Engineering Commons^™

Kinetic Study Of Free Radical-Radical Reactions Of Combustion Importance At Elevated Pressures, Chao Yan

Dissertations

Combustion mechanisms consist of hundreds elementary reactions of free radicals and stable molecules. Radical-radical elementary reactions play important roles due to the high concentration in which free radicals are accumulated in combustion systems. Radical-radical reactions are typically multi-channel. Some of the channels might be of chain propagation or even chain branching nature, while other channels might be of chain termination nature. The relative importance of different channels is pressure dependent. Compared to radical-molecule reactions, radical-radical reactions are much less studied. This is due to the difficulties of well characterized quantitative production of radical species as well as due to the …

Combustion Of Aerosolized Spherical Aluminum Powders And Flakes In Air, Binu Zacharia Eapen

Theses

Combustion rates and completeness of aerosolized spherical aluminum powders and flakes are compared using constant volume explosion experiments. The comparison of particles and flake sizes was made based on their specific surface areas determined using the Brunauer-Emmett-Teller (BET) method and respective "BET diameters". It is observed that the rates of pressure rise and rates of flame propagation were higher for aluminum powders with BET diameters of about 2 to 5 μm compared to aluminum flakes for which the BET diameters were under 1 μm In agreement with the flame propagation rates, the overall completeness of combustion was also higher for …

Parametric Study Of Heavy Metal Partitioning In A Pilot Scale Incinerator Burning Simulated Municipal Solid Waste, Sukrut S. Thipse

Dissertations

Incineration is a combustion process used to convert toxic waste to benign gases and residue in presence of excess air. The products of the incineration process are bottom ash, fly ash and the flue gas. Most of the metal-based phases formed in incineration are toxic and their emissions need to be strictly controlled. Therefore, behavior of metal species during incineration must be well understood. Such understanding is possible based on the experimental identification of the metal phases formed in the waste combustion and determination of their concentration in various incineration products.

A pilot-scale incinerator of 140,000 Btu/hr capacity was constructed, …

Entrance Effects For Short Catalytic Combustion Monoliths, Dong Dai

Theses

Catalytic combustion/incineration is becoming increasingly important in modern industrial processes. This thesis work investigates the importance of heat and mass transfer entrance effects in short catalytic combustion monoliths, and includes these effects in an engineering model. Consideration is limited to laminar-flow heat and mass transfer in a circular tube, in which Prandtl number is close to unity, as is the case for air. Thermal, mass and velocity boundary layer growths are considered with inlet conditions assumed uniform at a monolith bed entrance. Conservation equations are solved assuming laminar, steady-state flow, with constant wall temperature, and negligible axial diffusion of heat …