarabulsi

LSU Doctoral Dissertations

The main objective of this work is toimprove the accuracy on calculations of design set pressure and performance curves (sizing equations) for Gas-Lift Valves (GLVs) at high pressure (real conditions). This improved calculation method is demonstrated to have an important effect on well unloading and production operations.

The analysis of the valve design set pressure includes an experimental evaluation of the effect of internal dome volume changes on the design set pressure due to the presence of silicone and thermal effects. The evaluationis carried out for different levels of GLV silicone fill, pressures and temperatures. Silicone fills covered 7.5, 10, …


Characterization And Evaluation Of Cordless Nailer Performance For Liquid And Gaseous Fuels, Mark Carioscio Oct 2018

Characterization And Evaluation Of Cordless Nailer Performance For Liquid And Gaseous Fuels, Mark Carioscio

Master's Theses (2009 -)

The Paslode Cordless XP Framing Nailer is a combustion-powered nail gun that operates using a fuel blend of a propylene and 1-butene. This tool is designed to drive nails using a piston driven by a combustion reaction. The current fuel blend is able to fire approximately 1200 shots per fuel cartridge and match the energy output of pneumatic, corded nailers on the market. This thesis is written with the intent to gain a better understanding of the operation of the tool and how its performance varies when the fuel source is altered. A bizonal combustion model was created to simulate …


Well-Failure Analysis Of The Devil’S Basin In Musselshell County, Mt., Alexander Koerner Oct 2018

Well-Failure Analysis Of The Devil’S Basin In Musselshell County, Mt., Alexander Koerner

Graduate Theses & Non-Theses

Central Montana’s Devil’s Basin is the home of the first wildcat well in Montana. However, numerous operators have failed to recover economic oil reserves in the nearly 100- year history of the play. Analysis of the geologic conditions within the Devil’s Basin leads to a modern understanding of the charge, reservoir, and trap potentials of the greater Devil’s Basin petroleum play. Primary focus within the play is the Heath and Tyler Formations. Evaluation of previous exploration guides the end narrative of recommendations to direct future production in the Devil’s Basin.

A representative geologic model describing the southeastern portion of the …


Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain Aug 2018

Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain

LSU Doctoral Dissertations

In this study we investigate displacement mechanism for oil recovered using Gas- Assisted Gravity Drainage (GAGD) method. For a typical oil recovery under gravity drainage, the recovery profile can be characterized by an initial bulk flow which occurs rapidly and a later film flow that extends for a longer duration. It is the latter period where film spreading, the ability of oil to spread above water in the presence of gas, is identified as the displacement mechanism responsible for recovering the remaining oil in gravity drainage process. Literature survey indicates that mathematical models for gravity drainage do not account for …


Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain Aug 2018

Investigation Of Flow Mechanisms In Gas-Assisted Gravity Drainage Process, Iskandar Dzulkarnain

LSU Doctoral Dissertations

In this study we investigate displacement mechanism for oil recovered using Gas- Assisted Gravity Drainage (GAGD) method. For a typical oil recovery under gravity drainage, the recovery profile can be characterized by an initial bulk flow which occurs rapidly and a later film flow that extends for a longer duration. It is the latter period where film spreading, the ability of oil to spread above water in the presence of gas, is identified as the displacement mechanism responsible for recovering the remaining oil in gravity drainage process. Literature survey indicates that mathematical models for gravity drainage do not account for …


Modeling Fluid Coker Cyclone Fouling, Erica Glatt Aug 2018

Modeling Fluid Coker Cyclone Fouling, Erica Glatt

Electronic Thesis and Dissertation Repository

Fluid CokingTM is a continuous process that thermally converts heavy hydrocarbons, such as oil-sands bitumen, to lighter and higher-value products by horizontal injection onto a fluidized bed of hot coke particles. The deposition of carbonaceous materials in the cyclone sections of commercial Fluid Cokers has been observed throughout each run. The main objective of this work is to improve unit reliability by proposing cyclone fouling mitigation strategies based on a localized phenomenological model using Aspen Plus®. The heavy ends condensation fouling mechanism was studied by incorporating vapour-liquid thermodynamics, thermal cracking reactions, and overall fluid dynamics in the Fluid Coker. …


