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Full-Text Articles in Engineering
Electrochemical Impedance Spectroscopy Analysis Of Corrosion Of Reinforcing Steel In Fly Ash Mortar By Means Of Transmission Line Modeling, Padraig Stack
Williams Honors College, Honors Research Projects
Electrochemical impedance spectroscopy (EIS) is an important non-destructive tool that allows for a deeper understanding of the electrochemical processes and mechanisms occurring in an electrochemical cell. Equivalent electrical circuits (EECs) are used to model the impedance data into electrical components, such as resistors and capacitors, on a circuit. Current potentiostat offers software packages that can analyze the frequency response, but the software only supports “simple” EEC that can be written as fixed electrical components in some combination of series and parallel. Park and Macdonald propose a transmission line model (TLM) that does not use lumped-element models, instead, the values of …
Effect Of Sintering Temperature On Microstructure, Corrosion Behavior, And Hardness Of Nanocrystalline Al-5at.%Ni And Al-5at.%V Alloys, Matthew G. Wachowiak
Effect Of Sintering Temperature On Microstructure, Corrosion Behavior, And Hardness Of Nanocrystalline Al-5at.%Ni And Al-5at.%V Alloys, Matthew G. Wachowiak
Williams Honors College, Honors Research Projects
The purpose of this project was to investigate thermal stability of high energy ball milled Al-5at.%Ni and Al-5at.%V alloys. Characterization was done by analyzing grain size and solid solubility. Samples were created using high energy ball milling, cold compaction to 3 GPa, and sintering from 100 °C to 500 °C at 100 °C increments, as well 450 °C and 614 °C. Microstructure, mechanical properties, and corrosion properties were determined using scanning electron microscopy, energy dispersive x-ray spectroscopy, x-ray diffraction, hardness testing, and cyclic potentiodynamic polarization. Vickers hardness of Al-5at.%Ni decreased with increasing temperature. For Al-at.%V, hardness increased with sintering temperature …