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Full-Text Articles in Engineering

Secondary Organic Aerosol Formation And Organic Nitrate Yield From No3 Oxidation Of Biogenic Hydrocarbons, Juliane L. Fry, Danielle C. Draper, Kelley C. Barsanti, James N. Smith, John Ortega, Paul M. Winkler, Michael J. Lawler, Steven S. Brown, Peter M. Edwards, Ronald C. Cohen, Lance Lee Sep 2014

Secondary Organic Aerosol Formation And Organic Nitrate Yield From No3 Oxidation Of Biogenic Hydrocarbons, Juliane L. Fry, Danielle C. Draper, Kelley C. Barsanti, James N. Smith, John Ortega, Paul M. Winkler, Michael J. Lawler, Steven S. Brown, Peter M. Edwards, Ronald C. Cohen, Lance Lee

Civil and Environmental Engineering Faculty Publications and Presentations

The secondary organic aerosol (SOA) mass yields from NO3 oxidation of a series of biogenic volatile organic compounds (BVOCs), consisting of five monoterpenes and one sesquiterpene (α-pinene, β-pinene, Δ-3-carene, limonene, sabinene, and β-caryophyllene), were investigated in a series of continuous flow experiments in a 10 m3 indoor Teflon chamber. By making in situ measurements of the nitrate radical and employing a kinetics box model, we generate time-dependent yield curves as a function of reacted BVOC. SOA yields varied dramatically among the different BVOCs, from zero for α-pinene to 38−65% for Δ-3-carene and 86% for β-caryophyllene at mass loading of 10 …


Quantifying The Impacts Of Initial Condition And Model Uncertainty On Hydrological Forecasts, Caleb Matthew Dechant May 2014

Quantifying The Impacts Of Initial Condition And Model Uncertainty On Hydrological Forecasts, Caleb Matthew Dechant

Dissertations and Theses

Forecasts of hydrological information are vital for many of society's functions. Availability of water is a requirement for any civilization, and this necessitates quantitative estimates of water for effective resource management. The research in this dissertation will focus on the forecasting of hydrological quantities, with emphasis on times of anomalously low water availability, commonly referred to as droughts. Of particular focus is the quantification of uncertainty in hydrological forecasts, and the factors that affect that uncertainty. With this focus, Bayesian methods, including ensemble data assimilation and multi-model combinations, are utilized to develop a probabilistic forecasting system. This system is applied …