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Articles 1 - 30 of 33
Full-Text Articles in Engineering
Behavior Of Gamma Tial Subjected To Impact Damage And Elevated Temperature Fatigue, Trevor S. Harding, J. Wayne Jones
Behavior Of Gamma Tial Subjected To Impact Damage And Elevated Temperature Fatigue, Trevor S. Harding, J. Wayne Jones
Materials Engineering
Gamma titanium aluminide has received significant attention in recent years as a candidate material for use in aerospace and industrial gas turbine engine applications. In particular, these materials offer significant weight reductions (densities are less than half that of nickel-based superalloys), high specific strength retention at elevated temperature and high specific stiffness which is particularly important in vibrating components such as blades. This combination of weight savings and good mechanical properties has led to the possibility that γ-TiAl may be a suitable replacement for nickel-based alloys, such as Inconel 718, in low pressure turbine blades without significant redesign of the …
Method Of Destroying Hazardous Organic Compounds, Dibakar Bhattacharyya, Susan Mawhinney
Method Of Destroying Hazardous Organic Compounds, Dibakar Bhattacharyya, Susan Mawhinney
Chemical and Materials Engineering Faculty Patents
The present invention relates to a method of destroying hazardous vapor phase or aqueous phase organic compound(s) by providing a polymeric siloxane based solvent in a vessel and adding the hazardous organic compound(s) and ozone to the solvent. The solvent may also comprise a mixture of polymeric siloxane based solvent and fluorinated hydrocarbon solvent.
Effect Of Interfacial Mobility On Flexural Strength And Fracture Toughness Of Glass/Epoxy Laminates, T. W. H. Wang, Frank D. Blum, Lokeswarappa R. Dharani
Effect Of Interfacial Mobility On Flexural Strength And Fracture Toughness Of Glass/Epoxy Laminates, T. W. H. Wang, Frank D. Blum, Lokeswarappa R. Dharani
Chemistry Faculty Research & Creative Works
Mechanical testing and surface fractography were used to characterize the fracture of E-glass fiber reinforced epoxy composites as a function of the silane coupling agent used. gamma-Aminopropyltriethoxysilane (APS) and delta-aminobutyltriethoxysilane (ABS) were used because these have been shown to have different interfacial mobilities at multilayer coverage. The values of the properties studied generally increased from untreated c, as determined from a Mode I translaminar fracture toughness tests, for the untreated composites (10.5 ± 0.4 kJ/m2) was lower than that for the ABS-treated composites (14.3 ± 2.1 kJ/m2) which was lower than that for the APS-treated composites (17.1 ± 2.4 kJ/m2). …
Reactive Infiltration Of Silicon Melt Through Microporous Amorphous Carbon Preforms, P. Sangsuwan, Surendra N. Tewari, Jorge E. Gatica, M. Singh, R. Dickerson
Reactive Infiltration Of Silicon Melt Through Microporous Amorphous Carbon Preforms, P. Sangsuwan, Surendra N. Tewari, Jorge E. Gatica, M. Singh, R. Dickerson
Chemical & Biomedical Engineering Faculty Publications
The kinetics of unidirectional capillary infiltration of silicon melt into microporous carbon preforms has been investigated as a function of the pore morphology and melt temperature. The infiltrated specimens showed alternating bands of dark and bright regions, which corresponded to the unreacted free carbon and free silicon regions, respectively. The decrease in the infiltration front velocity for increasing infiltration distances is in qualitative agreement with the closed-form solution of capillarity-driven fluid flow through constant-cross-section cylindrical pores. However, drastic changes in the thermal response and infiltration front morphologies were observed for minute differences in the preform's microstructure. This suggests the need …
Optical Spray Painting Practice And Training System, Richard J. Klein Ii
Optical Spray Painting Practice And Training System, Richard J. Klein Ii
Patents (University of Northern Iowa)
An optical spray painting practice gun emits a shaped optical beam onto a practice surface to simulate an actual paint spray on the surface. The gun preferably uses a class 2 diode laser to generate a laser beam which is reshaped by a collimating lens into a diverging beam that illuminates the practice surface. The collimating lens creates an elongated image on the practice surface having a length corresponding linearly to the distance of the practice gun nozzle to the practice surface as with a conventional spray gun. The illuminated image distorts when the practice gun is not perpendicular to …
