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Full-Text Articles in Engineering

Thermal Analysis Of Fe-Carbide And Fe-C Mixtures, R Tongsri, B Vetayanugul Jul 2010

Thermal Analysis Of Fe-Carbide And Fe-C Mixtures, R Tongsri, B Vetayanugul

Journal of Metals, Materials and Minerals

Differential thermal analysis (DTA) was employed to monitor changes which occurred during heating of Fe-carbide and Fe-C mixtures. The DTA curves showed a relationship between endothermic peaks and phase transformations given in the Fe-C phase diagram. The transformations included (i) magnetic Fe to non-magnetic Fe, (ii) pure α-Fe to pure γ-Fe, (iii) γ + Fe3C → Liquid and (iv) pure γ-Fe to pure δ-Fe. Melting of the Fe-SiC powder compacts when sintered at temperatures higher than 1200°C was revealed and indicated by the endothermic peak of 1230°C. This peak corresponded to the transformation of γ + Fe3C → Liquid. That …


The Effects Of Carbon, Boron And Vanadium On The Microstructural Evolution And Hardness Of Steel-Based Hardfacing Alloys, Kyle Rafa Jun 2010

The Effects Of Carbon, Boron And Vanadium On The Microstructural Evolution And Hardness Of Steel-Based Hardfacing Alloys, Kyle Rafa

Materials Engineering

Current hardfacing alloys provide insufficient wear resistance due to either cracking or significant material wear. To increase wear resistance of steel-based hardfacing alloys, the effects of composition on microstructure and hardness were investigated in a progression of alloys. Initially, seven new alloys were prepared varying the carbon-boron ratio with the total constant at 3 wt%. Small arc-melt cast circular ingots were produced roughly 1 x 0.5 inches. Metallography provided insufficient phase magnification, thus a SEM equipped with EDS was used, allowing for microstructure and phase composition analysis. Four distinct carbide phases were found and image analysis software allowed for carbide …


Processing Of Zrb2-Zrc-Zrxsiy Ceramic By Reactive Metal Penetration, Nischel B. Maheswaraiah Jan 2010

Processing Of Zrb2-Zrc-Zrxsiy Ceramic By Reactive Metal Penetration, Nischel B. Maheswaraiah

Open Access Theses & Dissertations

The processing of ZrB2-ZrC-ZrxSiy composite by reactive metal penetration was investigated as a successor to the ZrB2-SiC composites for hypersonic vehicles application, which cannot be used for extended time at temperatures greater than 1600C due to formation of SiO and CO gases. Zirconium (Zr), zirconium disilicide (ZrSi2), and boron carbide (B4C) were reacted in graphite crucibles for 60, 120, 180, and 240 minutes. Microscopy and x-ray diffraction (XRD) deduced the formation of a heterogeneous microstructure of ZrB2-ZrC-ZrxSiy precipitates surrounded by a solidified Zr-Si melt. Unreacted boron carbide was observed in samples held at 1860C for 60 minutes and 120 minutes, …