Engineering Commons^™

Characterization Techniques And Electrolyte Separator Performance Investigation For All Vanadium Redox Flow Battery, Zhijiang Tang

Doctoral Dissertations

The all-vanadium redox flow battery (VRFB) is an excellent prospect for large scale energy storage in an electricity grid level application. High battery performance has lately been achieved by using a novel cell configuration with advanced materials. However, more work is still required to better understand the reaction kinetics and transport behaviors in the battery to guide battery system optimization and new battery material development. The first part of my work is the characterization of the battery systems with flow-through or flow-by cell configurations. The configuration difference between two cell structures exhibit significantly different polarization behavior. The battery output can …

Investigation Of The One-Probe And Two-Probe Calibration Integral Equation Methods Using Experimental Data, Abhay Sanjeev Pande

Masters Theses

This work aims to expand the applicability of the recently devised physics-based Calibration Integral Equation Method (CIEM) at the University of Tennessee Knoxville, for solving the Inverse Heat Conduction Problem (IHCP) as applied to a one-dimensional domain. Contrary to conventional schemes of solving the IHCP, the CIEM does not require the knowledge of the thermo-physical properties of the domain, sensor characterization and sensor probe locations. The pertinent information is implicitly accounted for via an experimental run. The experimental run ‘calibrates’ the physics of the domain and is called the ‘calibration run’. The net surface heat flux during a real ‘unknown’ …

Characterization Of Heat Transfer Coefficient Uncertainty In Support Of High Temperature Probe Measurement Technology, Marcus S. Conner

Masters Theses

The development of new materials and processes have enabled defense, industrial, and research devices that operate in high temperature environments. Measurement technology must keep up with the demand of these environments.

The objective of this work is to provide a correlation between the heat transfer coefficient (and Nusselt Number) and the flow Reynolds number (and Prandtl number) for a truncated cylindrical probe. The correlation provides reduced uncertainty for materials whose heat transfer coefficient is not well defined. The configuration for the experiment uses the University of Tennessee Space Institute’s (UTSI) blow down air supply system discharging into a duct and …

A Novel Approach To Multiphysics Modeling Of Heat And Mass Transfer In Porous Media, Seth Allen Pemberton

Masters Theses

This thesis aims to investigate conjugate heat and mass transfer in porous media with an emphasis on textiles. Both hygroscopic materials, those that absorb water vapor, and non-hygroscopic materials are examined. A model was developed that utilizes COMSOL’s equation-based partial differential equation (PDE) interface which allows the user to input any equation(s) to be solved. By the use of experimental and numerical data each part of the model, i.e. flow field, gas diffusion, convection and vapor absorption, is verified. The accuracy of the equation-based unsteady flow field is verified by modeling the flow over a circular cylinder and extracting the …

Modeling And Validation Of Heat Transfer Present In A Solar Thermal Collector, Eric Ezekiel Stannard

Masters Theses

A solar absorber panel for a solar water heating system located at the College of Architecture’s New Norris House in Norris, TN was modeled and validated against field data in this work. The purpose of this modeling was to create the foundations of a tool that can be used in collector design and building energy simulations. This tool would take into account the radiometric properties of the collector materials, which are essential for an accurate model. Solar water heaters convert the shortwave energy of the Sun into usable heat for residential and industrial applications and have the potential to greatly …

Fully Coupled Fluid And Electrodynamic Modeling Of Plasmas: A Two-Fluid Isomorphism And A Strong Conservative Flux-Coupled Finite Volume Framework, Richard Joel Thompson

Doctoral Dissertations

Ideal and resistive magnetohydrodynamics (MHD) have long served as the incumbent framework for modeling plasmas of engineering interest. However, new applications, such as hypersonic flight and propulsion, plasma propulsion, plasma instability in engineering devices, charge separation effects and electromagnetic wave interaction effects may demand a higher-fidelity physical model. For these cases, the two-fluid plasma model or its limiting case of a single bulk fluid, which results in a single-fluid coupled system of the Navier-Stokes and Maxwell equations, is necessary and permits a deeper physical study than the MHD framework. At present, major challenges are imposed on solving these physical models …