Theoretical And Experimental Investigation On The Low Temperature Properties Of The Nbcr2 Laves Phase, Dan J. Thoma, Chu Fuming, Katherine C. Chen, Paul G. Kotula, Terence E. Mitchell, John M. Wills, Alim Ormeci, Shao Ping Chen, Robert C. Albers
Theoretical And Experimental Investigation On The Low Temperature Properties Of The Nbcr2 Laves Phase, Dan J. Thoma, Chu Fuming, Katherine C. Chen, Paul G. Kotula, Terence E. Mitchell, John M. Wills, Alim Ormeci, Shao Ping Chen, Robert C. Albers
Materials Engineering
This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The goal of the project was to develop methodologies in which to define and improve the properties of NbCr2 so that the high temperature structural applications of alloys based upon this would not be limited by the low-temperature brittle behavior of the intermetallic. We accomplished this task by (1) understanding the defect structure and deformation mechanisms in Laves phases, (2) electronic and geometric contributions to phase stability and alloying behavior, and (3) novel processing of dual phase (Laves/bcc) …
Cellular/Dendritic Array Tip Morphology During Directional Solidification Of Pb-5.8 Wt Pct Sb Alloy, L. Yu, G. L. Ding, J. Reye, S. N. Ojha, Surendra N. Tewari
Cellular/Dendritic Array Tip Morphology During Directional Solidification Of Pb-5.8 Wt Pct Sb Alloy, L. Yu, G. L. Ding, J. Reye, S. N. Ojha, Surendra N. Tewari
Chemical & Biomedical Engineering Faculty Publications
Cellular/dendritic array tip morphology has been examined in directionally solidified and quenched Pb-5.8 wt pet Sb alloy by a serial sectioning and three-dimensional image reconstruction technique. There is a large scatter in the tip radius, the nearest neighbor spacing, and the mushy zone length, even among the immediately neighboring cells and dendrites. This scatter may be caused by the natural convection (in the mushy zone and in the bulk melt at the array tip), which also produces macrosegregation along the length of the directionally solidified samples. Even in the presence of convection, however, the tip radii are observed to be …
Capillary Surfaces In An Exotic Container: Results From Space Experiments, Paul Concus, Robert Finn, Mark M. Weislogel
Capillary Surfaces In An Exotic Container: Results From Space Experiments, Paul Concus, Robert Finn, Mark M. Weislogel
Mechanical and Materials Engineering Faculty Publications and Presentations
Experimental results from the Interface Configuration Experiment (ICE) performed aboard the Space Shuttle and the Mir Space Station are reported. The experiment concerns fluid interfaces in certain ‘exotic’ containers in a low-gravity environment. These containers are rotationally symmetric and have the property that for given contact angle and liquid volume, a continuum of distinct rotationally symmetric equilibrium configurations can appear, all of which have the same mechanical energy. These symmetric equilibrium configurations are unstable, in that deformations that are not rotationally symmetric can be shown mathematically to yield configurations with lower energy. It is found experimentally, in confirmation of mathematical …
Electrodeposition Of Cerium-Based Coatings For Corrosion Protection Of Aluminum Alloys, James O. Stoffer, Thomas J. O'Keefe, Xuan Lin, Eric L. Morris, Pu Yu, Srinivas Pravin Sitaram
Electrodeposition Of Cerium-Based Coatings For Corrosion Protection Of Aluminum Alloys, James O. Stoffer, Thomas J. O'Keefe, Xuan Lin, Eric L. Morris, Pu Yu, Srinivas Pravin Sitaram
Chemistry Faculty Research & Creative Works
A process for enhancing the corrosion resistance of an aluminum-containing component with a cerium based coating. An aluminum-containing cathode and an oxygen- evolving anode are immersed in an electrolyte comprising water, solvent, oxidizing agent and cerium ions. An electrical current is passed through the electrolyte by applying electrical current to deposit a cerium based coating onto the cathode. An electrolyte for use in depositing a cerium based coating. An electrodeposited cerium-based coating. An aluminum aircraft structural component having a cerium-based coating thereon.