Development Strategies For A Fractured, Heavy Oil Reservoir - Results From Numerical Simulations, German Albertovich Abzaletdinov Aug 2018

Development Strategies For A Fractured, Heavy Oil Reservoir - Results From Numerical Simulations, German Albertovich Abzaletdinov

LSU Master's Theses

This research is focused on studying reservoir “N” in the Yarega heavy oilfield (YHOF) for development strategies and production optimization. YHOF is a naturally fractured heavy oil field where only very recently SAGD technology has been introduced. The motivation for this research is derived from the fact that SAGD employed in this field has so far resulted in early steam breakthrough leading to producer abandonment and new drilling, thus increasing costs. This study explores numerically different static and dynamic reservoir characterization models (single porosity versus dual porosity systems), and subsequent pressure-production history matched reservoir simulation for understanding heat and mass …


Experimental And Numerical Investigation Of Liquid-Assisted Gas-Lift Unloading, Renato Peixoto Coutinho Jun 2018

Experimental And Numerical Investigation Of Liquid-Assisted Gas-Lift Unloading, Renato Peixoto Coutinho

LSU Doctoral Dissertations

The case for a unique form of gas-lift unloading, termed “Liquid-Assisted Gas-Lift (LAGL),” is presented. This work demonstrates that the injection of a gas-liquid mixture allows transport of gas to a deep injection point utilizing injection pressure considerably lower than single-phase gas injection. The LAGL is demonstrated in a 2,880 ft deep test well. The test well is kicked-off using an injection pressure that would normally be lower than the pressure for single-point single-phase gas injection at this depth. Experimental results indicate that the LAGL can lower the injection pressure by up to 75%.

This work breaks the LAGL system …


Thermogenic Gas Hydrate Formation In Gulf Of Mexico Offshore Environment- Results From Numerical Simulation, Sulav Dhakal Apr 2018

Thermogenic Gas Hydrate Formation In Gulf Of Mexico Offshore Environment- Results From Numerical Simulation, Sulav Dhakal

LSU Master's Theses

Development of civilization and the resulting quest for energy have led us to previously uncharted territory in exploration and production of fuel. As the demand continues to grow and conventional oil reserves become depleted, we are looking into unconventional resources such as gas hydrates. However, due to the volatile nature of the energy market and production technology yet to perfected, we are not able to fully utilize the potential of gas hydrates yet.

Reservoir characterization of hydrates have so far been limited to seismic mapping, well log interpretation and laboratory scale studies. This research uses numerical simulation to understand the …


Mobility Of Nano-Particles In Rock Based Micro-Models, Jagannath Upadhyay Apr 2018

Mobility Of Nano-Particles In Rock Based Micro-Models, Jagannath Upadhyay

LSU Doctoral Dissertations

A confocal micro-particle image velocimetry (C-μPIV) technique along with associated post-processing algorithms is detailed for obtaining three dimensional distributions of nano-particle velocity and concentrations at select locations of the 2.5D (pseudo 3D) Poly(methyl methacrylate) (PMMA) and ceramic micro-model. The designed and fabricated 2.5D micro-model incorporates microchannel networks with 3D wall structures with one at observation wall which resembles fourteen morphological and flow parameters to those of fully 3D actual reservoir rock (Boise Sandstone) at resolutions of 5 and 10 μm in depth and 5 and 25 μm on plane. In addition, an in-situ, non-destructive method for measuring the geometry of …


Simulating Fluid Flow And Gas Expansion In The Marine Riser Using Computational Fluid Dynamics (Cfd) Software, Ross Teichman Apr 2018

Simulating Fluid Flow And Gas Expansion In The Marine Riser Using Computational Fluid Dynamics (Cfd) Software, Ross Teichman

Honors Theses

No abstract provided.


