Engineering Commons^™

Near-Infrared Surface-Enhanced Fluorescence Using Silver Nanoparticles In Solution, Michael D. Furtaw

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Fluorescence spectroscopy is a widely used detection technology in many research and clinical assays. Further improvement to assay sensitivity may enable earlier diagnosis of disease, novel biomarker discovery, and ultimately, improved outcomes of clinical care along with reduction in costs. Near-infrared, surface-enhanced fluorescence (NIR-SEF) is a promising approach to improve assay sensitivity via simultaneous increase in signal with a reduction in background. This dissertation describes research conducted with the overall goal to determine the extent to which fluorescence in solution may be enhanced by altering specific variables involved in the formation of plasmonactive nanostructures of dye-labeled protein and silver nanoparticles …

Flow-Induced Crystallization Of Isotactic Polypropylene And Random Polyethylene-Polypropylene Copolymers, Frederic Aubin

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Flow-induced crystallization (FIC) has been investigated for decades but the effect of molecular characteristics that hinder crystallization—such as the presence of random comonomers— on FIC remains scarcely explored. Flow greatly enhances crystallization kinetics and can induce the formation of highly oriented morphologies that affect final properties (i.e. stiffness, permeability, thermal conductivity, elastic modulus, etc.). Therefore, understanding FIC remains particularly important for developing predictive models to allow optimization of processing techniques involving flows.

Polypropylene represents ~ 40% of the global polyolefin production. The addition of ethylene comonomer allows their use as engineering plastics because of their particular toughness and flexibility. This …

Zone Of Intrusion For Permanent 9.1-Degree Single Slope Concrete Barriers, Cale J. Stolle

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Three WDOT 9.1-degree single-slope concrete barriers, with top heights of 36 in. (914 mm), 42 in. (1,067 mm), and 56 in. (1,422 mm) (Standard 14B32), were analyzed for Zone of Intrusion (ZOI)’ and working width using nonlinear finite element analysis (FEA). Tire-barrier friction, vehicle-barrier friction, barrier stiffness, mesh size, tire deflation, and suspension component failures were all found to have effects on simulation results. The zone of intrusion and working width were evaluated for each barrier under varying tire deflation and suspension failure conditions and determined to have a maximum value of 12.2 in. (310 mm) for the front fender …