Macrosegregation Caused By Thermosolutal Convection During Directional Solidification Of Pb-Sb Alloys, S. N. Ojha, G. L. Ding, Y. Lu, J. Reye, Surendra N. Tewari
Macrosegregation Caused By Thermosolutal Convection During Directional Solidification Of Pb-Sb Alloys, S. N. Ojha, G. L. Ding, Y. Lu, J. Reye, Surendra N. Tewari
Chemical & Biomedical Engineering Faculty Publications
Pb-2.2 and 5.8 wt pet Sb alloys were directionally solidified with a positive thermal gradient of 140 K cm(-1) at growth speeds ranging from 0.8 to 30 mu m s(-1), and then quenched to retain the mushy-zone morphology. Chemical analysis along the length of the directionally solidified portion and in the quenched melt ahead of the dendritic array showed extensive longitudinal macrosegregation, Cellular morphologies growing at smaller growth speeds are associated with larger amounts of macrosegregation as compared with the dendrites growing at higher growth speeds. Convection is caused, mainly, by the density inversion in the overlying melt ahead of …
Cell/Dendrite Distribution In Directionally Solidified Hypoeutectic Pb-Sb Alloys, S. P. O'Dell, G. L. Ding, Surendra N. Tewari
Cell/Dendrite Distribution In Directionally Solidified Hypoeutectic Pb-Sb Alloys, S. P. O'Dell, G. L. Ding, Surendra N. Tewari
Chemical & Biomedical Engineering Faculty Publications
The alloys Pb-2.2 wt pet Sb and Pb-5.8 wt pet Sb were directionally solidified with three different thermal gradients of 40, 86, and 140 K cm(-1) at growth rates ranging from 0.6 to 30 mu m s(-1). A Gaussian peak amplitude analysis of the cell/dendrite spacing distribution shows a distinct peak corresponding to the nearest neighbors. The peaks corresponding to the second and the third nearest neighbor spacings are also brought out by this technique. The ratios of the second to the first nearest neighbor spacings and that of the third to the first neighbor spacings are 1.85 +/-: 0.11 …
Training Graduate Student Instructors Effectively: The University Of Michigan Model, Trevor S. Harding
Training Graduate Student Instructors Effectively: The University Of Michigan Model, Trevor S. Harding
Materials Engineering
No abstract provided.
Development Of A Curved Layer Lom Process For Monolithic Ceramics And Ceramic Matrix Composites, Donald A. Klosterman, Richard P. Chartoff, Nora R. Osborne, George A. Graves, Allan Lightman, Gyoowan Han, Akos Bezewredi, Stan Rodrigues, Sung Pak, Gary Kalmanovich, Leon Dodin, Song Tu
Development Of A Curved Layer Lom Process For Monolithic Ceramics And Ceramic Matrix Composites, Donald A. Klosterman, Richard P. Chartoff, Nora R. Osborne, George A. Graves, Allan Lightman, Gyoowan Han, Akos Bezewredi, Stan Rodrigues, Sung Pak, Gary Kalmanovich, Leon Dodin, Song Tu
Chemical and Materials Engineering Faculty Publications
A novel rapid prototyping technology incorporating a curved layer building style was developed. The new process, based on Laminated Object Manufacturing (LOM), was designed for efficient fabrication of curved layer structures made from ceramics and fiber reinforced composites. A new LOM machine was created, referred to as Curved Layer LOM. This new machine uses ceramic tapes and fiber prepregs as feedstocks and fabricates curved structures on a curved-layer by curved-layer basis. The output of the process is a three dimensional "green" ceramic that is capable of being processed to a seamless, fully dense ceramic using traditional techniques. A detailed description …
Oxygen And Phosphorus Coordination Around Iron In Crystalline Ferric Ferrous Pyrophosphate And Iron-Phosphate Glasses With Uo₂ Or Na₂O, C. H. Booth, P. G. Allen, J. J. Bucher, N. M. Edelstein, D. K. Shuh, G. K. Marasinghe, Mevlüt Karabulut, C. S. Ray, D. E. Day
Oxygen And Phosphorus Coordination Around Iron In Crystalline Ferric Ferrous Pyrophosphate And Iron-Phosphate Glasses With Uo₂ Or Na₂O, C. H. Booth, P. G. Allen, J. J. Bucher, N. M. Edelstein, D. K. Shuh, G. K. Marasinghe, Mevlüt Karabulut, C. S. Ray, D. E. Day
Materials Science and Engineering Faculty Research & Creative Works
Fe K-edge x-ray absorption fine-structure (XAFS) measurements were performed on glass samples of (Fe3O4)0.3(P2O5)0.7 with various amounts of Na2O or UO2. Near-edge and extended-XAFS regions are studied and comparisons are made to several reference compounds. We find that iron in the base glass is ~25% divalent and that the Fe2+ coordination is predominantly octahedral, while Fe3+ sites are roughly split between tetrahedral and octahedral coordinations. Also, we measure roughly one FeñOñP link per iron. Substitution of Na2O or UO2 up to 15 mo1% primarily affects the first FeñO shell. The results are compared to data from the related material Fe3(P2O7)2.
