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Traversing With Quantitative Fidelity Through The Glass Transition Of Amorphous Polymers: Modeling The Thermodynamic Dilatational Flow Of Polycarbonate, Mehrdad Negahban, Wenlong Li, Jean-Marc Saiter, Laurent Delbreilh, Kyle Strabala, Zheng Li
Traversing With Quantitative Fidelity Through The Glass Transition Of Amorphous Polymers: Modeling The Thermodynamic Dilatational Flow Of Polycarbonate, Mehrdad Negahban, Wenlong Li, Jean-Marc Saiter, Laurent Delbreilh, Kyle Strabala, Zheng Li
Department of Mechanical and Materials Engineering: Faculty Publications
We follow the assumption that the dilatational response of glassy polymers can be characterized by a back-stress type analog that includes a thermal expansion for each elastic component, and with a viscosity that is dependent on the expansion of the elastic back stress component. To this, we add the assumption of an unloaded equilibrium temperature that correlates to the past processing through the viscous flow. After setting this in a thermodynamically consistent structure, the elastic, elastic backstress, thermal expansion, back-stress thermal expansion, heat capacity and viscous damping are evaluated using existing experiments for the response of polycarbonate over the glassy …
Dynamic Fracture Analysis Of Polycarbonate By The Optical Method Of Caustics, Guiyun Gao, Zheng Li, Mehrdad Negahban
Dynamic Fracture Analysis Of Polycarbonate By The Optical Method Of Caustics, Guiyun Gao, Zheng Li, Mehrdad Negahban
Department of Mechanical and Materials Engineering: Faculty Publications
Glassy polycarbonate (PC) is a widely used engineering material in industries, since it has high strength and toughness as well as good transparency. However, these advantages of PC can be suppressed by physical aging, especially its dynamic fracture toughness. In addition, the material properties of PC can be changed dramatically after large plastic compressive deformation, and it can show obvious orthotropic behavior. Here, the combined effect of aging and plastic compressive deformation on dynamic facture of PC was investigated by the optical method of caustics. The dynamic reflective method of caustics for orthotropic materials was developed here to study the …