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Synthesis And Characterization Of Glycidyl Methacrylate-Based Graft Copolymer Functional Interfaces, Nikolay Brordinov Dec 2017

Synthesis And Characterization Of Glycidyl Methacrylate-Based Graft Copolymer Functional Interfaces, Nikolay Brordinov

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Modification of materials properties such as surface energy, wettability, ability to absorb, contain or release specific type of chemicals enables practical application of these materials in various scientific and engineering set-ups. However, designing protocol that could be easily adapted for different situations and simultaneously unlock multiple variations of the resulting properties is a non-trivial task. This dissertation is devoted to application of glycidyl methacrylate-based graft copolymers for the purposes of surface modification, establishing fundamental trends and dependencies of this process and exploring the possible range of applications. These materials have extremely valuable property to undergo controllable post-synthetic modifications including surface …


Incorporation Of Polydiacetylene Sensors Into Commercial Polymers, Jennifer Kauffman May 2008

Incorporation Of Polydiacetylene Sensors Into Commercial Polymers, Jennifer Kauffman

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Polydiacetylenes (PDAs) exhibit a chromatic response to solvents, temperature, strain and other environmental perturbations. When formed in a solid-state polymerization, the backbone of the polymer is planar and continuous π-overlap is observed. However, when the PDA backbone is distorted by an outside force the extended conjugation is interrupted and an optical shift from blue to red occurs. By exploiting the PDAs properties within polymer systems, smart fibers and films have been created that enhance the original intention of the host. Under this umbrella, a strain sensitive polydiacetylene-polyurethane blend was created using 3 and 4-butoxycarbonylmethylurethane PDA and a medical grade polyurethane, …