Grain Oriented Crystallization, Piezoelectric, And Pyroelectric Properties Of (Baxsr₂ - X)Tisi₂O₈ Glass Ceramics, Jianping Zhang, Burtrand I. Lee, Robert W. Schwartz, Zhenya Ding
Grain Oriented Crystallization, Piezoelectric, And Pyroelectric Properties Of (Baxsr₂ - X)Tisi₂O₈ Glass Ceramics, Jianping Zhang, Burtrand I. Lee, Robert W. Schwartz, Zhenya Ding
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Polar, nonferroelectric (BaxSr2 - x)TiSi2O8 glass ceramics with highly oriented crystallites were prepared by a gradient temperature heat treatment technique. The crystallization mechanism and microstructures of (BaxSr2 - x)TiSi2O8 glass ceramics were investigated by means of differential thermal analysis, x-ray diffraction and scanning electron microscopy, and the dielectric, piezoelectric and pyroelectric properties were investigated for various compositions. The results show that polar (BaxSr2 - x)TiSi2O8 glass ceramics have a low dielectric constant and a high hydrostatic figure of merit dh × gh = ~ 2500. This high hydrostatic figure of merit, along with other unique characteristics, such as no aging …
Why Does Ni Suppress Superconductivity In La₁.₈₅Sr₀.₁₅Cu1-YNiYO₄?, Daniel Haskel, Edward A. Stern, Victor Z. Polinger, Fatih Dogan
Why Does Ni Suppress Superconductivity In La₁.₈₅Sr₀.₁₅Cu1-YNiYO₄?, Daniel Haskel, Edward A. Stern, Victor Z. Polinger, Fatih Dogan
Materials Science and Engineering Faculty Research & Creative Works
The role played by Ni impurities in destroying the superconducting state of La2-xSrxCuO4 is still unclear. This is partly due to the lack of clear experimental evidence on the effect of Ni substitution upon the atomic and electronic structure of this cuprate. To provide this information, we performed Ni K-edge polarized XAFS measurements on oriented powder. A special magnetic alignment geometry allowed us to measure pure ĉ and âb-polarized XAFS in identical experimental conditions. We found that the NiO6 octahedra are contracted along the ĉ-axis by 0.16(Å) relative to the CuO6 octahedra in …
Low-Temperature Molecular Beam Epitaxy Of Gaas: A Theoretical Investigation Of Antisite Incorporation And Reflection High-Energy Diffraction Oscillations, K. Natarajan, Rama Venkat, Donald L. Dorsey
Low-Temperature Molecular Beam Epitaxy Of Gaas: A Theoretical Investigation Of Antisite Incorporation And Reflection High-Energy Diffraction Oscillations, K. Natarajan, Rama Venkat, Donald L. Dorsey
Electrical & Computer Engineering Faculty Research
Surface dynamics dominate the incorporation of charged, As+Ga, and neutral, As0Ga, antisite arsenic, and the temporal variation of reflection high-energy electron diffraction(RHEED) intensity in the low-temperature molecular beam epitaxy of (100) gallium arsenide(GaAs). A rate equation model is proposed which includes the presence and dynamics of a physisorbed arsenic (PA) layer riding the growth surface. The PA layer dictates the incorporation and concentration of As+Ga and As0Ga. Additionally, it influences the RHEED oscillations (ROs) behavior and the RO’s dependence on its coverage through its contribution to the reflected intensity. The model results for the dependence of As+Ga and As0Ga concentrations …
Structural Disorder And The Origin Of High-Tc Suppression In La₁.₈₇₅Ba₀.₁₂₅ Cuo4−Δ, Daniel Haskel, Edward A. Stern, Fatih Dogan, Arnie R. Moodenbaugh
Structural Disorder And The Origin Of High-Tc Suppression In La₁.₈₇₅Ba₀.₁₂₅ Cuo4−Δ, Daniel Haskel, Edward A. Stern, Fatih Dogan, Arnie R. Moodenbaugh
Materials Science and Engineering Faculty Research & Creative Works
No abstract provided.
