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Mechanics of Materials

2009

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Full-Text Articles in Engineering

Method Of Transferring Strained Semiconductor Structure, Michael Nastasi Dec 2009

Method Of Transferring Strained Semiconductor Structure, Michael Nastasi

Department of Mechanical and Materials Engineering: Faculty Publications

The transfer of strained semiconductor layers from one substrate to another substrate involves depositing a multilayer structure on a substrate having surface contaminants. An interface that includes the contaminants if formed in between the deposited layer and the substrate. Hydrogen atoms are introduced into the structure and allowed to diffuse to the interface. Afterward, the deposited multilayer structure is bonded to a second substrate and is separated away at the interface, which results in transferring a multilayer structure from one substrate at least one strained semiconductor layer and at least one strain-induced seed layer. The strain-induced seed layer can be …


Imprinting Polymerfilm On Patterned Substrate, Li Tan, Yen-Peng Kong, Stella W. Pang, Albert F. Yee Nov 2009

Imprinting Polymerfilm On Patterned Substrate, Li Tan, Yen-Peng Kong, Stella W. Pang, Albert F. Yee

Department of Mechanical and Materials Engineering: Faculty Publications

A method of applying a pattern on a topography includes first applying a polymer film to an elastormer member, such as PDMS, to form a pad. The pad is then applied to a substrate having a varying topography under pressure. The polymer film is transferred to the substrate due to the plastic deformation of the polymer film under pressure compared to the elastic deformation of the PDMS member pulls away from the polymer layer, thereby depositing the polymer layer, thereby depositing the polymer layer upon the substrate.


Waves In Inhomogeneous Solids, Arkadi Berezovski, Mihhail Berezovski, Juri Engelbrecht Aug 2009

Waves In Inhomogeneous Solids, Arkadi Berezovski, Mihhail Berezovski, Juri Engelbrecht

Publications

The paper aims at presenting a numerical technique used in simulating the propagation of waves in inhomogeneous elastic solids. The basic governing equations are solved by means of a finite-volume scheme that is faithful, accurate, and conservative. Furthermore, this scheme is compatible with thermodynamics through the identification of the notions of numerical fluxes (a notion from numerics) and of excess quantities (a notion from irreversible thermodynamics). A selection of one-dimensional wave propagation problems is presented, the simulation of which exploits the designed numerical scheme. This selection of exemplary problems includes (i) waves in periodic media for weakly nonlinear waves with …


Flexible Electronics Using Ion Implantation To Adhere Polymer Substrate To Single Crystal Silicon Substrate, Terry L. Alford, Douglas C. Thompson Jr., Hyunchul Kim, Michael A. Nastasi, James W. Mayer, Daniel Adams Jun 2009

Flexible Electronics Using Ion Implantation To Adhere Polymer Substrate To Single Crystal Silicon Substrate, Terry L. Alford, Douglas C. Thompson Jr., Hyunchul Kim, Michael A. Nastasi, James W. Mayer, Daniel Adams

Department of Mechanical and Materials Engineering: Faculty Publications

An electronic apparatus uses a single crystalline silicon Substrate disposed adjacent to a flexible substrate. The electronic apparatus may be a flexible flat panel display, or a flexible printed circuit board. The flexible substrate can be made from polymer, plastic, paper, flexible glass, and stainless steel. The flexible substrate is bonded to the single crystalline substrate using an ion implantation process. The ion implantation process involves the use of a noble gas Such as hydrogen, helium, Xenon, and krypton. A plurality of semiconductor devices are formed on the single crystalline silicon Substrate. The semi conductor devices may be thin film …


Performance Analysis Of Coal-Fired Boiler And Natural Gas Fired Boiler At Morehead State University, Devender Banne May 2009

Performance Analysis Of Coal-Fired Boiler And Natural Gas Fired Boiler At Morehead State University, Devender Banne

Morehead State Theses and Dissertations

A thesis presented to the faculty of the College of Science & Technology at Morehead State University in partial fulfillment of the requirements for the Degree of Master of Science by Devender Banne on May 4, 2009.