Integrated Stratigraphic Controls For Flow Simulation Of The Wall Creek Member Of Frontier Formation: Western Powder River Basin, Wyoming, Tuan Le Apr 2018

Integrated Stratigraphic Controls For Flow Simulation Of The Wall Creek Member Of Frontier Formation: Western Powder River Basin, Wyoming, Tuan Le

Graduate Theses & Non-Theses

The Frontier Formation in the Powder River Basin has been re-discovered for oil and gas potential with the development of long horizontal wells and multi-stage hydraulic fracturing. Over the last decade, the Upper Cretaceous Wall Creek Member (WCM) of the Frontier Formation has proven to be a successful hydrocarbon-producing target, yet a full understanding of the flow behavior in this complex stratigraphic unit has not been fully achieved.

The fluid and rock properties have uncertainty and are not well defined due to the low permeability rocks. This study aims to describe the fluid flow behaviors of these features and create …


Pore-Scale Analysis Of Interfacial Instabilities And Impact Of Heterogeneity On Relative Permeability By Lattice Boltzmann Method, Zhipeng Zhu Mar 2018

Pore-Scale Analysis Of Interfacial Instabilities And Impact Of Heterogeneity On Relative Permeability By Lattice Boltzmann Method, Zhipeng Zhu

LSU Master's Theses

Interfacial instabilities occur often during immiscible fluid flow through porous media and their understanding is essential for waterflooding operations or other oil recovery processes. Although many studies including experimental and numerical have been done to reproduce and analyze the interfacial instabilities in porous median, there is still significant knowledge gap in fundamental understanding of these flow instabilities at the pore-scale. In order to better understand the interfacial instabilities phenomenon, the pore-scale simulations are performed. In this study, Lattice Boltzmann Method is used to simulate two different types of interfacial instabilities: viscous fingering and capillary fingering in irregular sphere packs by …


Magnetic Gradient Drilling, Garrett Lowry Nielsen Mar 2018

Magnetic Gradient Drilling, Garrett Lowry Nielsen

LSU Master's Theses

The drilling industry has always had difficulties with staying within the mud weight window. The problems associated with failure to stay within the mud weight window include uncontrolled influxes and wellbore collapse on the low pressure side of the window, and fluid losses and wellbore damage on the high pressure side of the window. When the risk for getting outside of this mud window becomes too great, casing must be set in order to isolate formations from each other. If too many strings of casing are set, or if the damage from getting out of the mud weight window is …


Effect Of Pipe Rotation On Casing Pressure Within Mpd Applications, Zahrah Ahmed Al Marhoon Mar 2018

Effect Of Pipe Rotation On Casing Pressure Within Mpd Applications, Zahrah Ahmed Al Marhoon

LSU Master's Theses

Well control is one of the most crucial sectors in drilling engineering. Human lives and safety depend on the correct execution of the engineering design. Managed Pressure Drilling (MPD) is a new technology that has recently emerged in the oil and gas industry. It has special well control abilities supported by the RCD to continue drilling or carry operations that involve pipe rotation, while circulating out a gas kick. This thesis examines the effect of pipe rotation on casing pressure profiles within MPD kick circulation application. The analysis was carried on real scale kick experiments. These experiments were carried in …


Optimization Of A New Array Noise Tool; Analysis & Interpretation Of Case Studies Of Down- Hole Leak Detection, Moustafa Mahmoud Hassan Ismail Mar 2018

Optimization Of A New Array Noise Tool; Analysis & Interpretation Of Case Studies Of Down- Hole Leak Detection, Moustafa Mahmoud Hassan Ismail

Theses

This thesis is concerned with the optimization and analysis of new array noise tools. Various lab and field case studies are analyzed to test the capabilities and determine the optimum operating conditions of the new tool for leak detection purposes. The purpose of this study is to optimize the logging procedure of real-time array noise tool, selecting adequate gain parameters and frequency band in the processing phase, and to analyze the data acquired through multiple labs and field tests. The study methodology involved the following steps:

1. Performing lab and field tests for the tool in a range of different …


Image-Based Modeling Of Flow Through Porous Media: Development Of Multiscale Techniques For The Pore Level, Timothy Wayne Thibodeaux Jan 2018