Output Control Of Vertical Microcavity Light Emitting Device, James A. Lott
Output Control Of Vertical Microcavity Light Emitting Device, James A. Lott
AFIT Patents
An improved intracavity sensor based output power control for microcavity light emitting devices. An improved phototransistor transducer is both configured and physically disposed so that it passively transmits the spurious optical energy output of the microcavity light emitting device while simultaneously generating a light determined electrical signal of easily used large magnitude that is nearly free of error. The base-collector region of the transistor is disposed with a quantum well absorbing layer and produces a signal responsive to a selected emission wavelength. The configuration of the optical energy communicating transducer is arranged so that it is improved in sensitivity and …
Magnetic And Mössbauer Spectral Study Of Mixed Valent La₀.₂Sr₀.₈Cu₀.₂Fe₀.₈O2.68 And Related Perovskites, Gary J. Long, Dimitri Hautot, Amitabh Mohan, Ingeborg Kaus, Harlan U. Anderson, Fernande Grandjean
Magnetic And Mössbauer Spectral Study Of Mixed Valent La₀.₂Sr₀.₈Cu₀.₂Fe₀.₈O2.68 And Related Perovskites, Gary J. Long, Dimitri Hautot, Amitabh Mohan, Ingeborg Kaus, Harlan U. Anderson, Fernande Grandjean
Chemistry Faculty Research & Creative Works
The La0.2Sr0.8Cu1-xFexO 3-δ perovskites are important because they are mixed electron and oxygen anion conductors and thus are able to serve as dense oxygen separation membranes. In order to better understand the mechanism for this separation a Mössbauer spectral study has been carried out to determine the ratio of iron(III) to iron(IV) in these mixed valent compounds. The Mössbauer spectra of La0.2Sr0.8Cu0.2Fe0.8O 3-δ obtained between 4.2 and 78 K reveal that its Néel temperature is ~75 K and the two well-resolved magnetic sextets observed …
Preparation Of A Zro₂-Al₂O₃ Nanocomposite By High-Pressure Sintering Of Spray-Pyrolyzed Powders, Rajiv S. Mishra, V. Jayaram, B. Majumdar, C. E. Lesher, A. K. Mukherjee
Preparation Of A Zro₂-Al₂O₃ Nanocomposite By High-Pressure Sintering Of Spray-Pyrolyzed Powders, Rajiv S. Mishra, V. Jayaram, B. Majumdar, C. E. Lesher, A. K. Mukherjee
Materials Science and Engineering Faculty Research & Creative Works
ZrO2-Al2O3 powders were synthesized by spray pyrolysis. These powders were sintered at 1 GPa in the temperature range of 700Ç1100 ÉC. The microstructural evolution and densification are reported in this paper. The application of 1 GPa pressure lowers the crystallization temperature from ~850 to 700 ÉC. Similarly, the transformation temperature under 1 GPa pressure for <>g ê a Al2O3 reduces from ~1100 to 700Ç800 ÉC range, and that for t <>ê m ZrO2 reduces from ~1050 to 700Ç800 ÉC range. It was possible to ob-tain highly-dense nanocrystalline ZrO2-Al2O3 composite at temperatures as low as 700 ÉC. The effect of high …
Paint Gun Incorporating A Laser Device, Richard J. Klein Ii, Douglas L. Sevey
Paint Gun Incorporating A Laser Device, Richard J. Klein Ii, Douglas L. Sevey
Patents (University of Northern Iowa)
A spray gun for applying a liquid spray coating, such as paint, to a surface incorporates a light source and detection system for analyzing the position of the spray gun relative to a worksurface in order to optimize application of the coating to the surface. The light source is preferably in the form of a laser which emits a beam of light toward the worksurface. The laser is interconnected with the housing of the spray gun in a location over the spray gun handle so as not to effect the center of gravity of the spray gun. Optical sensors are …
Room Temperature Fatique Response Of Γ-Tial To Impact Damage, Trevor S. Harding, J. Wayne Jones, P. S. Steif, T. M. Pollock
