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Full-Text Articles in Engineering

Investigation Of Control Parameters, Strategies, And Transport Modeling For Effective Electrokinetic Nanoparticle Treatment Of Cementitious Materials, Huayuan Zhong Nov 2021

Investigation Of Control Parameters, Strategies, And Transport Modeling For Effective Electrokinetic Nanoparticle Treatment Of Cementitious Materials, Huayuan Zhong

Doctoral Dissertations

Various deleterious chemical species (including sulfates, chlorides, and others) contaminate concrete structures which are inherently porous and thus suffer from compromised durability. Several technologies have been developed for repairing concrete or enhancing the service life. Nevertheless, their efficiency, practicability, and cost can vary widely. Compared with chemical grout, fiber wrap, and traditional repair technology, electrokinetic nanoparticle treatment (EN) has been found to provide remarkable benefits for strength restoration and mitigation of durability problems via porosity reduction. Nanoparticle instability and over dosage issues can arise and lead to problems during treatments. In many cases, these treatment processes have been accompanied by …


Thermoelectric Transport In Disordered Organic And Inorganic Semiconductors, Meenakshi Upadhyaya Jul 2021

Thermoelectric Transport In Disordered Organic And Inorganic Semiconductors, Meenakshi Upadhyaya

Doctoral Dissertations

The need for alternative energy sources has led to extensive research on optimizing the conversion efficiency of thermoelectric (TE) materials. TE efficiency is governed by figure-of-merit (ZT) and it has been an enormously challenging task to increase ZT > 1 despite decades of research due to the interdependence of material properties. Most doped inorganic semiconductors have a high electrical conductivity and moderate Seebeck coefficient, but ZT is still limited by their high lattice thermal conductivity. One approach to address this problem is to decrease thermal conductivity by means of alloying and nanostructuring, another is to consider materials with an inherently low …


Designing Transition Metal Chalcogenides Electrocatalyst Surfaces For High-Efficiency Water Oxidation, Umanga De Silva Jan 2021

Designing Transition Metal Chalcogenides Electrocatalyst Surfaces For High-Efficiency Water Oxidation, Umanga De Silva

Doctoral Dissertations

”The rising demand for energy security and reducing fossil fuel dependence has prompted researchers to search for a clean, sustainable, and efficient energy generation system with low environmental impact. Water electrolysis has been identified as one of the most important processes satisfying the above needs to generate hydrogen as a clean fuel. Two half-cell reactions of oxygen evolution reaction (OER) at the anode and hydrogen evolution reaction (HER) at the cathode comprise the main process of water electrolysis. However, the oxygen evolution reaction is the most crucial step for efficient water splitting. Traditionally, metal oxides have been utilized as catalysts …