Engineering Commons^™

Effect Of Liquid-Solid Contact On Thermal Cracking Of Heavy Hydrocarbons In A Mechanically Fluidized Reactor, Mitesh C. Chaudhari

Electronic Thesis and Dissertation Repository

The aim of the thesis was to study the effect of liquid-solid contact on the thermal cracking of heavy hydrocarbons carried out in Fluid Cokers. The research has been carried out using a Mechanically Fluidized Reactor (MFR) in which the operating conditions of the Fluid Coking^TM reactions can be simulated and monitored. The first part of the research, aimed at investigating the effect of agitation on liquid-solid contact, which was carried out by changing the rotation speed of the agitator of the MFR for both non-reactive as well as for reactive systems. In both situations, it was observed that …

Pvt Study Of Selected Uae Reservoir Fluids, Rashid Sher Mohammad

Theses

Phase behavior modeling in crude oil includes prediction of thermodynamic properties (such as saturation pressure, density, viscosity, thermal conductivity, etc.) for the vapor and liquid phases. The aim of phase behavior modeling is to establish the accuracy and reliability of the developed equation of state model to predict various other fluid phase behavior properties at high pressure and temperature conditions.

In the first part of this work, a new and reliable phase behavior apparatus designed in Brazil was used for the two-stage recombination process and phase behavior measurements. The recombination of the surface sample fluids (first-stage separator gas and stock-tank …

Simultaneous Particle Agglomeration And Attrition In A High Temperature Fluidized Bed, Mithun Saha

Electronic Thesis and Dissertation Repository

Fluid Coking^TM is a major refining process to upgrade heavy crude oil or bitumen from oil sands. In Fluid Coking^TM bitumen is atomized with steam and sprayed inside a high temperature fluidized bed of coke particles where it thermally cracks into smaller molecules. Fluid Coking^TM is a carbon rejection process as solid carbon residues are formed during fragmentation into lighter hydrocarbon vapors. New coke deposits over existing coke particles and, consequently, the particle size increases. In addition, particles agglomeration occurs when the injected liquid does not disperse uniformly on individual hot coke particles but reaches, instead, local …

Optimization Of Co2 Wag Processes In A Selected Carbonate Reservoir: Laboratory Study, Mohamed Elwy Abdalla Amin

Theses

Miscible gas flooding using carbon dioxide is currently investigated as a possible EOR process for a number of United Arab Emirates (UAE) reservoirs. The major factors affecting the implementation of CO₂ floods are the availability of CO₂ at economic prices and the net utilization ratio of CO₂ per barrel of additional oil recovered.Minimizing net utilization requires controlling the high mobility ratio which causes lower sweep. To control the mobility ratio, the Water-Alternating CO₂-gas (WAG) technique is proposed.

The objective of this work is to experimentally assess the recovery of oil with CO₂ injection in …

Liquid Distribution From Industrial Scale Spray Jets In Fluidized Beds, Mohammadali Zirgachianzadeh

Electronic Thesis and Dissertation Repository

Liquid injections via spray nozzles are used in fluidized bed reactors such as Fluid Cokers. In such industrial processes, in order to maximize the product yields it is required to optimize the performance of the nozzle. Moreover parts of the bed might become defluidized, bogged, due to high liquid load. Then optimizing the performance of the nozzle and local bed bogging detection is the primary research objectives for this thesis work.

The first part of the research work was focused on developing a novel method employing electrical conductance to characterize the liquid distribution in a large scale fluid bed of …

Gas To Liquids (Gtl), Andrew David Hix, Mark Moore, Rachel Kendall, Rachel Svoboda, William Maningas

Chancellor’s Honors Program Projects

No abstract provided.

Developing Novel Methods To Characterize Liquid Dispersion In A Fluidized Bed, Masoumeh Farkhondehkavaki

Electronic Thesis and Dissertation Repository

The performance of several important industrial processes, such as fluid coking or fluid catalytic cracking, is dependent on the good distribution of liquid feed sprayed into a fluidized bed of hot inert or catalytic particles, respectively.