Droplet Assisted Self-Assembly Of Semiconductor Nanostructures, Kimberly Annosha Sablon May 2009

Droplet Assisted Self-Assembly Of Semiconductor Nanostructures, Kimberly Annosha Sablon

Graduate Theses and Dissertations

There is increasing interest in quantum dot (QD) structures for a plethora of applications, including optoelectronic devices, quantum computing and energy harvesting. While strain driven surface diffusion via stranski-krastanow (SK) method has been commonly used to fabricate these structures, a more recent technique, droplet epitaxy (DE) does not require mismatch strain and is therefore much more flexible in the combination of materials utilized for the formation of QDs.

As reported in this work, a hybrid approach that combines DE and SK techniques for realizing lateral ordering of QDs was explored. First, the droplet formation of various materials was discussed and …


Multiscale Modeling Of Impact On Heterogeneous Viscoelastic Solids With Evolving Microcracks, Flavio V. Souza Apr 2009

Multiscale Modeling Of Impact On Heterogeneous Viscoelastic Solids With Evolving Microcracks, Flavio V. Souza

Department of Engineering Mechanics: Dissertations, Theses, and Student Research

Multiscale computational techniques play a major role in solving problems related to viscoelastic composite materials due to the complexities inherent to these materials. In the present work, a numerical procedure for multiscale modeling of impact on heterogeneous viscoelastic solids containing evolving microcracks is proposed in which the (global scale) homogenized viscoelastic incremental constitutive equations have the same form as the local scale viscoelastic incremental constitutive equations, but the homogenized tangent constitutive tensor and the homogenized incremental history dependent stress tensor depend on the amount of damage accumulated at the local scale. Furthermore, the developed technique allows the computation of the …


Effect Of Steam Environment On Creep Behavior Of Nextel720/Alumina-Mullite Ceramic Matrix Composite At Elevated Temperature, Tolga Kutsal Mar 2009

Effect Of Steam Environment On Creep Behavior Of Nextel720/Alumina-Mullite Ceramic Matrix Composite At Elevated Temperature, Tolga Kutsal

Theses and Dissertations

The tensile creep behavior of an oxide-oxide ceramic matrix composite (CMC) was investigated at 1000 and 1100° C in laboratory air and steam. The oxide-oxide CMC studied in this research was Nextel™ 720/alumina-mullite (N720/AM). The composite consists of N720/fibers with 0°/90° fiber orientation and a porous alumina-mullite matrix. Tensile-strain behavior was investigated and tensile properties measured at 900, 1000 and 1100° C. The effect of loading rate on tensile properties of N720/AM ceramic matrix composite at 1100° C in steam was also examined. Creep-rupture tests were performed at 1100° C in laboratory air and steam, and at 1000° C only …


A Finite Element Evaluation Of An Experiment Related To Coating Damping Properties, Armando Deleon Mar 2009

A Finite Element Evaluation Of An Experiment Related To Coating Damping Properties, Armando Deleon

Theses and Dissertations

Typically turbine engine blades gain protection from thermal damage by the use of hard coatings, such as magnesium aluminate spinel. Known as Thermal Barrier Coatings (TBC's), they have material properties that include several nonlinearities. These TBC's create damping primarily due to their nonlinear dissipation of energy. In order to effectively represent their damping properties, it is necessary to create a method which combines experimentation and analysis. Previous work has shown the need for a beam bounded and loaded in such a fashion that external support energy dissipation functions i.e. boundary conditions and aerodynamics are eliminated. Thus, a new experimental apparatus …


Effects Of Prior Aging At 316°C In Argon On Inelastic Deformation Behavior Of Pmr-15 Polymer At 316°C: Experiment And Modeling, Ozgur Ozmen Mar 2009

