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Full-Text Articles in Engineering

Layered Bismuth Tungstate: Heterogeneous Photocatalysis For Environmental Remediation, Mirabbos Hojamberdiev, Zuhra Kadirova, Shahlo Daminova, Khasan Sharipov, Nobuhiro Matsushita May 2021

Layered Bismuth Tungstate: Heterogeneous Photocatalysis For Environmental Remediation, Mirabbos Hojamberdiev, Zuhra Kadirova, Shahlo Daminova, Khasan Sharipov, Nobuhiro Matsushita

CHEMISTRY AND CHEMICAL ENGINEERING

Air and water pollution has been one of the challenging environmental issues in modern society. Since the Honda-Fujishima effect was first reported in 1972, a semiconductor-based photocatalysis has been regarded as one of the most green and economical processes for potential application in environmental remediation. Bismuth-based semiconductors are regarded as a promising group of advanced photocatalytic materials due to their suitable band gap for visible light response, an increased mobility of photo-generated charge carriers because of well-dispersed Bi 6s orbital, non-toxicity, and easy tailoring of their morphologies. To utilize its full potential in environmental remediation, various studies have been carried …


3d Printing Of Hybrid Architectures Via Core-Shell Material Extrusion Additive Manufacturing, Robert Cody Pack May 2021

3d Printing Of Hybrid Architectures Via Core-Shell Material Extrusion Additive Manufacturing, Robert Cody Pack

Doctoral Dissertations

Biological materials often employ hybrid architectures, such as the core-shell motif present in porcupine quills and plant stems, to achieve unique properties and performance. Drawing inspiration from these natural materials, a new method to fabricate lightweight and stiff core-shell architected filaments is reported. Specifically, a core-shell printhead conducive to printing highly loaded fiber-filled inks, as well as a new low-density syntactic foam ink, are utilized to 3D-print core-shell architectures consisting of a syntactic epoxy foam core surrounded by a stiff carbon fiber-reinforced epoxy composite shell. Effective printing of test specimens and structures with controlled geometry, composition, and architecture is demonstrated …


Stretching The Applications Of Biomass: Development Of Lignin Based Thermoplastic Elastomers And Composite Materials, Anthony Stephen Bova May 2021

Stretching The Applications Of Biomass: Development Of Lignin Based Thermoplastic Elastomers And Composite Materials, Anthony Stephen Bova

Doctoral Dissertations

Bio-based plastics and composites have seen increased industry adoption in recent years due to growing demand for materials with a low carbon footprint. The use of lignin as a feedstock for polymers has seen growing interest as the concept of an integrated cellulosic biorefinery gains traction and advances the need to use all components of separated biomass for value-added applications. Historically, use of lignin in thermoplastic and elastomeric copolymers and blends has been bottlenecked by the inability to introduce lignin content above 30 weight percent due to difficulties with interfacial adhesion of lignin with other soft segments. Efforts to overcome …