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Full-Text Articles in Engineering

Corrosion Assessment Of Carbon Steel In Thailand By Atmospheric Corrosion Monitoring (Acm) Sensors, W Pongsaksawad, E Viyanit, S Sorachot, T Shinohara Dec 2010

Corrosion Assessment Of Carbon Steel In Thailand By Atmospheric Corrosion Monitoring (Acm) Sensors, W Pongsaksawad, E Viyanit, S Sorachot, T Shinohara

Journal of Metals, Materials and Minerals

Atmospheric corrosion of metal depends on material compositions, weather condition (dry, dew, and rain period), temperature, relative humidity, and airborne sea salt of specific location. General testing procedure to obtain the corrosion rate is by actual exposure test of the specimen panels based on time interval plan. In Japan, atmospheric corrosion monitoring (ACM) sensor, made of an iron-silver galvanic couple, has been developed and used to sense the corrosivity in terms of galvanic current. Under some atmospheric conditions, these data can be converted to time of wetness and related to the corrosion rate of carbon steel. With ACM sensors, it …


Versatile Route For Preparation Of Polydiacetylene/Zno Nanocomposites And Their Colorimetric Response To Ph And Ethanol, N Rungruangviriya, N Traiphol Dec 2010

Versatile Route For Preparation Of Polydiacetylene/Zno Nanocomposites And Their Colorimetric Response To Ph And Ethanol, N Rungruangviriya, N Traiphol

Journal of Metals, Materials and Minerals

This contribution presents a simple method to prepare polydiacetylene(PDA)/ZnO nanocomposites, which can be utilized as active materials in sensing technology. The ZnO nanoparticles, which constitute of Zn-OH2 + , Zn-OH and Zn-O- groups at their surfaces, function as nano-substrates for self-assembling of diacetylene monomers, 10,12-pentacosadiynoic acid (PCDA), in aqueous medium. Photopolymerization of the assemblies yields poly(PCDA)/ZnO nanocomposites with core-shell structure. Strong interactions between the active groups at ZnO surface and carboxylic head groups of poly(PCDA) promote chain ordering and reduce segmental dynamics of poly(PCDA) in the nanocomposites. The existence of strong interfacial interaction drastically affects the colorimetric response behavior of …


Development Of Layered Zn-Fe Coatings For Better Corrosion Protection, R S. Bhat, R Udupak, A C. Hegde Dec 2010

Development Of Layered Zn-Fe Coatings For Better Corrosion Protection, R S. Bhat, R Udupak, A C. Hegde

Journal of Metals, Materials and Minerals

In this research, the Zn-Fe coating having successive layers of alloys of two different compositions were developed alternatively on mild steel for better corrosion protection. The multilayer coatings, or alternatively, composition modulated alloy (CMA) coatings of different configurations have been developed, and their corrosion behaviors were evaluated by electrochemical DC and AC methods. The cyclic cathode current densities and numbers of layers have been optimised for peak corrosion stability of the coatings. Under optimal condition, the CMA coating having 300 layers, having about 67 nm average thickness was found to be approximately six times higher corrosion resistant than monolayer coating …


Hardness And Fracture Toughness Of Alumina-Based Particulate Composites With Zirconia And Strontia Additives, T Oungkulsolmongkol, P Salee-Art, W Buggakupta Dec 2010

Hardness And Fracture Toughness Of Alumina-Based Particulate Composites With Zirconia And Strontia Additives, T Oungkulsolmongkol, P Salee-Art, W Buggakupta

Journal of Metals, Materials and Minerals

This project aims to study characteristics and mechanical properties i.e. hardness and fracture toughness of alumina matrix composite materials containing zirconia and strontium oxide. Two groups of composite specimen were fabricated: (i) Al2O3 matrix with 3 mol% Y2O3- ZrO2, varied from 10, 20, 30 and 40 vol%, and (ii) Al2O3 matrix with 2, 5, 10 and 15 vol% SrO added in the form of SrCO3. The powders were blended and then pressed into pellets. The compacts were pressureless sintered at 1600 o C for 2 hours in air. Density measurement of the sintered composites was carried out using liquid immersion. …


Surface Modification Of Polyester Fabrics With Vinyltriethoxysilane, B Kusuktham Dec 2010

Surface Modification Of Polyester Fabrics With Vinyltriethoxysilane, B Kusuktham

Journal of Metals, Materials and Minerals

Surface modification of polyester fabrics was studied aiming at improving the water repellency property. Vinyltriethoxysilane (VTES) was employed as surface modifying agent. Prior to application, VTES was prepared in aqueous emulsion using cetyltrimethylammoniun bromide (CTAB) as an emulsifying agent. The application of VTES emulsion was carried out using a padder and followed by curing at 150° C for 15 minutes. The result showed that the treated fabrics exhibited higher contact angle values when compared to untreated fabric, indicating an increase in water repellency property. It was believed that VTES was converted into silicone through siloxane network. The presence of a …


Preparation And Characteristics Of Galangal Essential Oil/Alginate Microcapsules, T Jiamrungraksa, S Charuchinda Dec 2010