Liquid injected into a fluidized bed is distributed in three different ways: (i) free moisture, or liquid coating individual particles; (ii) wet micro-agglomerates, which are fluidized; and (iii) wet macro-agglomerates, which settle to the bottom of the bed. This study develops and evaluates various methods for the determination of this moisture.

In the study using electrical techniques, two different kinds of electrodes geometries are …

Supercritical Co2 Extraction Of Oil From Henna Flower: Experimental, Mathematical Modeling, And Antioxidant Activity, Bushra Saeed Mohammed Dohai

Theses

Henna is a plant that has been used traditionally for coloring nail, skin, and hair, and as medicinal plant. The supercritical fluid technology offers a considerable promise as extraction media due to its advantages over other conventional extraction techniques. The extraction of volatile components from flowers of henna was studied using supercritical carbon dioxide at temperatures and pressures ranging from 35 to 55°C and 80 to 120 bar, respectively. A maximum extraction yield of 31 % from 2g of henna flowers was obtained at 45 °C and 120 bar. The composition of the extracts was investigated by gas chromatography technique. …

Surfactant Enhanced Oil Recovery By Wettability Alteration In Sandstone Reservoirs, Omar Elmofty

Masters Theses

"Recovering more oil from existing oil reservoirs using enhanced oil recovery methods holds the key for meeting future energy demands. Even though wettability is a cornerstone in oil recovery, few studies have focused on increasing oil recovery in sandstone reservoirs through wettability alteration. The objective of this thesis is to prove that altering the wettability of a sandstone rock to preferentially water-wet condition will reduce the remaining oil saturation and thus increase the percentage of recovered oil.

Two commercial surfactants were selected after studying both the phase behavior and the interfacial properties of 30 surfactants with oil and 1.00% sodium …

Investigation Of Wellbore Stability In A North Sea Field Development, Steven Austin Hilgedick

Doctoral Dissertations

"Planning drilling operations is key to the development of oil and natural gas fields. As part of well design, wellbore stability and pore pressure analysis are main factors in determining the safe operating window for selecting mud density. The motivation for this research was to conduct wellbore stability based on exploration wells as basis for planning new offshore field developments with deviated and horizontal wells. A second objective was to investigate the use of a probabilistic approach to wellbore stability, and compare it to the conventional deterministic methods, in order to evaluate the value of including a probabilistic approach to …

Numerical Study Of Downhole Heat Exchanger Concept In Geothermal Energy Extraction From Saturated And Fractured Reservoirs, Yin Feng

LSU Doctoral Dissertations

Geothermal energy has gained a lot of attention recently due to several favorable aspects such as ubiquitously distributed, renewable, low emission resources while leveraging the advances in the associated technologies such as directional drilling and low enthalpy power generation plant. However, there are still many challenges such as the high initial capital cost of drilling and surface facilities, environmental risk of seismicity due to the induced disequilibrium in the formation, and sustainability of project over designed operational life. Traditional downhole heat exchangers (DHE) could potentially reduce the capital cost and the risk of seismicity, but they are unable to maintain …

A Methodology For Statistical Propped Fracture Treatment Design In Fluvial Environments, Prue Elizabeth Smith

Doctoral Dissertations

"Treatment design for hydraulic fracturing historically has been deterministic in nature. In a deterministic design, required variables can be determined and are assumed to be laterally continuous. This is difficult for geologic settings in general, but nearly impossible in fluvial geologic environments where the second assumption is violated.