Effects Of Prior Aging At 316°C In Argon On Inelastic Deformation Behavior Of Pmr-15 Polymer At 316°C: Experiment And Modeling, Ozgur Ozmen

Theses and Dissertations

The inelastic deformation behavior of PMR-15 neat resin, a high-temperature polymer, was investigated at 316 deg C. The experimental program was designed to explore the influence of strain rate on tensile loading, unloading, and strain recovery behaviors. In addition, the effect of the prior strain rate on the relaxation response of the material, as well as on the creep behavior following strain controlled loading were examined. The material exhibits positive, nonlinear strain rate sensitivity in monotonic loading and unloading. Early failures occur in the inelastic regime. The recovery of strain at zero stress and creep response are strongly affected by …


Thermomechanical Properties Of Center-Reinforced Aluminum, Geofrey S. Cox Mar 2009

Thermomechanical Properties Of Center-Reinforced Aluminum, Geofrey S. Cox

Theses and Dissertations

The rule of mixture approach was shown to produce an accurate theoretical prediction of the room temperature elastic modulus values when compared to the experimental results. The laminate's modulus value remained relatively constant over the -55C to 80C temperature range, indicating stable behavior despite temperature changes. Blunt notch tests also revealed that the laminate's strength was not significantly reduced due to the presence of small holes. Finally, fatigue testing demonstrated that the laminate retains its stiffness properties throughout its fatigue life, until failure.


The Effect Of Silicon Content On Impact Toughness Of T91 Grade Steels, Ajit K. Roy, Pankaj Kumar, Debajyoti Maitra Mar 2009

The Effect Of Silicon Content On Impact Toughness Of T91 Grade Steels, Ajit K. Roy, Pankaj Kumar, Debajyoti Maitra

Mechanical Engineering Faculty Research

The impact resistance of silicon (Si)-containing modified 9Cr-1Mo steels has been investigated within a temperature regime of -40 to 440°C using the Charpy method. The results indicate that the energies absorbed in fracturing the tested specimens were substantially lower at temperatures of -40, 25, and 75°C compared to those at elevated temperatures. Lower impact energies and higher ductile-to-brittle-transition-temperatures (DBTTs) were observed with the steels containing 1.5 and 1.9 wt.% Si. The steels containing higher Si levels exhibited both ductile and brittle failures at elevated temperatures. However, at lower temperatures, brittle failures characterized by cleavage and intergranular cracking were observed for …


Convergence, Adaptive Refinement, And Scaling In 1d Peridynamics, Florin Bobaru Ph.D., Mijia Yabg Ph.D., Leonardo F. Alves M.S., Stewart A. Silling Ph.D., Ebrahim Askari Ph.D., Jifeng Xu Ph.D. Jan 2009

Convergence, Adaptive Refinement, And Scaling In 1d Peridynamics, Florin Bobaru Ph.D., Mijia Yabg Ph.D., Leonardo F. Alves M.S., Stewart A. Silling Ph.D., Ebrahim Askari Ph.D., Jifeng Xu Ph.D.

Department of Engineering Mechanics: Faculty Publications

We introduce here adaptive refinement algorithms for the non-local method peridynamics, which was proposed (in J. Mech. Phys. Solids 2000; 48:175–209) as a reformulation of classical elasticity for discontinuities and long-range forces. We use scaling of the micromodulus and horizon and discuss the particular features of adaptivity in peridynamics for which multiscale modeling and grid refinement are closely connected. We discuss three types of numerical convergence for peridynamics and obtain uniform convergence to the classical solutions of static and dynamic elasticity problems in 1D in the limit of the horizon going to zero. Continuous micromoduli lead to optimal rates of …


Characterization Of A Viscoelastic Response From Thin Metal Films Deposited On Silicon For Microsystem Applications, Steven L. Meredith Jan 2009

Characterization Of A Viscoelastic Response From Thin Metal Films Deposited On Silicon For Microsystem Applications, Steven L. Meredith

