Engineering Commons^™

Metastability And Degradation In Cu(In,Ga)Se2 Thin-Film Solar Cells, Mohsen Jahandardoost

UNLV Theses, Dissertations, Professional Papers, and Capstones

Cu(In,Ga)(S,Se)2 or CIGS is a thin-film semiconductor that has shown a device efficiency of 23.35% and 24.2% for single-junction and perovskite/CIGS tandem solar cells, respectively. CIGS offers promising properties such as tunable bandgap and ease of processing making them great candidates for thin-film tandem devices. However, knowledge of the effect of material defects, buffer materials, and post-deposition treatment (PDT) on degradation and metastability behavior in these devices is not well understood.In this dissertation, metastability and long-term degradation of CIGS thin-film solar cells have been investigated under combinatorial stress factors of heat, light, and voltage bias to systematically understand the effect …

Spectroscopic Investigation Of The Chemical And Electronic Properties Of Chalcogenide Materials For Thin-Film Optoelectronic Devices, Kimberly Horsley

UNLV Theses, Dissertations, Professional Papers, and Capstones

Chalcogen-based materials are at the forefront of technologies for sustainable energy production. This progress has come only from decades of research, and further investigation is needed to continue improvement of these materials.

For this dissertation, a number of chalcogenide systems were studied, which have applications in optoelectronic devices, such as LEDs and Photovoltaics. The systems studied include Cu(In,Ga)Se2 (CIGSe) and CuInSe2 (CISe) thin-film absorbers, CdTe-based photovoltaic structures, and CdTe-ZnO nanocomposite materials. For each project, a sample set was prepared through collaboration with outside institutions, and a suite of spectroscopy techniques was employed to answer specific questions about the system. These …