Image-Based Modeling Of Flow Through Porous Media: Development Of Multiscale Techniques For The Pore Level, Timothy Wayne Thibodeaux

LSU Doctoral Dissertations

Increasingly, imaging technology allows porous media problems to be modeled at microscopic and sub-microscopic levels with finer resolution. However, the physical domain size required to be representative of the media prohibits comprehensive micro-scale simulation. A hybrid or multiscale approach is necessary to overcome this challenge. In this work, a technique was developed for determining the characteristic scales of porous materials, and a multiscale modeling methodology was developed to better understand the interaction/dependence of phenomena occurring at different microscopic scales. The multiscale method couples microscopic simulations at the pore and sub-pore scales. Network modeling is a common pore-scale technique which employs …


Solvent And Concentration Effects Governing The Hierarchical Organization Of Asphaltenes: A Small-Angle X-Ray Scattering Study, Hasan Rejoanur Rahman Jan 2018

Solvent And Concentration Effects Governing The Hierarchical Organization Of Asphaltenes: A Small-Angle X-Ray Scattering Study, Hasan Rejoanur Rahman

Open Access Theses & Dissertations

Asphaltenes are a group of planar molecules found in crude oil and are prone to aggregation which often causes blockage of pipes along the oil production stream resulting a huge economic downside. In an effort to understand the hierarchical organization of asphaltene in different solvents and concentrations, the solution structure of various asphaltene solutions were studied using small-angle x-ray scattering (SAXS). Solvents were chosen based on miscibility maps. Such maps are generated on the critical value of the solubility parameter difference between asphaltenes or asphaltene components, and a range of solvents. The critical factors that affect asphaltene and asphaltene component …


Understanding Inhibition Of A Biodesulfurization Enzyme To Improve Sulfur Removal From Petroleum, Yue Yu Jan 2018

Understanding Inhibition Of A Biodesulfurization Enzyme To Improve Sulfur Removal From Petroleum, Yue Yu

Theses and Dissertations--Chemical and Materials Engineering

The biodesulfurization 4S-pathway is a promising complementary enzymatic approach to remove sulfur from recalcitrant thiophenic derivatives in petroleum products that remain from conventional hydrodesulfurization method without diminishing the calorific value of oil. The final step of this pathway involves the carbon-sulfur bond cleavage from HBPS, and the production of the final products 2-hydroxybiphenyl (HBP) and sulfite, has been recognized as the rate-limiting step, partially as a result of product inhibition. However, the mechanisms and factors responsible for product inhibition in the last step have not been fully understood. In this work, we proposed a computational investigation using molecular dynamic simulations …


Conical Folds -- An Artifact Of Using Simple Geometric Shapes To Describe A Complex Geologic Structure, Avery Joseph Welker Jan 2018

Conical Folds -- An Artifact Of Using Simple Geometric Shapes To Describe A Complex Geologic Structure, Avery Joseph Welker

Masters Theses

"Accurate representation of the 3D shapes of natural folds is essential to characterization of the dynamic models for fold formation. Geometrical analysis of folds commonly relies upon analyzing patterns defined by the variation in the orientation of poles to planar surfaces deformed by a shortening event when plotted using graphical calculators (e.g., stereogram, polar tangent diagrams) to interpret the shape of folds. Stereograms for which orientation data define small circles are classified as non-cylindrical regular folds and are interpreted as "conical folds," where the shape of the fold is represented by a cone that terminates at a point. Utilizing similar …


Geomechanical Characterizations And Correlations To Reduce Uncertainties Of Carbonate Reservoir Analysis, Farqad Hadi Jan 2018

Geomechanical Characterizations And Correlations To Reduce Uncertainties Of Carbonate Reservoir Analysis, Farqad Hadi

Doctoral Dissertations

"Although carbonate reservoirs hold a wealth of hydrocarbon, they are among the most difficult types of reservoirs to be characterized. Carbonate reservoirs by nature have complex depositional environments and diagenetic processes in which brittle, ductile, fractured rocks, and vugular pores may all exist within small interval. This huge variance in the rock mechanical properties can cause challenges in the reservoir's development, especially in applications related to geomechanics.

