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Materials Science and Engineering

Missouri University of Science and Technology

Doctoral Dissertations

2008

Ceramic materials -- Mechanical properties<br />High temperatures<br />Silicon carbide<br />Sintering<br />Zirconium

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Full-Text Articles in Engineering

Densification, Microstructure, And Mechanical Properties Of Zirconium Diboride Based Ultra-High Temperature Ceramics, Sumin Zhu Jan 2008

Densification, Microstructure, And Mechanical Properties Of Zirconium Diboride Based Ultra-High Temperature Ceramics, Sumin Zhu

Doctoral Dissertations

"The first part of this dissertation was aimed at studying the densification of ZrB₂ ceramics by pressureless sintering techniques. Various processes have been applied to coat ZrB₂ powders with polymer precursors, which were used to produce C after charring. After sintering at 1900⁰C, relative density increased of ~70% for uncoated ZrB₂ to >99% for ZrB₂ coated with at least 1.0 wt% C. Thermodynamic analysis suggested that C reacted with and removed oxide impurities (ZrO₂ and B₂O₃) that were present on the ZrB₂ particle surfaces, which promoted densification by minimizing grain coarsening"--Abstract, page iv.