Recent work has employed statistical methods to account for the complexity and heterogeneity in fluvial environments. Statistical design tools have been used to assist with improving the design process in complex fluvial geologic systems. Currently, the statistical design tools must be created using a "trial and error" process, which requires first completing/fracturing …

Updated Eor Screening Criteria And Modeling The Impacts Of Water Salinity Changes On Oil Recovery, Ahmad Aladasani

Doctoral Dissertations

"Developing technologies for enhanced oil recovery (EOR) from existing oil fields would supply the world's energy needs for several decades. The application of EOR in many major oil-producing countries remains in its conceptual stage. Thermal and gas EOR methods achieve high incremental rates; however, their application range has not broadened significantly as they have matured, while the rate at which new, promising EOR methods such as Low-salinity water flooding (LSWF) are being implemented is alarming. Despite, the potential of LSWF its development and application has been hindered by the lack of consensus concerning its recovery mechanism(s). Every oil reservoir has …

Numerical Simulations Of Fracture Propagation And Sealing: Implications For Wellbore Strengthening, Saeed Salehi

Doctoral Dissertations

"To mitigate the small tolerance between pore pressure and fracture gradients an engineering practice referred to as "wellbore strengthening" is conducted to increase the fracture gradient. The method relies on propping and/or sealing the fractures with specially designed materials. Different competing theories exist for physical wellbore strengthening mechanisms which can be categorized into two groups. The first group explains that strengthening happens as a result of increasing wellbore hoop stress when fractures are sealed while the second group emphasis is on fracture tip isolation with suitable materials and enhancing fracture propagation pressure. The numerical models and lab experiments …

Modeling Carbon Sequestration In Transition Zone To Optimize Storage Potential, Fang Yang

Doctoral Dissertations

"Shallow aquifers are potential candidates for carbon sequestration because of their wide distribution and low injection cost. Injected CO₂ in a shallow region segregates into two zones according to CO₂ phases within the initial reservoir pressure and the maximum bottom hole pressure: gas zone and transition zone. Transition zone is a better option because of favorable CO₂ properties. This work investigated the CO₂ storage potential in transition zone using the compositional simulator CMG-GEM and a design of experiment software iSIGHT. First, it addressed the basic characteristics of CO₂ sequestration in transition zone, and then modeled CO₂ injection with simultaneous water …

Development Of A Shared Earth Model To Investigate Potential For Carbon Dioxide Sequestration In The Springfield Area, Mo, Imowo Celestine Akpan

Masters Theses

"Carbon dioxide (C0₂) sequestration has been extensively implemented and explored predominantly in depleted oil reservoirs and deep saline aquifers where the C0₂ is stored under supercritical conditions. A lesser explored option with great potential is based on injection into shallow reservoirs where the C0₂ may not always be in its denser supercritical state. The research evaluates the potential for injecting C0₂ into saline aquifers at depths of ~550-650 meters and formation temperatures of -22⁰C.

To evaluate injectivity and cap rock integrity, reservoir and geomechanical simulations need to be conducted separately and subsequently coupled. A Shared Earth Model is developed utilizing …

Hydraulic Fracturing Experiments To Investigate Circulation Losses, Maximiliano Liberman

Masters Theses

"In recent years the oil and gas industry has been drilling more challenging wells due to long deviated wells, drilling through already depleted reservoirs, sub salt wells and increasing water depth. A major challenge these wells create is to prevent fluid loss into the formation and wellbore breakouts by having accurately determined the mud weight operational window. In addition to accurately determine the fracture gradient, additives in the drilling fluid have been used to enhance the fracture gradient in an industry process named wellbore strengthening. In order to study the phenomenon of fracture gradient alteration, a hydraulic fracturing apparatus was …

Evaluation Of The Reagan And Lamotte Sandstones In Southwestern Missouri For Carbon Dioxide Sequestration, Todd Jeffrey Miller

Masters Theses

"Carbon dioxide sequestration has been proposed as a way to reduce anthropogenic carbon dioxide emissions. Several characteristics are required in order for a geologic formation to be suitable for sequestration. There must be an impermeable confining layer to restrain CO₂ migration toward the surface, the porosity and permeability must be high enough to allow for long term injection and substantial storage capacity, and the formation must be strong enough for long term injection to occur without inducing fractures. In this work, The Reagan and Lamotte Sandstones near Springfield, Missouri were evaluated for the potential for carbon dioxide sequestration. The Derby-Doe …