The main objective of this research is to geomechanically characterize and correlate the carbonate mechanical properties with their petrophysical properties. A comprehensive review for the geomechanical-petrophysical properties of carbonates was conducted from previous …


Effectiveness Of Ammonium Ion In Low Salinity Waterflooding In Shaly-Sandstone Reservoir, Hung Vu Quoc Jan 2018

Effectiveness Of Ammonium Ion In Low Salinity Waterflooding In Shaly-Sandstone Reservoir, Hung Vu Quoc

Chulalongkorn University Theses and Dissertations (Chula ETD)

In this study was presented the pre-feasibility study of silica sand processing plant in Sihanoukville province. The resources approximately 8,750,000 tons, would be a high potential deposit for the glass industry. In this study focuses on the characteristics of the silica sand, methodology to remove the impurities which contained high Fe2O3, Al2O3 and another major oxide element, and economic evaluation technique. To identification of silica sand which used sieve analysis, Frantz isodynamic magnetic separator following by electrical microscope, XRD, and XRF. Therefore, to upgrade the quality of silica sand, which is using Shaking Table, Wet High-Intensity Magnetic Separator, and Reverse …


Pre-Feasibility Study Of Silica Sand Processing Plant In Sihanoukville Province, Cambodia, Sochea Ros Jan 2018

Pre-Feasibility Study Of Silica Sand Processing Plant In Sihanoukville Province, Cambodia, Sochea Ros

Chulalongkorn University Theses and Dissertations (Chula ETD)

Nowadays, bottom ash and flue gas desulfurization (FGD) gypsum are by-products of the coal combustion process from coal-fired power plant. Bottom ash has been applied in many applications such as landfill, cement industry etc., and FGD gypsum is applied in cement and wallboard industry. Also, they can be used in agricultural activities for soil amendment but the amount of bottom ash and FGD used in this function is still low. Furthermore, biochar has long been used to improve soil fertility. The positive impacts of biochar amendment on soils are that it can increase soil capacity to adsorb plant nutrients, decrease …


Removal Of Mixed Vocs Of Benzene, Toluene, And Xylene By Using Catalytic Corona Discharge System, Issaree Tantiprapa Jan 2018

Removal Of Mixed Vocs Of Benzene, Toluene, And Xylene By Using Catalytic Corona Discharge System, Issaree Tantiprapa

Chulalongkorn University Theses and Dissertations (Chula ETD)

Silver (Ag) and Manganese (Mn) catalysts were loaded on TiO₂ and Al₂O₃ supports on quartz wool that were tested for the oxidation of mixed Volatile Organic Compounds (VOCs) of benzene, toluene, and xylene in nonthermal plasma corona discharge. The total feed concentration of VOCs was fixed at 100 ppm. The catalyst located between the pin and plate electrodes with a constant gap distance of 15 mm and the pin and plate plasma reactor had an inside diameter of 9 mm. The outlet stream was analyzed by gas chromatography equipped with TCD and FID detectors. The operating parameters including applied voltage, …


Kinetics Study For Fischer-Tropsch Synthesis Over Cobalt Catalyst By Kinetic Monte-Carlo Simulation, Nuttawut Pugingna Jan 2018

Kinetics Study For Fischer-Tropsch Synthesis Over Cobalt Catalyst By Kinetic Monte-Carlo Simulation, Nuttawut Pugingna

Chulalongkorn University Theses and Dissertations (Chula ETD)

Kinetic Monte-Carlo simulation was utilized to study the kinetic behaviors of C₁ and C₂ formation in the Fischer-Tropsch synthesis over the cobalt surface by varying reaction conditions. Two reaction models: the carbide mechanism and the CO insertion mechanism were applied to this simulation. The production rates and fractional coverages of each adsorbed species could be calculated under the steady state. Moreover, the combination between carbide and CO insertion mechanism was also studied to suggest the possibility of each reaction mechanism, and compared the results with the reported experimental results under the same conditions. It was ob-served that the C–C bond …


