Engineering Commons^™

Host-Guest Interaction Dictated Selective Adsorption And Fluorescence Quenching Of A Luminescent Lightweight Metal-Organic Framework Toward Liquid Explosives, Dan Liu, Xiaojuan Liu, Yongxin Liu, Yang Yu, Fanglin Chen, Cheng Wang

Faculty Publications

In this article, we report the successful preparation of a Mg-based luminescent MIL-53 metal–organic framework (MOF), namely [Mg2(BDC)2(BPNO)]·2DMF (1) (BDC = 1,4-benzene dicarboxylate, BPNO = 4,4’- dipyridyl-N,N’-dioxide, DMF = N,N-dimethylformamide) in a mixed solvent containing a 2 : 3 volume ratio of DMF and ethanol (EtOH) under solvothermal conditions. Desolvated compound 1a can be used as an absorbent for selective adsorption and separation of liquid explosives, including nitroaromatic (nitrobenzene (NB)) and nitroaliphatic (nitromethane (NM) and nitroethane (NE)) compounds, through single crystal-to-single crystal (SC–SC) transformations. As one of the weakly luminescent MOFs, the luminescence of compound 1a could be quenched by …

Capillarity And Two-Phase Fluid Transport In Media With Fibers Of Dissimilar Properties, Thomas M. Bucher Jr.

Theses and Dissertations

Capillarity is a physical phenomenon that acts as a driving force in the displacement of one fluid by another within a porous medium. This mechanism operates on the micro and nanoscale, and is responsible for countless observable events. This can include applications such as absorption in various hygiene products, self-cleaning surfaces such as water beading up and rolling off a specially-coated windshield, anti-icing, and water management in fuel cells, among many others.

The most significant research into capillarity has occurred within the last century or so. Traditional formulations for fluid absorption include the Lucas–Washburn model for porous media, which is …