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Materials Science and Engineering

New Jersey Institute of Technology

Theses/Dissertations

High pressure

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Full-Text Articles in Engineering

A Study Of Three Transition Metal Compounds And Their Applications, Zhen Qin May 2011

A Study Of Three Transition Metal Compounds And Their Applications, Zhen Qin

Dissertations

The La5/8-yPryCa3/8MnO3 with colossal magnetoresistance (CMR) effect has a rich phase diagram and is well studied for its electronic phase separation phenomenon, where the ferromagnetic (FM) metal order co-exists and competes with the charge-ordered (CO) insulator phase. High Pr doping will favor the CO order, leading a sharp FM to CO dominated phase transition around Pr concentration of 0.3 and above. Hydrostatic pressure favors FM metallic order without damaging the sample and can be tuned continuously. In this study, pressurized-magnetic and resistivity measurements was done on a La0.25Pr0.375Ca0.375 …


Probing Spin, Charge And Lattice Coupling In Manganites, Zhiqiang Chen Aug 2008

Probing Spin, Charge And Lattice Coupling In Manganites, Zhiqiang Chen

Dissertations

Complex oxides such as the manganites exhibit an intimate coupling of the electron spin, charge and lattice degrees of freedom. The characteristic feature of these materials is the existence of a ground state topology with many closely lying minima. The system can be switched from one minimum to another by the application of external parameters such as strain, temperature, magnetic fields, or electrical fields. These materials thus exhibit large responses to these external parameters and can be used as novel sensors in data storage and other applications. Understanding the couplings will have an impact on the fundamental science of highly …