Preparation And Characteristics Of Galangal Essential Oil/Alginate Microcapsules, T Jiamrungraksa, S Charuchinda

Journal of Metals, Materials and Minerals

Galangal essential oil/alginate microcapsules were prepared by solidifying in liquid (orifice method) between sodium alginate and calcium chloride. The structure, morphology and also the thermal stability of the microcapsules were investigated by FT-IR, optical microscope, infrared moisture determination balance (IMDB) at 120°C for 2 hours. The galangal essential oil release content of microcapsules was estimated by measuring time course of weight of microcapsules determination by isothermal TGA at 37°C and 120°C. FT-IR spectral data confirmed the presence of galangal essential oil in the prepared microcapsules. An increase of sodium alginate concentration and oil content resulted in significantly higher average size …


Oxidation Of Cyclohexane And Ethylbenzene By Hydrogen Peroxide Over Co-Substituted Heteropolytungstate Catalyst, W Kanjina, W Trakarnpruk Dec 2010

Oxidation Of Cyclohexane And Ethylbenzene By Hydrogen Peroxide Over Co-Substituted Heteropolytungstate Catalyst, W Kanjina, W Trakarnpruk

Journal of Metals, Materials and Minerals

The tetrabutylammonium salt of Co-substituted heteropolytungstate, [(n-C4H9)4N]4 HPW11Co(H2O)O39.3H2O was synthesized and characterized. It was shown to be an active catalyst for the oxidation of cyclohexane and ethylbenzene. The oxidation reactions were performed using green oxidant hydrogen peroxide and acetonitrile as solvent. The major products of the oxidation of cyclohexane were cyclohexanone (K) and cyclohexanol (A). High selectivity towards K-A oil was achieved. At longer time cyclohexanol was converted to cyclohexanone. Ethylbenzene was also selectively oxidized to acetophenone. These oxidation reactions appear to be radical processes since they were totally inhibited in the presence of radical scavenger.


Effect Of Sintering On Microstructure And Properties Of Hydroxyapatite Produced By Different Synthesizing Methods, N Monmaturapoj, C Yatongchai Dec 2010

Effect Of Sintering On Microstructure And Properties Of Hydroxyapatite Produced By Different Synthesizing Methods, N Monmaturapoj, C Yatongchai

Journal of Metals, Materials and Minerals

The aim of this study is to investigate the effect of the sintering schedule on microstructure and properties of hydroxyapatite which is produced by different synthesizing methods. Hence, wet-chemical precipitation and solid-state reaction were performed to prepare nano-sized hydroxyapatite (HA) powders. Powders were then uniaxially pressed and sintered by varying temperatures and times. XRD and SEM were used to identify phases and morphology. Density and porosity of the sintered sample were determined using the Archimedes technique. Flexural strength was measured by a universal testing machine. The results show that density and strength could be improved by increasing the sintering temperature …


Study On Flame Retardancy And Anti-Dripping Of Polyester Fabric Treated With Bentonite, Diammonium Hydrogen Phosphate And Aluminium Hydroxide, P Lerdkajornsuk, S Charuchinda Dec 2010

Study On Flame Retardancy And Anti-Dripping Of Polyester Fabric Treated With Bentonite, Diammonium Hydrogen Phosphate And Aluminium Hydroxide, P Lerdkajornsuk, S Charuchinda

Journal of Metals, Materials and Minerals

The purpose of this research was to improve flame retardancy and anti-dripping of polyester fabric by using bentonite, 3% (w/w) diammonium hydrogen phosphate (DA) and 5, 10% (w/w) aluminium hydroxide (Al(OH)3) via pad-dry technique. The burning behavior of the treated polyester fabric was investigated according to ASTM D1230. The results showed that 10wt% of bentonite alone were capable of imparting anti-dripping. Nevertheless, the preparation of the slurry of bentonite (>10% (w/w)) caused high viscosity leading to difficulties for the preparation and finishing process. Thus, the addition of 4% (w/w) of sodium chloride (NaCl) to the suspension of bentonite (up …


Preparation And Properties Of Superhydrophobic Cotton Fabrics, P Kampeerapappun, K Visatchok, D Wangarsa Dec 2010

Preparation And Properties Of Superhydrophobic Cotton Fabrics, P Kampeerapappun, K Visatchok, D Wangarsa

Journal of Metals, Materials and Minerals

In this study, superhydrophobic cotton fabric was prepared by coating maleic-anhydride grafted poly[styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS-g-MA) triblock copolymer solutions containing calcium carbonate (CaCO3) particles. SEBS-g-MA solutions were prepared using single solvent (toluene and tetrahydrofuran (THF)) and mixed solvent (toluene: ethanol (EtOH) and THF: EtOH). Cotton fabrics were treated with the prepared solution using padding technique. All coated fabrics exhibited a water contact angle (WCA) of more than 100°. Optimum WCA values were observed when THF and 90:10 toluene: EtOH were employed. In case of CaCO3 particles addition, 6% W/V CaCO3 could impart the highest WCA value of 154°. However, the durability of …


