Engineering Commons^™

Corrosion Research On Rock Bolts And Steel Sets For Sub-Surface Reinforcement Of The Yucca Mountain Repository, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

Underground nuclear waste storage repositories generally use steels and super alloys for various structural members and storage containers. These materials are susceptible to corrosion due to seepage of water. We studied rock bolt materials for reinforcing tunnels and containment materials for storing nuclear waste materials. In general, the design of underground support materials for tunnels are mainly based on mechanical behavior of the materials, but not much was known about the interaction of the seepage YM waters with the structural members under various conditions in the tunnels. The sources of water in the Yucca Mountain (YM) repository are due to …

Environmental Effects On Corrosion Properties Of Alloy 22, Mano Misra

Publications (YM)

This document presents detailed technical report for four Subtasks that were conducted independently. All four Subtasks investigated environmental effects on corrosion properties of Alloy 22. The four Subtasks that were investigated are as follows: Subtask 1: Experimental Determination of Parameters for the General Corrosion Model. Subtask 2: Corrosion under Dust Deposits Containing Hygroscopic Salts. Subtask 3: Heated Electrode Approach for the Study of Corrosion Under Aggressive Conditions. Subtask 4: Effect of Hydrogen Permeation on the Stability of the Passive Film of Alloy 22.

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 14, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report shows the work done for this period in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic and immersion tests to determine the corrosion rates of rock bolts.

In this quarter specifically we have accomplished the following:

Potentiodynamic tests were performed to determine …

Final Report: Phase Stability And Segregation In Alloy 22 Base Metal And Weldments, Jeffrey Lacombe

Publications (YM)

At the outset of this project, the design of the waste disposal containers relied heavily on encasement in a multi-layered container, featuring a corrosion barrier of Alloy 22, a Ni-Cr- Mo-W based alloy with excellent corrosion resistance over a wide range of conditions. The fundamental concern from the perspective of the Yucca Mountain Project, however, was the inherent uncertainty in the (very) long-term stability of the base metal and welds. Should the properties of the selected materials change over the long service life of the waste packages, it was conceivable that the desired performance characteristics (such as corrosion resistance) would …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 13, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report shows the work done for this period in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic and immersion tests to determine the corrosion rates of rock bolts.

In this quarter:

Potentiodynamic tests were performed to determine corrosion rates (CR) of 4340 Steel …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 12, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This 12th report shows the work done in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic and immersion tests to determine the corrosion rates of rock bolts.

In this quarter:

Potentiodynamic tests were performed to determine corrosion rates (CR) of 4340 Steel in pure …

Final Report: Second Generation Waste Package Design Study, L. S. Armijo, Mano Misra, Piyush Kar

Publications (YM)

The objectives of this project activity are: to review the current YMP baseline environment and establish corrosion test environments representative of the range of dry to intermittently wet conditions expected in the drifts as a function of time. to demonstrate the oxidation and corrosion resistance of A588 weathering steel and reference Alloy 22 samples in the representative dry to intermittently dry conditions. to evaluate backfill and design features to improve the thermal performance analyses of the proposed second-generation waste packages using existing models developed at UNR.

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 11, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report shows the work done for this period in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic and immersion tests to determine the corrosion rates of rock bolts.

In this quarter:

Potentiodynamic tests were performed to determine corrosion rates (CR) of 4340 Steel …

Phase Stability And Segregation In Alloy 22 Base Metal And Weldments, Jeffrey Lacombe, G. L. Mcmillon

Publications (YM)

Subtask 1: Microstructural Characterization of Phase Stability and Variability in Alloy 22. Develop an improved understanding of Alloy 22 and the extent to which compositional and microstructural variations are present in otherwise “nominal” as-procured material.

Subtask 2: Electrochemical Methods to Detect Susceptibility of Alloy 22 to Localized Corrosion. Study the influence that compositional and microstructural variations have on the corrosion performance of Alloy 22.

Environmental Effects On Corrosion Properties Of Alloy 22, Mano Misra, L. G. Mcmillion

Publications (YM)

Subtask 1: Experimental Determination of Parameters for the General Corrosion Model Subtask 2: Corrosion Under Dust Deposits Containing Hygroscopic Salts Subtask 3: Heated Electrode Approach for the Study of Corrosion Under Aggressive Conditions Subtask 4: Effect of Hydrogen Permeation on the Stability of the Passive Film of Alloy 22

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For Yucca Mountain Repository, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

Outline Metallurgical Issues in Underground Repository Reinforcement Support for Nuclear Materials Storage in simulated Yucca Mountain Environment used for Corrosion Issues
Issues related to I-beams (Low Carbon) and Rock Bolts (Med. Carbon)

Experimental

Results 1. Corrosion Tests- Effect of Ionic Concentration (1x,10x,100x), Temperature, concentration and aeration/deaeration effects in YM waters (RB and I-Beam)
2. Hydrogen Permeation Tests
3. Environmentally Assisted Corrosion Tests - Stress Corrosion Cracking/Hydrogen Embrittlement in 100x YM water concentration at Room Temperature and 85oC (I-Beams)

Influence Of Lithophysae Geometry On Mechanical Properties Of Hydro-Stone®, Moses Karakouzian, Doug Rigby

Publications (YM)

85 percent of YM drift tunnels will be constructed in lithophysal volcanic tuff.

