Engineering Commons^™

High Temperature Oxidation Of Nb-Cr-Mo-Si-B Alloys, Kathryn S. Thomas

Open Access Theses & Dissertations

It has been the trend to use nickel based superalloys in high temperature applications, however higher temperatures are required in the effort to enhance the efficiency of such components as jet turbine engines. The melting temperature of the nickel based superalloy limits the extent to which temperature can be raised as these materials are typically used at temperatures within 200 degrees of their melting point. Refractory metal based systems are attractive due to their high melting points, low densities, and good high temperature strength. However, in such cases as niobium, poor oxidation resistance limits the widespread use of such alloys. …

Characterization Of High-Purity Niobium Structures Fabricated Using The Electron Beam Melting Process, Cesar Adrian Terrazas

Open Access Theses & Dissertations

Additive Manufacturing (AM) refers to the varied set of technologies utilized for the fabrication of complex 3D components from digital data in a layer-by-layer fashion. The use of these technologies promises to revolutionize the manufacturing industry. The electron beam melting (EBM) process has been utilized for the fabrication of fully dense near-net-shape components from various metallic materials. This process, catalogued as a powder bed fusion technology, consists of the deposition of thin layers (50 - 120µm) of metallic powder particles which are fused by the use of a high energy electron beam and has been commercialized by Swedish company Arcam …

The Effects Of Uncommon Silicides On The Oxidation Of Alloys From The Nb-Cr-Si System, Daniel Brendan Voglewede

Open Access Theses & Dissertations

Niobium based alloys are being tapped as potential successors to current nickel base superalloys in high temperature applications. In the aerospace industry, high temperature materials are constantly being pushed to higher temperature regimes in order to improve engine efficiency however current superalloys cannot be pushed further due to melting temperature limitations. Niobium, being a refractory metal, can withstand much higher temperatures than nickel however its oxidation properties are woefully inadequate.

The purpose of this study is to ascertain whether increased silicon additions can improve niobium oxidation properties by: forming ternary silicides with better oxidation properties and by preventing the formation …

Development And Characterization Of The Oxidation Behavior Of Various High Temperature Niobium Based Alloys, Benedict Isabel Portillo

Open Access Theses & Dissertations

The oxidation response of various niobium based refractory alloys from the Nb-Mo-Si-B-X alloy system has been examined at temperatures between 700 and 1400°C in air. The development of these alloys was part of an ongoing effort to develop and discover a new materials system capable of replacing nickel based super alloys. Additions of titanium were found to provide limited oxidation resistance. A discontinuous layer of TiO2 was observed to from at temperatures above 1100°C. Alloys containing titanium additions were observed to suffer from pest oxidation at low and intermediate temperatures due to the development of Nb2O5. Poor oxidation resistance at …