Engineering Commons^™

Improving Tribological Properties Of Polydopamine/Polytetrafluoroethylene Coatings Through Incorporating Core-Shell Nanoparticles And Laser Surface Texturing, Firuze Soltani-Kordshuli

Graduate Theses and Dissertations

Polytetrafluoroethylene (PTFE) is a widely used polymer that has unique properties such as chemical and temperature resistance, corrosion resistance, low maintenance cost, and a very low coefficient of friction (COF). These distinctive properties have made PTFE a promising candidate for industrial applications where surfaces are in relative motion. PTFE can be utilized as a thin film solid lubricant to significantly reduce the friction between moving surfaces. However, PTFE coatings have low cohesion and poor adhesion to the substrate resulting in its low wear resistance. This fact limits the application of PTFE coatings in load-bearing situations. To address these limitations, an …

Adhesion And Deformation Mechanisms Of Polydopamine And Polytetrafluoroethylene: A Multiscale Computational Study, Matthew Brownell

Graduate Theses and Dissertations

Polydopamine (PDA) has been shown to bond via covalent bonding, van der Waals forces, and hydrogen bonding and is known to adhere strongly to almost any material. The application of PDA between a substrate and a PTFE surface coating has resulted in low friction and a greatly reduced wear rate. Previous research probing the capabilities and limitations of PDA/PTFE films have studied the wear and mechanical properties of the film, but the overall adhesive and deformation mechanisms remain unclear.

In this research, we investigate the tribological properties of PDA and PTFE molecules and composites from the atomic to the microscale …

Wear Resistant Polydopamine/Ptfe Nanoparticle Composite Coating For Dry Lubrication Applications, Samuel George Beckford

Graduate Theses and Dissertations

This dissertation presents an investigation into the effect of nanoparticle fillers and a polydopamine adhesive primer on the tribological performance of thin PTFE films. The principal objective of this investigation was to reduce wear in PTFE films, an issue which precludes the use of PTFE films in tribological applications requiring high durability. The friction and wear of the composite films were evaluated using a ball-on-flat configuration in linear reciprocating motion. It was found that the use of a polydopamine adhesive primer reduces the wear of PTFE films more than 600 times. X-ray photoelectron spectroscopy (XPS) results show that a tenacious …