Room Temperature Fatique Response Of Γ-Tial To Impact Damage, Trevor S. Harding, J. Wayne Jones, P. S. Steif, T. M. Pollock
Materials Engineering
Gamma based titanium aluminides have received considerable attention recently as candidate materials in gas turbine applications, particularly low pressure turbine blades (1–3). Their low density and high specific stiffness, result in potentially significant weight savings in structures such as gas turbine engines if substituted for current materials. Two γ-TiAl microstructures are predominately identified in the literature: a lamellar microstructure consisting of alternating plates of γ and α2, and a duplex microstructure consisting of equiaxed γ grains and lamellar colonies (3,4). Lamellar alloys generally exhibit better fracture toughness and fatigue crack growth resistance (5–7). Duplex alloys, on the other …
Paint Gun Incorporating A Laser Device, Richard J. Klein, Douglas L. Sevey, Alireza Badakhshan, Ricky Jay Bauer
Paint Gun Incorporating A Laser Device, Richard J. Klein, Douglas L. Sevey, Alireza Badakhshan, Ricky Jay Bauer
Patents (University of Northern Iowa)
A spray gun for applying a liquid spray coating, such as paint, to a surface incorporates a light source system for gauging the position of the spray gun relative to a worksurface in order to optimize application of the coating to the surface. The light source is preferably in the form of a laser which emits a pair of light beams toward the worksurface. The pair of light beams converge toward each other in a direction toward the surface, and the position of the beams on the surface is used by the operator to judge the distance of the spray …
Application Of Pvd Coatings To Enhance The Wear Life Of Needles Used In The Textile Industry, Neil Donnelly
Application Of Pvd Coatings To Enhance The Wear Life Of Needles Used In The Textile Industry, Neil Donnelly
Masters
Needles are used in the textile industry for weaving. In high volume textile production a problem is wear of the needle eyelet as the threat is pulled through. This wear results in a cost to the textile manufacturer both in needle replacement, but in many cases more importantly, lost production during needle substitution The objective of this study was to examine the potential of wear resistant coatings deposited using the magnetron sputtering technique to increase the life-time of textile needles. Four coatings were evaluated, titanium nitride, titanium carbonitride, titanium diamond-like carbon and a novel coating titanium nitride/molybdenum disulphide. These coatings …
Thermal Characterization Of Pmma Thin Films On Silica Using Modulated Differential Scanning Calorimetry, Crystal E. Porter, Frank D. Blum
Thermal Characterization Of Pmma Thin Films On Silica Using Modulated Differential Scanning Calorimetry, Crystal E. Porter, Frank D. Blum
Chemistry Faculty Research & Creative Works
The number of studies of thin polymer films has increased over recent years as technological processes incorporate the use of nanomaterials. An enhanced understanding of these films would enable us to predict bound-polymer behavior and thus improve the efficiency of processes and the quality of products. This is especially true as the thickness of the films approach molecular dimensions. The glass transition temperature of a polymer is one of the most important properties for characterization because it indicates how the polymer might perform macroscopically. when a polymer is confined, such as one the surface of a substrate, its behavior is …
Dynamics Of Acrylic Coupling Agents At Interfaces Of Composites, Hyoryoon Jo, Frank D. Blum
Dynamics Of Acrylic Coupling Agents At Interfaces Of Composites, Hyoryoon Jo, Frank D. Blum
Chemistry Faculty Research & Creative Works