Master's Theses

Understanding the mechanisms that control the mechanical behavior of microscale actuators is necessary to design an actuator that responds to an applied actuation force with the desired behavior. Micro actuators which employ a diaphragm supported by torsional hinges which deform during actuation are used in many applications where device stability and reliability are critical. The material response to the stress developed within the hinge during actuation controls how the actuator will respond to the actuating force. A fully recoverable non-linear viscoelastic response has been observed in electrostatically driven micro actuators employing torsional hinges of silicon covered with thin metal films. …


Temperature-Induced Phenomena In Systems Of Magnetic Nanoparticles, Abdul Wazed Bhuiya Jan 2009

Temperature-Induced Phenomena In Systems Of Magnetic Nanoparticles, Abdul Wazed Bhuiya

Open Access Theses & Dissertations

Magnetic nanoparticle ensembles have received a lot of attention, stemming in part from their current and potential applications in biomedicine and in the development of high-density magnetic storage media. Key to the functionality of these systems are microscopic structures and mechanisms that make them exhibit unique properties and behave differently from their bulk counterparts.

We studied microscopic structures and processes that dictate macroscopic properties, behavior and functionality of magnetic nanoparticle ensembles. As the temperature T strongly influences the magnetic behavior of these systems, we studied temperature dependent magnetic properties using AC-susceptibility and DC-magnetization measurements carried out over a broad range …


Art In A New Light: Design And Assessment Of Illuminants To Reduce Photochemical Degradation Of Works Of Art, Monica Fabiola Delgado Jan 2009

Art In A New Light: Design And Assessment Of Illuminants To Reduce Photochemical Degradation Of Works Of Art, Monica Fabiola Delgado

Open Access Theses & Dissertations

The purpose of this research is to design the best lighting that will minimize long term photochemical degradation of Old Master Drawings and/or other works of art, while maintaining the patron's appreciation of the object's color and detail. The present approach is a technological refinement to the basic underlying earlier work on fluorescent lighting by W. A. Thornton, W.A. at General Electric1. Thin-film dielectric, multi-coating technology is used to create filters that eliminate ultraviolet light, near infrared light and significant unnecessary parts from the visible spectrum, thus maximizing the reduction in photochemical degradation, while maintaining optimal color rendering. Three interference …


Assessing Repeatability Of Four-Point Bending Method For Estimating Fatigue Cracking Of Hot Mix Asphalt, Sara -. Montazeri Jan 2009

Assessing Repeatability Of Four-Point Bending Method For Estimating Fatigue Cracking Of Hot Mix Asphalt, Sara -. Montazeri

Open Access Theses & Dissertations

The objective of this thesis was to assess the repeatability of four-point bending method for estimating fatigue cracking of hot mix asphalt. This experimental research examined the influence of mix proportions, specifically asphalt and air void contents, on fatigue behavior of asphalt beam specimens in the laboratory tested with four-point bending method of loading. Following the relevant specifications, the strain-controlled mode of loading was selected. Fatigue failure is expected to occur at the cycle which the flexural stiffness of asphalt specimen reduced to 50% of initial amount. Up to a 1,000,000 cycles of loading were applied to each specimen.

Different …


Microstructural Characterization Of Overaged Gtd-111 Hp Turbine Buckets, Oscar Quintero Jan 2009

Microstructural Characterization Of Overaged Gtd-111 Hp Turbine Buckets, Oscar Quintero

Open Access Theses & Dissertations

Superalloys are metallic materials that exhibit excellent mechanical strength and creep resistance at high temperatures. They have good surface stability and are corrosion resistant. Superalloys are mostly used in the aerospace industry, gas turbine engines and blades (hot zones of gas turbines), and where extreme heat is encountered. The focus of this research was on the GTD-111 Ni-base superalloy, which is a General Electric (GE) proprietary superalloy mostly used in gas turbine blades with the form of high pressure or first stage buckets. This alloys features better mechanical properties, creep resistance, and a higher stress rupture temperature than the commonly …