Toward Direct Biosynthesis Of Drop-In Ready Biofuels In Plants: Rapid Screening And Functional Genomic Characterization Of Plant-Derived Advanced Biofuels And Implications For Coproduction In Lignocellulosic Feedstocks, Blake Lee Joyce

Doctoral Dissertations

Advanced biofuels that are “drop-in” ready, completely fungible with petroleum fuels, and require minimal infrastructure to process a finished fuel could provide transportation fuels in rural or developing areas. Five oils extracted from Pittosporum resiniferum, Copaifera reticulata, and surrogate oils for Cymbopogon flexuosus, C. martinii, and Dictamnus albus in B20 blends were sent for ASTM International biodiesel testing and run in homogenous charge combustion ignition engines to determine combustion properties and emissions. All oils tested lowered cloud point. Oils derived from Copaifera reticulata also lowered indicated specific fuel consumption and had emissions similar to the ultra-low sulfur diesel control. Characterization …

Essentially Analytical Theory Closure For Space Filtered Thermal-Incompressible Navier-Stokes Partial Differential Equation System On Bounded Domains, Mikhail Alexandrovich Sekachev

Doctoral Dissertations

Numerical simulation of turbulent flows is identified as one of the grand challenges in high-performance computing. The straight forward approach of solving the Navier-Stokes (NS) equations is termed Direct Numerical Simulation (DNS). In DNS the majority of computational effort is spent on resolving the smallest scales of turbulence, which makes this approach impractical for most industrial applications even on present-day supercomputers. A more feasible approach termed Large Eddy Simulation (LES) has evolved over the last five decades to facilitate turbulent flow predictions for reasonable Reynolds (Re) numbers and domain sizes. LES theory uses the concept of convolution with a spatial …

Plasmonics Resonance Enhanced Active Photothermal Effects In Aluminum Nanoenergetics For Propulsion Applications, Jacques Abboud

Doctoral Dissertations

In this dissertation, aluminum nanoparticles (Al NPs) are shown capable to on-demand enhance and control the local photothermal energy deposition, both spatially and temporally, via active photothermal effects initiated by the localized surface plasmon resonance (LSPR) phenomenon, and amplified by the Al exothermal oxidation reactions. Experiments in dry and wet environments along with computational modeling of the photothermal process are very desirable for gaining fundamental understanding, ignition optimization and parameter exploration.

Combined phenomena of motion and ignition of Al NPs are explored first in this study. Both resulting from exposing a pile of the nanoenergetics in hand to a single …

Multidimensional Compressible Framework For Modeling Biglobal Stability In Rocket Motors, Michel Henry Akiki

Doctoral Dissertations

Rocket motor stability analysis has historically been focused on two fundamental theories: the acoustic and the hydrodynamic. While the acoustic part examines the system at resonant states, the hydrodynamic component focuses on the fluid-wall interactions and the vortex shedding mechanisms which are responsible for exciting the system. Traditionally, the two concepts are studied independently and their results are then superposed for a more complete solution. In this study, we analyze the problem from a hydrodynamic standpoint and extend it to include compressibility. This is realized by reducing the linearized Navier-Stokes and energy equations to their biglobal form assuming a two-dimensional …

Two-Dimensional Formulation And Quasi-One-Dimensional Approximation To Inverse Heat Conduction By The Calibration Integral Equation Method (Ciem), Hongchu Chen

Masters Theses

The recently devised calibration integral equation method developed at the University of Tennessee for resolving transient inverse heat conduction in one-dimensional applications is extended and studied in the context of two-dimensional linear inverse heat conduction. This study investigates a simplified plate geometry possessing three known boundary conditions and one unknown boundary condition. This plate contains a series of temperature sensors located on a fixed plane below the surface of interest. To begin the investigation, a quasi-one-dimensional formulation is proposed for predicting the surface heat flux (W/m²) based on a zonal formulation where each zone contains a single thermocouple. …

Experimental And Theoretical Investigations Of Lube Oil Performance And Engine Friction, William Fredrick Rohr