การเตรียมฟิล์มพอลิพิร์โรลบนแผ่นทองแดงโดยวิธีการพอกพูนด้วยไฟฟ้า, ธิดา คุณสมบัติ Jan 2018

การเตรียมฟิล์มพอลิพิร์โรลบนแผ่นทองแดงโดยวิธีการพอกพูนด้วยไฟฟ้า, ธิดา คุณสมบัติ

Chulalongkorn University Theses and Dissertations (Chula ETD)

งานวิจัยนี้ศึกษาการเตรียมฟิล์มพอลิพิร์โรล (Polypyrrole) บนแผ่นทองแดงโดยเทคนิคการพอกพูนด้วยกระแสไฟฟ้า (Electrodeposit) เพื่อทดสอบผลต่อความสามารถในการป้องกันการกัดกร่อนและค่าการนำไฟฟ้าของแผ่นทองแดงที่ผ่านการเคลือบ ศึกษาตัวแปร คือ ค่าความหนาแน่นกระแสไฟฟ้า เวลาในการพอกพูน และปริมาณผงคาร์บอน รวมถึงขนาดและรูปแบบของช่องทางการไหลของแก๊ส พบว่าชิ้นงานที่เคลือบด้วยฟิล์มพอลิพิร์โรลที่ได้จากการเตรียมในสารละลายอิเล็กโทรไลต์โดยใช้กรดโดเดซิลเบนซีนซัลโฟนิก และพอลิพิร์โรล ความเข้มข้น 0.05 และ 0.15 โมลต่อลิตร ตามลำดับ ที่ภาวะต่างกัน พบว่าที่ภาวะความหนาแน่นกระแสไฟฟ้าที่ 12.7 มิลลิแอมแปร์ต่อตารางเซนติเมตร เป็นระยะเวลา 10 นาที มีประสิทธิภาพการป้องกันการกัดกร่อนและค่าการนำไฟฟ้าที่ได้ดีที่สุด แต่เมื่อมีการเติมคาร์บอนวัลแคน 13.3 มิลลิกรัมต่อลิตร พบว่าสามารถนำไฟฟ้าได้มากขึ้นถึง 338 ซีเมนต์ต่อเซนติเมตร และป้องกันการกัดกร่อนได้ดีขึ้นถึง 0.030 มิลลิเมตรต่อปี และมีค่าความต้านทานเชิงสัมผัสเท่ากับ 0.090 มิลลิโอห์มตารางเซนติเมตร หลังจากนั้นศึกษาการเคลือบพอลิพิร์โรลบนแผ่นทองแดงที่เซาะร่อง 2 รูปแบบ คือ รูปแบบขนาน และรูปตัวยู พบว่ากระบวนการเคลือบนี้สามารถเคลือบแผ่นทองแดงที่มีการเซาะร่องได้ทั้งสองแบบรูปแบบ โดยประสิทธิภาพการป้องกันการกัดกร่อนของแผ่นทองแดงเคลือบดีขึ้น แต่ค่าการนำไฟฟ้าลดลง โดยเฉพาะการเซาะร่องแบบตัวยู


Using Artificial Intelligence And Machine Learning To Develop Synthetic Well Logs, Marwan Mohammed Alnuaimi Jan 2018

Using Artificial Intelligence And Machine Learning To Develop Synthetic Well Logs, Marwan Mohammed Alnuaimi

Graduate Theses, Dissertations, and Problem Reports

There has been an increase in the need for energy in the recent past. Oil and gas stand as the source of energy that are widely used. The oil and gas reservoirs are targeted for the purposes of field development. The conventional methods of reservoir characteristics require computing techniques that are unique and complex, some of which are labor and time intensive. Mohaghegh argues that all efforts must be tried and made possible to apply Petroleum Data analytics in production and management of reservoir so as to earn a maximum return (Mohaghegh, Shale Analytics, 2017). Different methodologies have been applied …


การแยกแก๊สผสมไนโตรเจน/เฮกเซน/1-บิวทีนด้วยเมมเบรนคอมพอสิตไคโตซาน, ภาณุวัฒน์ ภาวิไล Jan 2018