Fabrication And Characterization Of Zirconium Oxide Thin Films, Vemnkata Rama Sesha Ravi Kumar Vemuri Jan 2009

Fabrication And Characterization Of Zirconium Oxide Thin Films, Vemnkata Rama Sesha Ravi Kumar Vemuri

Open Access Theses & Dissertations

Zirconium oxide (ZrO2) is an important material with a potential for a wide range of technological applications. The outstanding chemical stability, electrical and mechanical properties, high dielectric constant, and wide band gap of ZrO2 make it suitable for several industrial applications in the field of optics, electronics, magneto-electronics, and optoelectronics. ZrO2 is frequently used as a high refractive index material in multilayer optical coatings in high power laser systems. ZrO2 is employed in super plastic structural ceramics that demonstrate excellent strength and fracture toughness. ZrO2 has been considered as a promising dielectric to replace SiO2 in advanced metal oxide semiconductor …


Characterization And Cytotoxic Assessment Of Ballistic Aerosolized Particulates For Tungsten Alloy Penetrators Interacting With Steel Targets, Brenda Ivette Machado Jan 2009

Characterization And Cytotoxic Assessment Of Ballistic Aerosolized Particulates For Tungsten Alloy Penetrators Interacting With Steel Targets, Brenda Ivette Machado

Open Access Theses & Dissertations

The aerosolized particulates produced during an impact of depleted uranium munitions can potentially contaminate extensive areas around the impact sites and cause a wide spectrum of civilian and military damage. Thus materials such as WHA have been prompted for consideration. The present research is concerned with the regular collection of aerosol particulates associated with ballistic WHA rod penetration into rolled homogeneous steel (RHA) or other related steel armor as armor plate sequences. Particulate size characterization via scanning electron microscopy (SEM) and transmission electron microscopy (TEM) along with chemical compositions via energy dispersive spectroscopy (EDS) were the focus of this research. …


Identification Of Multiple Oscillation States Of Carbon Nanotube Tipped Cantilevers Interacting With Surfaces In Dynamic Atomic Force Microscopy, Mark Strus, Arvind Raman Jan 2009

Identification Of Multiple Oscillation States Of Carbon Nanotube Tipped Cantilevers Interacting With Surfaces In Dynamic Atomic Force Microscopy, Mark Strus, Arvind Raman

Birck and NCN Publications

Carbon nanotubes (CNTs) have gained increased interest in dynamic atomic force microscopy (dAFM) as sharp, flexible, conducting, nonreactive tips for high-resolution imaging, oxidation lithography, and electrostatic force microscopy. By means of theory and experiments we lay out a map of several distinct tapping mode AFM oscillation states for CNT tipped AFM cantilevers: namely, noncontact attractive regime oscillation, intermittent contact with CNT slipping or pinning, or permanent contact with the CNT in point or line contact with the surface while the cantilever oscillates with large amplitude. Each state represents fundamentally different origins of CNT-surface interactions, CNT tip-substrate dissipation, and phase contrast …


Failure Analysis And Materials Characterization Of Hip Implants, Amanda Marie Bastidos Jan 2009

Failure Analysis And Materials Characterization Of Hip Implants, Amanda Marie Bastidos

Open Access Theses & Dissertations

This research focused on the microstructural characterization and failure analysis of hip implant components. The main hip components analyzed were the femoral heads and the ultra-high molecular weight polyethylene (UHMWPE) liners. Previous research has shown that hip implants tend to fail by the PE liners due to adhesive and abrasive wear, delamination, and third body particles (metals, ceramics, and PE). The methods and procedures for analyzing the said failures consisted of non-destructive and destructive evaluations. Non-destructive evaluations included of techniques such as visual characterization and dye penetrant inspection (DPI)-which displayed macroscopic surface details and presented initial clues as to the …