Rock behavior depends on porosity.

Limited experimental data exists to characterize rock porosity and dependencies on properties such as σc , E, and n.

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 10, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report shows the work done for this period in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic tests to determine the corrosion rates of rock bolts, other support materials including bench mark materials.

In this quarter:

Potentiodynamic tests were performed to determine corrosion …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 9, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report shows the work done for this period in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic tests to determine the corrosion rates of rock bolts, other support materials including bench mark materials.

In this quarter, we have performed:

Potentiodynamic tests were performed …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 8, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report shows the work done for this period, in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We are performing oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic tests to determine the corrosion rates of rock bolts, other support materials including bench mark materials.

In this quarter, we have performed:

Potentiodynamic tests were performed …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 6, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report encompasses the work done for this fourth quarter of the year 2005, in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We have started oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic tests to determine the corrosion rates of rock bolts, other support materials including bench mark materials.

In this quarter, we have …

Second Generation Waste Package Design Study, Sam Armijo, Mano Misra

Publications (YM)

The design of waste packages currently proposed for YMP is highly conservative. The candidate materials of construction of the waste packages and drip shields while highly corrosion resistant are extremely expensive and components made from these materials will require complex and expensive fabrication methods to assure their integrity. A proposed, second generation operating concept and waste package design, is intended to permit more efficient and less costly operation of the repository while maintaining waste package integrity. Major reductions in waste package costs can be realized by increasing the number of fuel assemblies stored in each waste package, eliminating the reference …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 5, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report encompasses the work done for this third quarter, 2005, in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We have started oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic tests to determine the corrosion rates of rock bolts, other support materials including bench mark materials.

In this quarter, we have also performed (1) …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 4, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report encompasses the work done for this third quarter, 2005, in accordance to cooperative agreement of University of Nevada system for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the overall objective of which is to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We have started oxidation tests using Thermogravimetric Analyzer (TGA), and Potentiodynamic tests to determine the corrosion rates of rock bolts, other support materials including bench mark materials.

In this quarter, we have also performed hydrogen …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 3, Dhanesh Chandra, Jaak J.K. Daemen

Publications (YM)

This report encompasses the work done for third quarter in accordance to cooperative agreement of UCCSN for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the objective of which was proposed earlier, to conduct corrosion research and predict the durability of rockbolts and other underground metallic roof supports. We have recently started working on oxidation tests using Thermogravimetric Analyzer (TGA), stress corrosion cracking/hydrogen embrittlement studies on rock bolts, other support materials including bench mark materials.

In this quarterly report we will discuss “Dry” oxidation of steels and …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 2, Dhanesh Chandra

Publications (YM)

This report encompasses the work done for second quarter in accordance to cooperative agreement of UCCSN for the Task 019 “Subsurface Corrosion Research on Rock Bolt System, Perforated SS Sheets and Steel Sets for the Yucca Mountain Repository”, the objective of which was proposed earlier, to conduct corrosion research and predict the durability of rock-bolts and other underground metallic roof supports. We have recently started working on oxidation tests using Thermogravimetric Analyzer, stress corrosion cracking/hydrogen embrittlement studies on rock bolts, other support materials including bench mark materials.

In this quarterly report we will discuss “Dry” oxidation of steels and other …

Environmental Effects On Corrosion Properties Of Alloy 22, K. S. Raja, L. G. Mcmillion, Shantanu A. Namjoshi, Paige Russel, Raymond E. Keeler, Amy J. Smiecinski

Publications (YM)

During the regulatory life of the Yucca Mountain High Level Nuclear Waste (HLNW) repository the primary engineered barrier that is to prevent release of radioactive material into the environment is proposed to be a Corrosion-Resistant Material (CRM) outer shell covering the Waste Package (WP) container. The current selection for the CRM is Alloy 22 (UNS N06022), a Ni-Cr-Mo-W-Fe alloy. Alloy 22 forms a defective chromic oxide passive film which results in excellent corrosion resistance; the presence of molybdenum in Alloy 22 offers corrosion resistance in reducing environments as well as oxidizing environments.

Phase Stability And Segregation In Alloy 22 Base Metal And Weldments, Jeffrey Lacombe, Shantanu A. Namjoshi, Paige Russel, Raymond E. Keeler, Amy J. Smiecinski

Publications (YM)

The current design of the waste disposal containers relies heavily on encasement in a multi-layered container, featuring a corrosion barrier of Alloy 22, a Ni-Cr-Mo-W based alloy with excellent corrosion resistance over a wide range of conditions. The fundamental concern from the perspective of the Yucca Mountain Project, however, is the inherent uncertainty in the (very) long-term stability of the base metal and welds. Should the properties of the selected materials change over the long service life of the waste packages, it is conceivable that the desired performance characteristics (such as corrosion reistance) will become compromised, leading to premature failure …