การแยกแก๊สผสมไนโตรเจน/เฮกเซน/1-บิวทีนด้วยเมมเบรนคอมพอสิตไคโตซาน, ภาณุวัฒน์ ภาวิไล

Chulalongkorn University Theses and Dissertations (Chula ETD)

งานวิจัยนี้ได้ศึกษาการแยกแก๊สผสมไนโตรเจน/เฮกเซน/1-บิวทีนด้วยเมมเบรน คอมพอสิตไคโตซานที่ผสมผสานเทคนิคการเตรียม 4 รูปแบบ ได้แก่ 1) การเติมอนุภาคซีโอไลต์ชนิด 4A ปริมาณร้อยละ 0, 1 และ 5 โดยน้ำหนักของไคโตซาน 2) การปรับความหนาของชั้นฟิล์มไคโตซาน 100 และ 50 ไมครอน 3) การใช้วัสดุฐานรองเป็นผ้าสปันบอนด์ชนิดพอลิโพรพิลีนและพอลิเอสเตอร์ และ 4) การเชื่อมขวางเมมเบรนคอมพอสิตด้วยสารละลายกรดซัลฟิวริก นอกจากนั้นยังได้ศึกษาผลการสะสมของตัวเร่งปฏิกิริยาชนิดไตรเอทิลอลูมินัม (TEAL) ที่ใช้ในกระบวนการผลิตพอลิเอทิลีนด้วยเทคโนโลยี CX บนเมมเบรนคอมพอสิตไคโตซานต่อสมรรถนะการแยกแก๊ส จากการศึกษาพบว่าเมมเบรนคอมพอสิตไม่เชื่อมขวางที่มีความหนาของชั้นฟิล์มไคโตซานหนา 100 ไมครอน ผสมผงซีโอไลต์ 4A ปริมาณร้อยละ 1 โดยน้ำหนัก และใช้วัสดุฐานรองผ้าสปันบอนด์ชนิดพอลิโพรพิลีน มีค่าแฟกเตอร์การแยกแก๊สสูงถึง 2.08±0.06 สำหรับคู่แก๊สไนโตรเจน/เฮกเซน และ 1.28±0.10 สำหรับคู่แก๊สไนโตรเจน/1-บิวทีน ในขณะที่ค่าความสามารถในการซึมผ่านแก๊สเท่ากับ 5127±745 แบร์เรอร์ เมื่อใช้อุณหภูมิดำเนินการ 10 องศาเซลเซียส ความดันแก๊สผสมขาเข้า เมมเบรน 4 บาร์ ความดันฝั่งเพอมิเอตเป็นความดันบรรยากาศ (1 บาร์) ความเข้มข้นเฮกเซนและ 1-บิวทีน ในแก๊สผสมเป็นร้อยละ 0.50 และ 4.50 โดยปริมาตร ตามลำดับ แต่ประสิทธิภาพในการแยกแก๊สของเมมเบรนจะลดลงเมื่อได้รับ TEAL และสูญเสียความสามารถในการแยกแก๊สเมื่อถูกแช่ในสารละลาย TEAL ที่ความเข้มข้นร้อยละ 5 โดยน้ำหนัก เป็นเวลา 24 ชั่วโมง


Effects Of Monovalent Ions On Low Salinity Waterflooding In Shaly-Sandstone Reservoir, Ativish Yomchan Jan 2018

Effects Of Monovalent Ions On Low Salinity Waterflooding In Shaly-Sandstone Reservoir, Ativish Yomchan

Chulalongkorn University Theses and Dissertations (Chula ETD)

Multi-component Ion Exchange (MIE) was proved to be a major mechanism occurred during Low Salinity Waterflooding (LSWF). Reduction of both total salinity and concentration of divalent ions of injected water together with a presence of monovalent ion results in dissolution of divalent ions linking between rock surface and oil. As a consequence, oil is liberated from rock surface. This study aims to study effects of monovalent ions in MIE mechanism. Stirring test is performed and results show that ion with less hydration radius tends to be more active in MIE; hence, potassium ion and cesium ion illustrate potential in oil …