Effects Of Aggregate Structure On Hot-Mix Asphalt Rutting Performance In Low Traffic Volume Local Pavements, Yong-Rak Kim, Hee Mun Park, Francisco Thiago Sacramento Aragão, Jamilla Emi Sudo Lutif Jan 2009

Effects Of Aggregate Structure On Hot-Mix Asphalt Rutting Performance In Low Traffic Volume Local Pavements, Yong-Rak Kim, Hee Mun Park, Francisco Thiago Sacramento Aragão, Jamilla Emi Sudo Lutif

Department of Mechanical and Materials Engineering: Faculty Publications

The objective of this study is to evaluate the effect of mix gradations associated with the Superpave restricted zone on rutting potential specifically for low traffic volume roadways. Although the elim-ination of the restricted zone requirement in Superpave mix design is highly recommended, some questions still remain unanswered as the research conclusions supporting the elimination of the re-stricted zone were largely made for medium to high traffic volume roadways, where aggregates are highly crushed and of good quality. The applicability of such research conclusions based on high traffic volume mixes needs to be verified for low volume mixes because many …


Additive Layer Manufacturing Of Ti-6al-4v By Electron Beam Melting From Powder Particles: Solid, Mesh And Foam Components Study, Sara M. Gaytan Jan 2009

Additive Layer Manufacturing Of Ti-6al-4v By Electron Beam Melting From Powder Particles: Solid, Mesh And Foam Components Study, Sara M. Gaytan

Open Access Theses & Dissertations

Additive Manufacturing by Electron Beam Melting Rapid Manufacturing is a technology that consists of the fabrication of a CAD design by melting powder particles in a layer by layer fashion. In this study, Ti-6Al-4V has been utilized to fabricate solid, mesh and foam components by EBM technologies. Powder analysis of Ti-6Al-4V was performed to obtain a better understanding of the porosity obtained by the system. After proper optimization of the machine, and porosity control, microstructural analysis was performed to the components already mentioned and correlated by transmission electron microscopy. Besides the microstructural analysis, tensile and hardness testing was performed to …


Observed Superspin-Glass Behavior In Ni0.5zn0.5fe2o4 Nanoparticles, Antony Adair Jan 2009

Observed Superspin-Glass Behavior In Ni0.5zn0.5fe2o4 Nanoparticles, Antony Adair

Open Access Theses & Dissertations

In this investigation we seek to identify the magnetic behavior of Ni0.5Zn0.5Fe2O4 nanoparticles though AC-susceptibility and DC-magnetization measurements. Powder x-ray diffraction was performed to determine the purity and average diameter ( ~ 9nm) of the particles. Aditionally, structure was confirmed by comparison through the International Centre for Diffraction Data's Powder Diffraction File [52] (PDF # 08-0234).

Zero-field cooled and field cooled DC magnetization measurements (bifurcation and blocking temperature), as well as M(H) hysteresis (below and above the blocking temperature) lead us to initially suggest that the material may in fact be superparamagnetic. However, further investigation of the real AC susceptibility …


Experimental Investigation Of A Novel Blast Wave Mitigation Device, Zhenbi Su, Wen Peng, Zhaoyan Zhang, George Gogos, Reed Skaggs, Bryan Cheeseman, Chian Fong Yen Jan 2009

Experimental Investigation Of A Novel Blast Wave Mitigation Device, Zhenbi Su, Wen Peng, Zhaoyan Zhang, George Gogos, Reed Skaggs, Bryan Cheeseman, Chian Fong Yen

Department of Mechanical and Materials Engineering: Faculty Publications

A novel blast wave mitigation device was investigated experimentally in this paper. The device consists of a pistoncylinder assembly. A shock wave is induced within the cylinder when a blast wave impacts on the piston. The shock wave propagates inside the device and is reflected repeatedly. The shock wave propagation process inside the device lengthens the duration of the force on the base of the device to several orders of magnitude of the duration of the blast wave, while it decreases the maximum pressure over an order of magnitude. Two types of experiments were carried out to study the blast …


