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Full-Text Articles in Engineering

X-Ray Determination Of Lattice Parameters And Thermal Expansion Coefficients Of Aluminum, Silver And Molybdenum At Cryogenic Temperatures, Claude Lowell Woodard Jan 1969

X-Ray Determination Of Lattice Parameters And Thermal Expansion Coefficients Of Aluminum, Silver And Molybdenum At Cryogenic Temperatures, Claude Lowell Woodard

Doctoral Dissertations

"A multiple exposure back reflection diffraction camera was designed to mount on the vacuum jacket of a pressurized helium gas "Cryomite". With this design it is possible to obtain six diffraction exposures on a single film at any temperature in the range of 180 to 25°K. temperatures within this range are reached in short intervals and exposure periods are less than 30 minutes in a 2.875 inch (73.03 mm) diameter camera. Some of the advantages of this design are; direct measurements, multiple exposures on a single film, short exposures, direct compensation of film length changes due to evacuation or processing …


Phase Equilibria And Thermodynamic Studies In The System Ca0-Fe0-Fe₂0₃₋Si0₂, Muharrem Timucin Jan 1969

Phase Equilibria And Thermodynamic Studies In The System Ca0-Fe0-Fe₂0₃₋Si0₂, Muharrem Timucin

Doctoral Dissertations

"A study of phase relations and thermodynamic properties of phases in the system CaO-FeO-Fe₂O₃-SiO₂ was conducted at 1450°C and 1550°C. The region of stability of the different phases was determined by microscopic examination of the specimens. The thermodynamic properties of liquid were determined by analyses of quenched samples equilibrated at oxygen pressures from about 10⁻¹¹ to 1 atm. Isothermal phase diagrams were constructed from data for 0, 5, 10, 20, and 30 weight percent silica sections of the CaO-FeO-Fe₂O₃-SiO₂ system, and the effect of temperature and increased silica additions on the oxygen solubility of the liquid oxides was measured. Multicomponent …


The Iron-Holmium Binary System And Related Magnetic Properties, Gerald J. Roe Jan 1969

The Iron-Holmium Binary System And Related Magnetic Properties, Gerald J. Roe

Doctoral Dissertations

"The iron-holmium phase diagram was investigated to determine the alloying behavior of these two metals and to determine the magnetic properties of some of the iron-holmium alloys which formed intermediate phases. The iron-holmium binary system was determined by three experimental techniques, differential thermal analysis (DTA), x-ray diffraction, and metallography. A phase diagram with three eutectic points and four intermediate phases was constructed from the experimental data. The two phases, Ho₆Fe₂₃ and Ho₂Fe₁₇, melted congruently at 1322⁰C and 1343⁰C respectively. HoFe₂ and HoFe₃ melted incongruently at 1288⁰C and 1293⁰C respectively. Neutron diffraction investigations were made on the intermediate phases Ho₆Fe₂₃ and …


Grain Boundary Self-Diffusion In Sodium Chloride, Kenneth Ray Riggs Jan 1969

Grain Boundary Self-Diffusion In Sodium Chloride, Kenneth Ray Riggs

Doctoral Dissertations

"The diffusion of ²²sodium and ³⁶chlorine along tilt and twist grain boundaries in pure and calcium chloride doped sodium chloride bicrystals was investigated. No enhanced diffusion of ²²sodium along the grain boundaries was observed. Between 400°C and 500°C the chlorine grain boundary diffusion parameter, D'Δ, is described by D'Δ = (D'Δ)₀exp (-Qb/kT), where (D'Δ)₀ is approximately 10⁻⁷ cm³/sec and Qb is 1.15 ± .30 eV. The grain boundary angle, the grain boundary character (tilt or twist), and the calcium chloride concentration appear to have no pronounced effect upon the observed chlorine grain boundary diffusion. The ionic movement …


Calorimetry Of Room Temperature Deformed Copper, George Juri Filatovs Jan 1969

Calorimetry Of Room Temperature Deformed Copper, George Juri Filatovs

Doctoral Dissertations

"An adiabatic anisothermal differential calorimeter for the study of room temperature deformed 99.999% pure copper has been constructed. An annealed and a deformed specimen were heated at a constant rate in adiabatic surroundings and the differences in energy released between samples was obtained. The control circuits were automatic. Deformation was by elongation ranging from 12 to 40%, and the corresponding energy found was from 1.9 to 5.3 calories/gram-atom. No recovery energy was found. The results obtained generally agree with published results and, in particular, verify Gordon's isothermal annealing results. It is proposed that the criteria for the presence of recovery …


Diffusion Of Iron And Cobalt In Nickel Single Crystals, Charles Frederick Heuer Jan 1969

Diffusion Of Iron And Cobalt In Nickel Single Crystals, Charles Frederick Heuer

Doctoral Dissertations

"Diffusion coefficients of iron-59 in nickel have been determined in the temperature range 815°C to 1200°C. The temperature dependence can be represented by an Arrhenius type relationship,...The effect of the isotopic mass on the diffusion coefficient of cobalt in nickel has also been investigated. The isotope effect parameter, E, was found to vary from .26 to .84 over the temperature range 970.5°C to 1200°C. Both results are consistent with the single vacancy mechanism of diffusion. No evidence of divacancy contributions to the mass transport has been found"--Abstract, Page i.


A Crystallization Study Of A Tetrasilicic Fluormica Glass, William H. Daniels Jan 1969

A Crystallization Study Of A Tetrasilicic Fluormica Glass, William H. Daniels

Doctoral Dissertations

"The transformation of a synthetic mica composition K₂Mg₅Si₈O₂₀F₄ from amorphous to crystalline structure was studied isothermally at selected temperatures from 560°C to 1150°C. thermal changes associated with the transformation were followed by differential thermal analysis techniques. Structural changes promoted by the isothermal treatments were observed by density measurements, Debye-Scherrer X-ray diffraction techniques, electron replication microscopy, and electron scanning microscopy. Isothermal treatment at 450°C for 9 hours produces structural ordering in quenched K₂Mg₅Si₈O₂₀F₄ glass. Fluorine exerts a significant influence on the transformation temperature; decreasing amounts of fluorine producing increasing transformation temperatures. The crystallizing phase rapidly attains a limiting particle size and …