Engineering Commons^™

The Study Of Corrosion On Additive-Manufactured Metals., Braydan Daniels

Electronic Theses and Dissertations

The purpose of this study was to investigate and compare the corrosion mechanisms between wrought and additive-manufactured (3D-printed) copper and stainless steel. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, Tafel analysis, surface topology, and scanning electron microscopy for each metal within salt water, tap water, sulfuric acid, and synthetic body fluid (excluding copper in synthetic body fluid).

Overall, printed stainless steel was more corrosion-resistant than wrought stainless steel in tap water and synthetic body fluid based on OCP, LSV, and surface topology results. Additionally, printed copper was more corrosion-resistant than wrought …

Microstructural Investigation Of Vintage Pipeline Steels Highly Susceptible To Stress Corrosion Cracking, Monica Adriana Torres

Open Access Theses & Dissertations

The use of pipelines for the transmission of gas offers not only efficiency, but a number of economic advantages. Nevertheless, pipelines are subject to aggressive operating conditions and environments which can lead to in-service degradation [1] and thus to failures. These failures can have catastrophic consequences, such as environmental damage and loss of life [2]. One of the most dangerous threats to pipeline integrity is stress corrosion cracking (SCC). Despite the substantial progress that has been achieved in the field, due to the complex nature of this phenomenon there is still not a complete understanding of this form of external …

The Effects Of Uncommon Silicides On The Oxidation Of Alloys From The Nb-Cr-Si System, Daniel Brendan Voglewede

Open Access Theses & Dissertations

Niobium based alloys are being tapped as potential successors to current nickel base superalloys in high temperature applications. In the aerospace industry, high temperature materials are constantly being pushed to higher temperature regimes in order to improve engine efficiency however current superalloys cannot be pushed further due to melting temperature limitations. Niobium, being a refractory metal, can withstand much higher temperatures than nickel however its oxidation properties are woefully inadequate.

The purpose of this study is to ascertain whether increased silicon additions can improve niobium oxidation properties by: forming ternary silicides with better oxidation properties and by preventing the formation …