Computational Model For Predicting Nonlinear Viscoelastic Damage Evolution In Materials Subjected To Dynamic Loading, Flavio V. Souza, Yong-Rak Kim, George A. Gazonas, David H. Allen Jan 2009

Computational Model For Predicting Nonlinear Viscoelastic Damage Evolution In Materials Subjected To Dynamic Loading, Flavio V. Souza, Yong-Rak Kim, George A. Gazonas, David H. Allen

Department of Mechanical and Materials Engineering: Faculty Publications

Many inelastic solids accumulate numerous cracks before failure due to impact loading, thus rendering any exact solution of the IBVP untenable. It is therefore useful to construct computational models that can accurately predict the evolution of damage during actual impact/dynamic events in order to develop design tools for assessing performance characteristics. This paper presents a computational model for predicting the evolution of cracking in structures subjected to dynamic loading. Fracture is modeled via a nonlinear viscoelastic cohesive zone model. Two example problems are shown: one for model validation through comparison with a one-dimensional analytical solution for dynamic viscoelastic debonding, and …


Comparison Of Fuzzy Clustering Methods And Their Applications To Geophysics Data, David J. Miller, Carl A. Nelson, Molly Boeka Cannon, Kenneth P. Cannon Jan 2009

Comparison Of Fuzzy Clustering Methods And Their Applications To Geophysics Data, David J. Miller, Carl A. Nelson, Molly Boeka Cannon, Kenneth P. Cannon

Department of Mechanical and Materials Engineering: Faculty Publications

Fuzzy clustering algorithms are helpful when there exists a dataset with subgroupings of points having indistinct boundaries and overlap between the clusters. Traditional methods have been extensively studied and used on real-world data, but require users to have some knowledge of the outcome a priori in order to determine howmany clusters to look for. Additionally, iterative algorithms choose the optimal number of clusters based on one of several performance measures. In this study, the authors compare the performance of three algorithms (fuzzy c-means, Gustafson-Kessel, and an iterative version of Gustafson-Kessel) when clustering a traditional data set as well as real-world …


Microstructural Characterization And Heat Treatment Of A-286 Turbine Buckets, Christopher Michael Bradley Jan 2009

Microstructural Characterization And Heat Treatment Of A-286 Turbine Buckets, Christopher Michael Bradley

Open Access Theses & Dissertations

A-286 is an iron-based superalloy used extensively in land-based gas turbines for 2nd stage (low pressure) buckets and 1st and 2nd stage wheels. Although A-286 may appear to some as just another austenitic stainless steel, its elevated temperature properties are attributed to ' precipitate structures, effective distributions of alloy carbides in the forms of M23C6, M6C and MC, and solid solution strengthening. Unfortunately over the course of these components service lives microstructural degradation develops in the form of η-phase formation. The presence of η-phase, especially in large quantities, can have a negative effect on stress rupture properties. Resistance to creep …


Spectroscopic Characterizations Of Organic/Inorganic Nanocomposites, Jayesh Rasikalal Govani Jan 2009

Spectroscopic Characterizations Of Organic/Inorganic Nanocomposites, Jayesh Rasikalal Govani

Open Access Theses & Dissertations

Inorganic potassium dihydrogen phosphate (KDP) is widely known for its value as a nonlinear optical material. In this study, pure and l-arginine-doped KDP single crystals were grown by the slow solvent evaporation technique and further subjected to infrared absorption and Raman studies for the confirmation of chemical group functionalization and possible bonding between the organic and inorganic materials. The appearance in the infrared absorption spectra of additional vibrational lines, which mostly originate from disturbed N-H, C-H, and C-N bonds of the l-arginine-doped salt, confirm the interaction between KDP and the organic material. This affirmation is supported by more evidence from …