Doctoral Dissertations

The feasibility of using a motored small, single-cylinder 517 cc Hatz 1D50 diesel engine to evaluate lube oil performance and engine friction at conditions typical for a fired engine is investigated in the present study. In addition a commercial engine modeling software, AVL Excite Power Unit, is used to predict the effects of lube oil formulations on the engine friction of the same engine. The motored engine can be operated with and without compression and with and without the engine oil pump. Lube oil performance is evaluated for 19 different lube oils by using either instantaneous motoring torque (motoring torque …

Vibration Based Damage Identification Of Time-Varying Dynamical Systems, Jie Zhao

Doctoral Dissertations

This thesis develops and explores two new kinds of vibration-based damage identification methodologies suitable for dynamical systems with periodically time-varying coefficients; 1) a Floquet based method (Methodology I) and, 2) a Sideband Frequency Response Function (FRF) method (Methodology II). One important class of dynamical systems where periodic time-varying parametric terms naturally arise is rotordynamic systems. For the case of a flexible shaft-rotor system with multiple open cracks, this thesis explores a new Least Squares damage identification approach based on Floquet theory with iterative eigenvector estimate updating. It is found that this method is able to detect the location and severity …

Neutron Imaging Of Lithium Inside A High-Temperature Heat Pipe, Eric Henry Kirchoff

Masters Theses

Neutron imaging of a high-temperature Mo-Li [molybdenum-lithium] heat pipe has been performed to assess Li flow visualization. The high neutron attenuation cross section of Li allows for imaging inside the heat pipe shell structure, which has a lower value of neutron attenuation, making neutron radiography an ideal choice for characterizing Li movement.

The gravity assisted, cylindrical heat pipe was heated to 903^oC [degree] using a wire resistance Mo heater operating under vacuum. This Mo-Li heat pipe is 35 cm long with a square internal geometry 2.2 cm per side, utilizing small corner radii as the wicking structure for …

Water Transport In Polymer Electrolyte Fuel Cells: An Exploration Of Net Water Drag In Real Time, Susan Katherine Reid

Masters Theses

Polymer electrolyte fuel cells (PEFCs) are a promising alternative energy source. One challenge preventing widespread use of this technology is water management. A balance must be reached between providing sufficient water for membrane ionic conductivity while maintaining low enough water content to mitigate the reduction of available reaction sites in the cathode catalyst layer due to liquid water build up. Much exploration of this area of fuel cell research has been conducted, but the details of water transport in an operating fuel cell are not yet fully understood. The motivation of this work was to elucidate mass transport phenomena occurring …

A Decision Support Methodology For Improving Equipment Reliability, Caiqiao Xu

Masters Theses

Purpose - Aggressive Maintenance Strategy can improve the overall operation and reliability through redesigning or modifying equipment. A decision support tool is proposed that could aid in discovering the many options and in selecting the best approach for redesigning or for modifying the equipment. The new tool has three sections that correspond to the equipment life cycle:

1. Keeping the equipment in perfect running condition.
2. Identifying defects as soon as the equipment starts to degrade.
3. Minimizing losses after the equipment has ceased functioning.

Design/Methodology – The first section seeks to keep the equipment running in perfect condition. There …

Direct Measurement Of Through-Plane Thermal Conductivity Of Partially Saturated Fuel Cell Diffusion Media, Guoqing Xu

Masters Theses

Polymer electrolyte fuel cells (PEFCs) are predicted by many as the most feasible alternative to heat engines and for battery replacement in automotive, portable, and stationary power applications. Fuel cell performance and durability are inseparably related to the presence of liquid water throughout the fuel cell system. To better understand the mechanical and thermal characterization of diffusion media (DM) is essential to PEFC DM design, optimization and production to improve water and thermal managements. Diffusion media are one of the important components in PEFCs in terms of the reactant permeability, the product permeability, the electronic conductivity, the heat conductivity, and …

Sustainable Design Retrofit For The Visitor Center At The Oak Ridge National Laboratory, Michael A. Kerksick

Chancellor’s Honors Program Projects

No abstract provided.