Engineering Commons^™

Anion Grain-Boundary Diffusion In Soidum Chloride, K. S. Sabharwal, J. Mimkes, Manfred Wuttig

Materials Science and Engineering Faculty Research & Creative Works

The grain-boundary diffusion of 131I in Harshaw pure and Ca-doped NaCl was investigated in the temperature range between 430 and 560°C. The Arrhenius plot of the grain-boundary diffusivity parameter Dδ displays a marked dip at around 510°C. It is proposed that this dip is due to a phase transformation occurring at the grain boundary, possibly calcium segregation.

Analogy Between Spinodal Decomposition And Martensitic Transformation, Tetsuro Suzuki, Manfred Wuttig

Physics Faculty Research & Creative Works

The translation of the theory developed for the spinodal decomposition of a supercooled alloy to the language appropriate for the martensitic transformation is carried out. In the spinodal theory, the stability of the alloy with respect to the composition fluctuation is examined, while in the present theory the stability of the crystal with respect to the shear displacement fluctuation, the transverse phonon, is studied. The analogy to the spinodal theory requires the revival of the strain gradient energy term or the couple stress term, the presence of which has been a subject of controversies for a long time since Laval. …

Mechanism Of Uai3 To Uai4 Transformation, Ling Ping Lee, Hollis P. Leighly

Materials Science and Engineering Faculty Research & Creative Works

The compound, UA14, which forms during the peritectic reaction (Liquid + UA13 → UAI4), has a long needlelike shape and reveals the characteristic morphology of a fishtail when cut along the long axis. When cut perpendicular to the long axis, it shows an internal core of another phase, which has been identified as a primary aluminum solid solution. Because of the interesting relationship between the crystallographic structures of UA13 and UA14, the peculiar UA14 morphology can be explained on the basis of a proposed mechanism. The mechanism of UA13 to UA14 transformation has been identified as shear and diffusion controlled …

Application Of Voltammetry To Copper Electrodeposition, Louis Francis Toth Jr.

Doctoral Dissertations

"A study was undertaken to determine the feasibility of using voltammetry and scanning electron microscopy techniques to characterize copper deposition from an acid-sulfate electrolyte. The main process variables investigated were temperature and addition agents (chloride ion, glue, separan or thiourea) at different concentrations, over a range of current densities. Cathodes employed were either polycrystalline titanium or copper. Some long-time copper deposits were also made using Ti cathodes and the orientations of these deposits were determined by x-ray diffraction.

Observations of copper crystals produced during voltammetry scans, on a Ti cathode, indicated that a characteristic morphology was associated with each type …

Corrosion And Electrochemical Behavior Of Indium And Indium-Bismuth Alloys In Hydrochloric Acid, Yar Ming Wang

Doctoral Dissertations

"The corrosion of In-Bi alloys was studied using X-ray, scanning electron microscopy, atomic absorption spectroscopy, and cyclic voltammetry techniques.

Calculated activation energy values indicated that the corrosion of In-Bi alloys was activation controlled. The effect of amine mixtures on the corrosion of In and In₂Bi (ß₁ phase) was studied. Morphological studies revealed that the porosity of the resulting physical surface structure was influential in determining the corrosion rate. In deaerated 3N HCl solutions, the selective dissolution of indium was the predominant mechanism in the corrosion of In-Bi alloys. The corrosion was always accompanied by a phase change …

Variables Affecting The Rate Of Solution Of Mold Inoculants In Cast Iron, Jose Osorno Fonnegra

Masters Theses

"The purpose of this investigation was to measure the effectiveness of an inoculant alloy reacting with molten cast iron in a reaction chamber properly located in the gating system.

The chemical composition of the gray iron was held constant while several metallurgical factors were varied to produce test samples with different cementite thicknesses. These chill depths were measured as an indication of the inoculation effectiveness.

Appreciable differences in chilling tendency were observed within the different variables studied. The results indicate that pouring temperature, as well as the other variables studied, are of considerable importance when dealing with inoculation of gray …