Engineering Commons^™

Improving Sensitivity Of Electrochemical Sensors With Convective Transport In Free-Standing, Carbon Nanotube Structures, Benjamin J. Brownlee, Kevin M. Marr, Jonathan C. Claussen, Brian D. Iverson

Faculty Publications

High-aspect-ratio, porous membrane of vertically-aligned carbon nanotubes (CNTs) were developed through a templated microfabrication approach for electrochemical sensing. Nanostructured platinum (Pt) catalyst was deposited onto the CNTs with a facile, electroless deposition method, resulting in a Pt-nanowire-coated, CNT sensor (PN-CNT). Convection mass transfer enhancement was shown to improve PN-CNT sensor performance in the non-enzymatic, amperometric sensing of hydrogen peroxide (H₂O₂). In particular, convective enhancement was achieved through the use of high surface area to fluid volume structures and concentration boundary layer confinement in a channel. Stir speed and sensor orientation especially influenced the measured current in …