Engineering Commons^™

Experimental And Computational Study Of Determining Mass Transport Parameters In Vanadium Redox Flow Batteries, Tugrul Y. Ertugrul

Doctoral Dissertations

Vanadium redox flow batteries are a promising large-scale energy storage technology, but a number of challenges must be overcome for commercial implementation. At the cell level, mass transport contributes significantly to performance losses, limiting VRFB performance. Therefore, understanding mass transport mechanisms in the electrode is a critical step to mitigating such losses and optimizing VRFBs.

In this study, mass transport mechanisms (e.g. convection, diffusion) are investigated in a VRFB test bed using a strip cell architecture, having 1 cm² active area. It is found that diffusion-dominated cells have large current gradients; convection-dominated cells have relatively uniform current distribution from …

The Microchannel Flow Of A Micropolar Fluid, Guohua Liu

Doctoral Dissertations

Micro-channel flows have been computed to investigate the influence of Navier-Stokes formulation for the slip-flow boundary condition, and a micro-polar fluid model, respectively.

The results of the slip boundary condition show that the current methodology is valid for slip-flow regime (i.e., for values of Knudsen number less than approximately 0.1). Drag reduction phenomena apparent in some micro-channels can be explained by slip-flow theory. These results are in agreement with some computations and experiments.

An ad hoc micro-polar fluid model is developed to investigate the influence of micro effects, such as micro-gyration, in micro-scale flows. The foundation of the ad hoc …