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The Preparation Of Zirconium Powder, Herbert S. Kalish

Professional Degree Theses

"The preparation of zirconium powder by several different methods is fully described and evaluated. Most of the methods described are of a rather classical nature and these methods are discussed as taken from their original sources with suggestions for possible streamlining. Flow sheets are provided.

The first series of steps to produce zirconium powder is almost invariably the production of pure zirconium tetrachloride or pure zirconium oxide from the tetrachloride. The processes described include the sodium reduction of zirconium tetrachloride, sodium reduction of the double alkali fluorides, the calcium reduction of zirconium oxide, hydrogen embrittlement and comminution of reduction products. …