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Full-Text Articles in Engineering

Optimizing The Mechanical Properties Of Partially Yttria Stabilized Zirconia With Alumina Additions, Ramanaganapathy Kandaswamy Dec 2010

Optimizing The Mechanical Properties Of Partially Yttria Stabilized Zirconia With Alumina Additions, Ramanaganapathy Kandaswamy

All Theses

Zirconia is one of the extensively studied solid oxide ceramics with respect to its use in various industrial applications like electrolyte in fuel cells, sensors, refractories and exhaust chamber in automobile industry. It can be found from the literature 1-4 that are contradictory results on the mechanical properties when alumina is added. There are several factors like microstructure, phase composition and method of processing that affects the mechanical properties of the material. The focus of this research is to examine how hardness, tensile strength and other properties varies with alumina content and deduce the optimal amount of alumina that is …


Microstructure Modification Of Cu0.2ag2.8sbsete2 Through, Sloan Lindsey Aug 2010

Microstructure Modification Of Cu0.2ag2.8sbsete2 Through, Sloan Lindsey

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Cu0.2Ag2.8SbSeTe2 is new potential thermoelectric compound that exhibits very low thermal conductivity and a region of glass-like thermal conductivity. The compound phase segregates into AgSbTe2 and Ag2Te phases with Se and Cu acting as isoelectronic dopants. Backscatter SEM imaging is used to study the resulting microstructure. Normally cast samples exhibit cracks forming near the interfaces of the two phases. In this work we show that the cracks are caused by a low temperature monoclinic to cubic phase transition that occurs in the Ag2Te phase. We demonstrate that through rapid quenching we can control the size and shape of the phase …


Fabrication Of Fluorescent Nanoparticle-Polymer Composites For Photoactive-Based Materials, Brett Ellerbrock Aug 2010

Fabrication Of Fluorescent Nanoparticle-Polymer Composites For Photoactive-Based Materials, Brett Ellerbrock

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Nanocomposites of nanoparticles dispersed throughout a polymer matrix have been studied to great length to improve the overall polymer properties. These enhancements are observed in the thermal, physical, and/or optical characteristics. Being able to harness nanoparticles in such a way may help improve fiber technology into the 21st century.
This work was geared toward synthesizing rare earth doped lanthanum fluoride (LaF3) nanoparticles because good separation in the absorption and emission bands of the material and it fluoresces in the visible to near-infrared range. Terbium ions were added to a LaF3 crystal because of their distinct visible green …


Surface Characterization And Electrochemical Behavior Of Colloidal Particles, Cinta Pepin Aug 2010

Surface Characterization And Electrochemical Behavior Of Colloidal Particles, Cinta Pepin

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There is an ongoing interest in research focused on developing polymeric organic-light-emitting-devices (OLED) to replace inorganic devices. Compared to inorganic devices, OLEDs could present better properties such as higher efficiency, lower cost and simpler device fabrication. In an attempt to get a device with high efficiency, the hole transporting group and the electron transporting group were combined into a polymer to make an individual 'particle device'. The idea was to create a polymer particle containing both charge transporting moieties via emulsion polymerization. In this presentation, different techniques will be described that were used to determine the stability and the surface …


Influence Of Iso-Structural Substitutions On Properties Of Ge(As,Sb)(S,Se) Glasses, Guillaume Guery Aug 2010

Influence Of Iso-Structural Substitutions On Properties Of Ge(As,Sb)(S,Se) Glasses, Guillaume Guery

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Chalcogenide glasses possess exceptional infrared transparency, large non-linear refractive indexes and low phonon energies, making them good candidates for infrared optical applications. Previous studies in the Ge-Sb-S glass system have shown an increase in the nonlinear refractive index with an iso-structural substitution of two- coordinated selenium (Se) for sulphur (S) and variation of other physical properties with substitution of other iso-structural species such as three-coordinated arsenic (As) for antimony (Sb). The role of such iso-structural exchange on properties important to the thermo-, visco- and mechanical attributes of glasses in the Ge-As/Sb-S/Se system has not been thoroughly evaluated and form the …


Kinetic And Finite Element Modeling For Firing Brick, Daniel Mckinney May 2010

Kinetic And Finite Element Modeling For Firing Brick, Daniel Mckinney

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Kinetic modeling and simulation were used to optimize the firing cycle for brick. This was done to develop a tool for the brick industry to reduce fuel consumption and emissions during firing. A kinetic model was built using shrinkage data from dilatometer measurements and mass loss data from thermogravimetry measurements in order to predict the density as a function of temperature and time. The density of brick was related to the absorption coefficient (C/B), an ASTM standard which is related to the durability of the brick. The kinetic model was used to optimize the firing curve using a rate controlled …


Biodegradable Polymer Blends And Composites From Proteins Produced By Animal Co-Product Industry, Bernice Nzioki May 2010

Biodegradable Polymer Blends And Composites From Proteins Produced By Animal Co-Product Industry, Bernice Nzioki

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ABSTRACT
Development of new green materials from by-products of animal rendering industries would provide a substantial economic return to animal rendering processors. Meat and bone meal (MBM), one of the products of the rendering industry, has potential for numerous bio-based applications. This research focuses on fabrication of plastics blends made of MBM (Meat and bone meal) and UHMWPE (ultra high molecular weight polyethylene). We investigated thermal, morphological, water absorption and mechanical properties of the plastics. The plastics were compression molded and their properties were examined.
DSC thermographs of the blends indicated that the thermal properties of UHMWPE did not change …


Characterization And Modification Of Helmet Padding System To Improve Shockwave Dissipation, Katelyn Howay May 2010

Characterization And Modification Of Helmet Padding System To Improve Shockwave Dissipation, Katelyn Howay

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Currently soldiers are being exposed a much higher number of improvised explosive devices (IEDs) and the resulting shockwaves. These shockwaves can cause traumatic brain injuries (TBIs) even without the occurrence of ballistic impact. The focus of this research was to reduce the amount of shockwaves soldiers are exposed to by inserting fibers and woven fabrics into a foam padding system. These fibers and fabrics facilitate the dissipation of the shockwave energy before it is able to penetrate the padding and cause TBIs.
The sound velocity of high-performance fibers, commodity fibers and woven fabric was measured using a Dynamic Modulus Tester. …


Investigation Of The Thermoelectric Behavior Of Cu-Doped Pbteagxse, Ben Ma Jan 2010

Investigation Of The Thermoelectric Behavior Of Cu-Doped Pbteagxse, Ben Ma

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Sustainable energy research is currently on the forefront of scientific exploration thus a major effort is devoted to the development of new energy conservation and production techniques. Thermoelectric materials can play a significant part both in energy conservation and energy production via the Seebeck effect (heat to electric power) and the Peltier effect (electricity to cooling power), since they can convert wasted heat to useful electrical energy.
Presented herein are the measured electrical and thermal transport properties and phenomenal analysis of the PbTeAgxSe (x=1.9, 2.0, 2.01) system. First, it would lead to a significant reduction in the thermal conductivity and …