Investigation Of Geosteering In Non-Trivial Geological Settings, Anuroop Pandey

Masters Theses

"The well placement technology has advanced to a stage where we can explore small tolerance targets such as thin reservoirs. Well placement with geosteering, which is the real time adjustment of the well path based on the geological responses to place and maintain the well within the best part of the reservoir, is the technology that has made this progress possible. Geosteering however can get very complex with the increasing heterogeneities of the formations and there is no fixed methodology to devise a steering strategy in such complex geological settings. To accommodate this challenge, we investigated three methods to verify …

Geomechanical Characterization Of Reservoir & Cap Rocks For Co₂ Sequestration, Sudarshan Govindarajan

Masters Theses

"Geological sequestration of CO₂ has been identified as one method to reduce global emissions of CO₂ and achieve lower levels of CO₂ concentrations in the atmosphere. Geological formations have to be assessed in terms of their capacity, sealing capabilities and economic feasibility before CO₂ sequestration can commence. Potential leakage of injected CO₂ from the reservoir formation could occur due to natural or injection induced faults or fractures in the reservoir or sealing formations. As part of a potential leakage investigation a geomechanical characterization which refers to the assessment of the in-situ stress conditions, rock strength and stiffness properties of the …

Direct Shear Testing Of Fractured Rocks From Missouri Used To Evaluate Potential Fault Reactivation Induced By Carbon Dioxide Sequestration, Ishan Kumar

Masters Theses

"Geological storage projects of CO₂ are designed to maintain secure storage for thousands of years. Carbon Capture and Storage has been identified as one of the methods which is used to reduce global emission of CO₂ and achieve lower concentration of CO₂ in the atmosphere by capturing the CO₂ from the flue gases and storing it in underground formations. Potential leakage of injected CO₂ from the reservoir to the surface is caused by the reactivation of pre-existing faults and fractures which is caused by the change in the state of stresses and the pore pressure. To avoid damage to the …

Investigation Of Drillstring Vibration Reduction Tools, Mohammed Fayez Al Dushaishi

Masters Theses

"Drilling related problems such as drillstring vibration is an important cause of premature failure of drillstring components and drilling inefficiency. The vibration of drillstring interferes with measurement collected while drilling. In severe cases, drillstring vibration will lead to wellbore instability that will result in an increase in the operation cost. In the late 1980's, a lot of studies and techniques were developed to mitigate drillstring vibration and downhole vibration measurements were introduced to the industry in two forms; real time measurements and memory devices measurements

A study of drillstring vibration of three different wells located in the Norwegian North Sea …

Risk Of Well Integrity Failure Due Sustained Casing Pressure, Koray Kinik

LSU Master's Theses

Sustained casing pressure (SCP) is considered a well integrity problem. The approach of this study is to look at SCP as environmental risk due hydrocarbon release. Currently, the risk is qualified by the value of surface pressure (Pcsg) that may cause failure of casing head. However, the resulting rate of gas emission to the atmosphere is not considered. Also not considered is a possibility of breaching the casing shoe due transmission of Pcsg downhole. The objective of this study is to develop methods for maximum possible air emission rates (MER) and risk of subsurface well integrity failure due SCP. Mathematical …

Effect Of Surfactants And Brine Salinity And Composition On Spreading, Wettability And Flow Behavior In Gas-Condensate Reservoirs, Yu Zheng

LSU Doctoral Dissertations

The well-known condensate blockage problem causes severe impairment of gas productivity as the flowing bottom-hole pressure falls below the dew point in gas-condensate reservoirs. Hence, this study attempts to investigate the concept of modifying the spreading coefficient and wettability using low-cost surfactants in the near wellbore region, to prevent the gas flow problems associated with condensate buildup. This study also examines the effect of brine salinity and composition on wettability, spreading and adhesion in condensate buildup regions, to evaluate the ability of brine salinity/composition for enhanced gas productivity in gas-condensate reservoirs. In this study, experiments were performed at both ambient …

An Experimental And Theoretical Critique Of Flow Model Accuracy, Shannon Ray Chollett