Sub-Surface Corrosion Research On Rock Bolt System, Perforated Ss Sheets And Steel Sets For The Yucca Mountain Repository — Quarterly Technical Report No. 1, Dhanesh Chandra, Jaak J.K. Daemen, Raul Rebak

Publications (YM)

The principal purpose of the cooperative agreement is to develop and continue providing the public and the Office of Repository Development (ORD) of the U.S. Department of Energy’s (DOE) Office of Civilian Radioactive Waste Management (OCRWM) with an independently derived, unbiased body of scientific and engineering data concerning the study of Yucca Mountain as a potential high-level radioactive waste repository. Under this agreement, the University and Community College System of Nevada (UCCSN) will perform scientific or engineering research, and maintain and foster collaborative working relationships between government and academic researchers. The following describes the objectives of Task 019 “Subsurface Corrosion …

Experimental Investigation Of Time Dependent Behavior Of Welded Topopah Spring Tuff, Lumin Ma

Publications (YM)

Four types of laboratory tests have been performed. Specimens were attained from four lithophysal zones of the welded Topopah Spring Tuff unit at Yucca Mountain, Nevada: upper lithophysal, middle nonlithophysal, lower lithophysal and lower nonlithophysal zones. Two types of tests are conducted to study time-dependent behavior: constant strain rate and creep tests. Sixty five specimens from the middle nonlithophysal zone were tested at six strain rates: 10 , 10 , 10 , 10 , 10 , and 10 . Test durations range from 2 seconds to 7 days. Fourteen specimens from middle nonlithophysal, lower lithophysal and lower nonlithophysal zones are …

Corrosion Research On Rock Bolts And Steel Sets For Sub-Surface Reinforcement Of The Yucca Mountain Repository, Dhanesh Chandra, Jaak J.K. Daemen, Amy J. Smiecinski

Publications (YM)

Corrosion resistance of Yucca Mountain (YM) carbon steel rock bolt (0.44%C) and I-beam steel sets (0.08%C) towards electrochemical/general corrosion, stress corrosion cracking (SCC), and hydrogen embrittlement (HE) susceptibility has been determined using simulated YM waters in this Task 18 for YM site underground repository tunnel support. These findings show the corrosion behavior of these structural support members with and without applied stresses in simulated YM environments. The simulated YM waters were increased in nominal concentrations from Ix to lOOx (three different levels) for electrochemical and other corrosion studies. The effect of temperature, of significance to YM repository, on the corrosion …

Continue Stress Corrosion Cracking/ Electrochemical Testing And Model Support, L. G. Mcmillion, K. S. Raja, S. Namjoshi, Amy J. Smiecinski

Publications (YM)

The work reported here is focused on measuring values for various model parameters for the General Corrosion Model (GCM). The objective of the UNR work is to obtain the parameter values under Quality Assurance protocols, so that the data can be incorporated into models that might be used to address licensing issues, for example. The derived kinetic parameters may be used in models for predicting the accumulation of general and localized corrosion damage to Alloy-22 canisters over the 10,000-year lifetime of the YM repository. The work focuses on obtaining data of the highest possible accuracy to derive kinetic parameters for …

Stress Corrosion Cracking Studies, K. S. Raja, S. Namjoshi, Amy J. Smiecinski

Publications (YM)

This document reports on the activities for Task 17 of the U.S. DOE/UCCSN Cooperative Agreement Number DE-FC28-98NV12081. There are three subtasks in this Task, the experimental results, discussions, and conclusions of which are presented in the following sections. Data Sources and Electronic Data Control The Data Identification numbers for the data, graphs, and tables in this report, as submitted to the Data Management Database, are tabulated below. The table also includes the source files for the said data as well as the corresponding scientific notebooks where the data can be found. All data in the Q section of the report …

Corrosion And Mass Transport Processes In Carbon Steel Miniature Waste Packages, James Cizdziel, Kaveh Zarrabi, Susan Lestrange, Amy J. Smiecinski

Publications (YM)

In this study, we have systematically investigated corrosion and mass transport processes in carbon steel miniature waste packages (MWP) in dynamic systems (water in, water out) under varying chemical conditions. The MWP were fabricated to have similar configuration to the DOE Spent Nuclear Fuel (SNF) waste package and that individual components to be in scale with each other compare to the SNF waste package. Two MWP configurations were studied: a "bathtub" model and a "flow-through" model. By slowly dripping 4 different solutions (groundwater obtained from well water J-13 located near Yucca Mountain, and J-13 water adjusted to low-pH, high-salinity, and …

Identification Of Dynamic Properties Of Materials For The Nuclear Waste Package, Brendan O'Toole, Mohamed Trabia, Amy J. Smiecinski

Publications (YM)

Stainless steel 316L, titanium alloy grade 7, and alloy C22 are currently under consideration as candidate materials for use in various components associated with the spent nuclear fuel package, which must be designed to withstand structural deformation caused by static, thermal, and handling loads. In addition, it has to maintain its integrity in case of accidents, where it may be subjected to high loads over a very short period of time. Mechanical characteristics of these three materials under dynamic loading are not well documented. This paper describes the procedures and results obtained from experiments performed over a range of slow …