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Nanoscience and Nanotechnology

Donald Heiman

Selected Works

Nanoparticles

Publication Year

Articles 1 - 2 of 2

Full-Text Articles in Engineering

Tuning The Magnetostructural Phase Transition In Ferh Nanocomposites, Radhika Barua, Xiujuan Jiang, Felix Jiménez-Villacorta, J. Shield, D. Heiman, L. Lewis Aug 2013

Tuning The Magnetostructural Phase Transition In Ferh Nanocomposites, Radhika Barua, Xiujuan Jiang, Felix Jiménez-Villacorta, J. Shield, D. Heiman, L. Lewis

Donald Heiman

Effects of nanostructuring on the magnetostructural response of the near-equiatomic FeRh phase were investigated in nanocomposite materials synthesized by rapid solidification and subsequent annealing of an alloy of nominal atomic composition (FeRh)5Cu95. Transmission electron microscopy studies confirm attainment of a phase-separated system of nanoscaled (∼10–15 nm diameter) precipitates, consistent with FeRh embedded in a Cu matrix. These nanoprecipitates are crystallographically aligned with the coarse-grained Cu matrix and possess an L10-type (CuAu 1) structure, in contrast to the B2 (CsCl)-type structure of bulk FeRh. It is proposed that the face-centered cubic crystal structure of the …


Large Coercivity In Nanostructured Rare-Earth-Free Mnₓga Films, Don Heiman, Tom Nummy, Steve Bennett, Tom Cardinal Oct 2012

Large Coercivity In Nanostructured Rare-Earth-Free Mnₓga Films, Don Heiman, Tom Nummy, Steve Bennett, Tom Cardinal

Donald Heiman

The magnetic hysteresis of MnₓGa films exhibit remarkably large coercive fields as high as μₒHC=2.5 T when fabricated with nanoscale particles of a suitable size and orientation. This coercivity is an order of magnitude larger than in well-ordered epitaxial film counterparts and bulk materials. The enhanced coercivity is attributed to the combination of large magnetocrystalline anisotropy and ~50-100 nm size nanoparticles. The large coercivity is also replicated in the electrical properties through the anomalous Hall effect. The magnitude of the coercivity approaches that found in rare-earth magnets, making them attractive for rare-earth-free magnet applications.