LSU Master's Theses

In today’s exploration and production environment it is required that engineers must collect and use vast amounts of data for flow model construction and calibra- tion, as well as reservoir estimation and optimization. With modern technology, the data volume can be overwhelming. It is necessary that data monitoring and calibration are highly efficient. It is also essential that physical and mathematical models can be tested in repeatable, inexpensive experiments. The experiments described in this thesis will develop and perform verification of algorithms and can generate prior geomodels, collect and process seismic refraction data, collect and process production data, and calibrate …

Experimental Investigations In Co2 Sequestration And Shale Caprock Integrity, Abiola Olukola Olabode

LSU Master's Theses

More than sixty percent (60%) of conventional hydrocarbon reservoirs which are potential CO2 repositories are sealed by tight shale caprock. The geochemical reactivity of shale caprock during CO2 diffusive transport needs to be included in the reservoir characterization of potential CO2 sequestration sites as slow reactive transport processes can either strengthen or degrade seal integrity over the long term. Several simulation results had predicted that influx-induced mineral dissolution/precipitation reactions within shale caprocks can continuously reduce micro-fracture networks, while pressure and effective-stress transformation first rapidly increase then progressively constrict them. This experimental work applied specific analytical techniques in investigating changes in …

Measurement Of Interfacial Tension In Hydrocarbon/Water/Dispersant Systems At Deepwater Conditions, Mohamed Abdelrahim

LSU Master's Theses

The events of the Deepwater Horizon oil spill in the Gulf of Mexico were associated with great water depths that made it difficult to understand the behavior of the spilled oil as it came in contact with the seawater. The remedial subsea application of chemical dispersants draws interest to evaluate the interfacial interactions between the oil and water at such great water depths. Most importantly, a quantification of the interfacial tension (IFT) between the spilled oil and seawater at deepwater conditions can provide insight into the effectiveness of the chemical dispersion of spilled oil. In this study, Macondo crude oil …

Strategies For Real Time Reservoir Management, Yuanyuan Shuai

LSU Doctoral Dissertations

Real–time reservoir management is developed to manage a shrinking labor force and rising demand on energy supply. This dissertation seeks good strategies for real–time reservoir management. First, two simulator–independent optimization algorithms are investigated: ensemble–based optimization (EnOpt) and bound optimization by quadratic approximation (BOBYQA). Multiscale regularization is applied to both to find appropriate frequencies for well control adjustment. Second, two gathered EnKF methods are proposed to save computational cost and reduce sampling error: gathered EnKF with a fixed gather size and adaptively gathered EnKF. Finally, oil price uncertainty is forecasted and quantified with three price forecasting models: conventional forecasting, bootstrap forecasting …

A Review Of Offshore Blowouts And Spills To Determine Desirable Capabilities Of A Subsea Capping Stack, Louise Matilde Smith

LSU Master's Theses

The events surrounding the Deepwater Horizon disaster have changed the face of deepwater operations. In order to continue drilling in the Gulf of Mexico, the regulatory body, the Bureau of Safety and Environmental Enforcement (BSEE), has required that applications to conduct work in the Gulf of Mexico (GOM) include a plan to stop, capture, or contain any uncontrolled release of fluids. The capping and containment systems built and implemented by BP during the event are an excellent starting point for minimizing pollution from deepwater subsea blowouts, but the system has limitations. The industry recognizes these limits but is currently focused …

Simulations Of The Primary Cement Placement In Annular Geometries During Well Completion Using Computational Fluid Dynamics (Cfd), Muhammad Zulqarnain

LSU Master's Theses

Effective zonal isolation during primary cementing is only possible when drilling mud in the annulus is completely displaced with cement, while the spacers aid in this process. During the displacement process the rheological properties of fluids used and the operating conditions control the motion of different fluids interfaces; desired stable interfacial displacement leads to piston like motion. Computational Fluid Dynamics (CFD) tool with the Volume-of-Fluid (VOF) has been validated against experimental and used to conduct numerical experiments in a virtual well model consisting of 50 ft vertical section of 8.765" x 12.5" annulus having initially mud and this mud is …