Engineering Commons^™

Optics Of Two-Dimensional Materials Used As Substrates For Nanoparticle-Based Devices, Reagan Newman

Chancellor’s Honors Program Projects

No abstract provided.

Enhanced And Tunable Optical Quantum Efficiencies From Plasmon Bandwidth Engineering In Bimetallic Coag Nanoparticles, A. Malasi, H. Taz, M. Ehrsam, J. Goodwin, H. Garcia, Ramki Kalyanaraman

Faculty Publications and Other Works -- Materials Science & Engineering

Plasmonic nanoparticles are amongst the most effective ways to resonantly couple optical energy into and out of nanometer sized volumes. However, controlling and/or tuning the transfer of this incident energy to the surrounding near and far field is one of the most interesting challenges in this area. Due to the dielectric properties of metallic silver (Ag), its nanoparticles have amongst the highest radiative quantum efficiencies (η), i.e., the ability to radiatively transfer the incident energy to the surrounding. Here we report the discovery that bimetallic nanoparticles of Ag made with immiscible and plasmonically weak Co metal can show comparable and/or …

Symbiotic Plasmonic Nanomaterials: Synthesis And Properties, Abhinav Malasi

Doctoral Dissertations

Metal particles of the dimensions of the order of 1 to 100's of nanometers show unique properties that are not clearly evident in their bulk state. These nanoparticles are highly reactive and sensitive to the changes in the vicinity of the particle surface and hence find applications in the field of sensing of chemical and biological agents, catalysis, energy harvesting, data storage and many more. By synthesizing bimetallic nanoparticles, a single nanoparticle can show multifunctional characteristics. The focus of this thesis is to detail the synthesis and understand the properties of bimetallic nanomaterial systems that show interesting optical, chemical, and …

Nanomaterials Synthesis By A Novel Phenomenon: The Nanoscale Rayleigh-Taylor Instability, S. Yadavali, Ramki Kalyanaraman

Faculty Publications and Other Works -- Materials Science & Engineering

The Rayleigh-Taylor (RT) interfacial instability has been attributed to physical phenomenon in a wide variety of macroscopic systems, including black holes, laser generated plasmas, and thick fluids. However, evidence for its existence in the nanoscale is lacking. Here we first show theoretically that this instability can occur in films with thickness negligible compared to the capillary length when they are heated rapidly inside a bulk fluid. Pressure gradients developed in the evaporated fluid region produce large forces causing the instability. Experiments were performed by melting Au films inside glycerol fluid by nanosecond laser pulses. The ensuingnanoparticles had highly monomodal size …

Processing, Structure, And Properties Of Nanoparticle Reinforced Nonwoven Sandwich Composites, Josh Griffith Fogle

Doctoral Dissertations

Shockwaves produced from ballistic impacts and improvised explosive devices are capable of causing severe internal trauma to soldiers. Current antiballistic materials give adequate protection to soldiers from high velocity impacts, however they are insufficient at absorbing and dissipating shockwave energy generated by these impacts and explosive blasts. The goal of this research was to develop shockwave absorbing protective materials which can be used as liners in conjunction with current antiballistic materials by reinforcing thermoplastic polyurethane nonwovens with high modulus nanoparticles

To determine the appropriate TPU for the application, a series of TPUs of shore hardness ranging from 60D to 85A …

Optimizing The Performance Of A Glass-Ceramic Storage Phosphor As An Imaging Plate For Medical Use, Manh Vu

Masters Theses

Europium-doped-fluorochlorozirconate glass ceramics, known as ZBLAN, were produced in a glove box which has a controlled environment of argon gas. For imaging applications BaCl₂ is used instead of BaF₂. Their properties after different thermal processing and different amounts of europium-doping were investigated. After annealing the ZBLAN glass, BaCl₂ nanoparticles are precipitated in the glass matrix. These glass ceramic storage phosphors are strong candidates for replacing traditional x-ray screen film system and commercial storage phosphors such as Agfa MD-30.

Differential scanning calorimetry (DSC) was used to determine the crystallization temperature of the hexagonal phase of BaCl_{2 …}