Most applications of polymers involve composites, wherein a polymer is used in conjunction with another material, typically a solid fiber or filler. A coupling agent can enhance the adhesion between a polymer matrix and an inorganic filler. Organofunctional silanes, RSiX are often used as coupling agents. The methoxy or ethoxy group, X, can typically be hydrolyzed with water and an acid or a base catalyst in a protic solvent. The silanol groups of a hydrolyzed coupling agent can condense with other silanol groups from a glass surface, while the alkyl group, R, blends physically or bonds chemically to the polymer …
Copper Alloy-Impregnated Carbon-Carbon Hybrid Composites For Electronic Packaging Applications, S. K. Datta, Surendra N. Tewari, Jorge E. Gatica, W. Shih, L. Bentsen
Copper Alloy-Impregnated Carbon-Carbon Hybrid Composites For Electronic Packaging Applications, S. K. Datta, Surendra N. Tewari, Jorge E. Gatica, W. Shih, L. Bentsen
Chemical & Biomedical Engineering Faculty Publications
Porous carbon-carbon preforms, based on three-dimensional networks of PAN (Polyacrylonitrile)-based carbon fibers and various volume fractions of chemical vapor-deposited (CVD) carbon, were impregnated by oxygen-free, high-conductivity (OFHC) Cu, Cu-6Si-0.9Cr, and Cu-0.3Si-0.3Cr (wt pct) alloys by pressure infiltration casting. The obtained composites were characterized for their coefficient of thermal expansion (CTE) and thermal conductivity (K) along the through-thickness and two in-plane directions. One composite, with a 28 vol pct Cu-0.3Si-0.3Cr alloy, showed outstanding potential for thermal management applications in electronic applications. This composite exhibited approximately isotropic thermal expansion properties (CTE = 4 to 6.5 ppm/K) and thermal conductivities (k greater than …
X-Ray Absorption, Neutron Diffraction, And Mössbauer Effect Studies Of Mnzn-Ferrite Processed Through High-Energy Ball Milling, D. J. Fatemi, V. G. Harris, Mingxing Chen, Satish K. Malik, William B. Yelon, Gary J. Long, Amitabh Mohan
X-Ray Absorption, Neutron Diffraction, And Mössbauer Effect Studies Of Mnzn-Ferrite Processed Through High-Energy Ball Milling, D. J. Fatemi, V. G. Harris, Mingxing Chen, Satish K. Malik, William B. Yelon, Gary J. Long, Amitabh Mohan
Physics Faculty Research & Creative Works
MnZn-ferrite has been prepared via high-energy ball milling of elemental oxides MnO, ZnO, and α-Fe2O3. Neutron diffraction measurements suggest a high density of vacancies in a spinel structure. The spinel phase appears to comprise 99.8 wt % of the material in the sample milled for 40 h, with the remainder attributable to unreacted α-Fe2O3. The x-ray absorption near-edge structure was analyzed to provide an understanding of the charge state of the constituent Fe ions. This analysis reveals about 2/3 of Fe cations to be trivalent, increasing to about 3/4 after a 5 …
Integrated Computational Chemistry System For Catalysts Design, Salai Cheettu Ammal, S. Takami, M. Kubo, A. Miyamoto
Integrated Computational Chemistry System For Catalysts Design, Salai Cheettu Ammal, S. Takami, M. Kubo, A. Miyamoto
Faculty Publications
The understanding of valuable catalytic and adsorptive properties of heterogeneous catalysts at atomic and electronic levels is essential for the design of novel catalysts. Computer simulation studies can significantly contribute to provide a rational interpretation of the observed experimental results and suggest modification of new catalysts. Our recent work on the application of integrated computer simulation methods to investigate the structure and catalytic properties of solid surfaces including zeolites, transition metals and their oxides have been reviewed in this paper. We have emphasized the effectivity and applicability of integrated computer simulation system to solve the problems in a variety of …