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Full-Text Articles in Engineering
Radiation Response From A Novel Uo2 Crystal, Stephan A. Varga
Radiation Response From A Novel Uo2 Crystal, Stephan A. Varga
Theses and Dissertations
The radiation response of a novel, single-crystalline UO2 sample was analyzed using several types of radiation. The crystal was exposed to alpha, gamma, and neutron radiation under various environmental conditions and the electronic response of the crystal was measured using a pulse shape discrimination algorithm. The distributions of pulse amplitude (Vmax) and pulse decay times (τ) were used to compare the output. This research revealed that the crystal radiation response is exceptionally sensitive to surface conditions, specifically humidity, which tends to alter the time dependent currents resulting from the radiation interactions. The pulse τ can be made to …
Surface Oxidation Study Of Uranium Dioxide Under Wet And Dry Conditions, Gary T. Brett
Surface Oxidation Study Of Uranium Dioxide Under Wet And Dry Conditions, Gary T. Brett
Theses and Dissertations
The surface oxidation of pressed uranium dioxide (UO2) powder under controlled environmental conditions and the oxidation and reduction of pressed uranium trioxide (UO3) powder are presented. This is a continuing research project in the investigation of the oxidation of UO2 powder using Photoluminescence (PL) Spectroscopy. UO2 particles exposed to the ambient atmosphere will oxidize into a number of chemical complexes (specifically hydrates, hydroxides, and carbonates). During certain of these oxidation processes, the uranium ion can lose two of its electrons and change from uranous (UIV+) to uranyl (UVI+). This research …
Theoretical Comparison Of The Excited Electronic States Of The Linear Uranyl (Uo22+) And Tetrahedral Uranate (Uo42-) Ions Using Relativistic Computational Methods, Eric V. Beck
Theses and Dissertations
This thesis examines the ground and excited electronic states of the uranyl (UO2+) and uranate (UO42-) ions using Hartree-Fock self-consistent field (HF SCF), multi-configuration self-consistent field (MCSCF) and multi-reference single and double excitation configuration interaction (MR- CISD) methods. The MR-CISD SD calculation included spin-orbit operators. Molecular geometries were obtained from self-consistent field (SCF ) second-order perturbation theory (MP2), and density functional theory (DFT) geometry optimizations using the NWChem 4.01 massively parallel ab initio software package. COLUMBUS version 5.8 was used to perform in-depth analysis on the HF SCF MCSCF and MR-CISD potential energy surfaces. Excited …