Effect Of Temperature And Pressure On The Densification Of Titanium Silicide Compound, P Thapnuy, S Larpkiattaworn, T Luangvaranunt, J Ikeuchi Dec 2010

Effect Of Temperature And Pressure On The Densification Of Titanium Silicide Compound, P Thapnuy, S Larpkiattaworn, T Luangvaranunt, J Ikeuchi

Journal of Metals, Materials and Minerals

Titanium silicide compound was synthesized from the mixture of titanium and silicon powder with atomic ratios of 60:40 and 70:30. The powders were mixed by ball milling and pressed by different methods: by using uniaxial pressing at 64 MPa, cold isostatic pressing (CIP) at 200 MPa, hot forging (HF) at 648 MPa, and hot pressing (HP) at 24 MPa. The samples were then sintered at 1300o C or 1600o C for 2 hours soaking time in argon atmosphere. The sintered samples were subsequently characterized for phase constitution using X-ray diffraction (XRD). Ti5Si3 was observed as main compound of mixtures with …


Pickling Behavior Of Aisi 304 Stainless Steel In Sulfuric And Hydrochloric Acid Solutions, W Homjabok, S Permpoon, G Lothongkum Dec 2010

Pickling Behavior Of Aisi 304 Stainless Steel In Sulfuric And Hydrochloric Acid Solutions, W Homjabok, S Permpoon, G Lothongkum

Journal of Metals, Materials and Minerals

Oxide scales as well as a Cr-depleted layer, which grows between the oxide scale and base metal, are formed on AISI 304 stainless steel surface during high temperature processing. Pickling is an important process which includes mechanical and chemical operations to remove oxide scales, Cr-depleted layers, and to recover the surface passivity. The multi-step pickling is commonly used because of its higher efficiency than a single step pickling. In this study, the multi-step pickling of AISI 304 stainless steel in HCl solution was investigated instead of H2SO4 solution for the first step of pickling. HF+HNO3 mixed acid is traditionally used …


Effects Of Aluminium On Sintered Properties Of Cu-10wt%Sn Bearing, V Chobaomsup, T Luangvaranunt Dec 2010

Effects Of Aluminium On Sintered Properties Of Cu-10wt%Sn Bearing, V Chobaomsup, T Luangvaranunt

Journal of Metals, Materials and Minerals

Self-lubricating bearings are one of the oldest industrial applications of porous powder metallurgy parts, dating back to the mid-1920s. They remain the highest part produced by the P/M industry. The objective of this research was to study the effects of sintering time, sintering temperature and ratio of adding aluminium on sintered properties of Cu-10wt%Sn bearing that was produced from powder metallurgy processing. Various physical and mechanical properties such as density, percentage of porosity and hardness were tested to elucidate the effect of processing parameters. Phase identification and microstructure were analyzed by X-Ray Diffractometer and optical microscope, respectively. Sintering times in …


Development Of An Aluminum Semi-Solid Extrusion Process, T Rattanochaikul, S Janudom, N Memongkol, J Wannasin Dec 2010

Development Of An Aluminum Semi-Solid Extrusion Process, T Rattanochaikul, S Janudom, N Memongkol, J Wannasin

Journal of Metals, Materials and Minerals

Semi-solid extrusion process is a new forming process that is quite promising because the process requires lower forming pressure than conventional solid extrusion. In addition, semi-solid extrusion does not require large machines, which results in lower production costs. The aim of this article is to study the feasibility of an aluminum semi-solid extrusion process. The semi-solid technique selected for usage in this study was the Gas Induced Semi-Solid (GISS) process. The laboratory extrusion system was developed in this work. In the experiments, nitrogen gas was injected into aluminum melt for about 5 seconds. After that, the obtained semi-solid slurry was …


An Investigation Of Microstructural Change Of Low Alloy Steel Aisi 4150 By Seebeck Coefficient, T Samran, P Termsuksawad Jul 2010

An Investigation Of Microstructural Change Of Low Alloy Steel Aisi 4150 By Seebeck Coefficient, T Samran, P Termsuksawad

Journal of Metals, Materials and Minerals

Low alloyed steels, whose hardness can be modified by heat treatment, have been widely used in various applications. After heat treatment, they are normally destructively characterized and tested by many approaches via optical microscope and hardness testing. It is useful to develop a non-destructive method relating to its properties and microstructures. The proposed non-destructive approach in this study is the Seebeck coefficient measurement. The materials in this study were carbon steels AISI 4150 rod with a diameter of 1.3 cm and length of 3 cm. The specimens were heat-treated at 900ºC for 1 hour and were then cooled to room …


Preparation Of Hydrophobic Chitosan Using Complexation Method For Pla/Chitosan Blend, P Chouwatat, P Polsana, P Noknoi, K Siralertmukul, K Srikulkit Jul 2010

Preparation Of Hydrophobic Chitosan Using Complexation Method For Pla/Chitosan Blend, P Chouwatat, P Polsana, P Noknoi, K Siralertmukul, K Srikulkit

Journal of Metals, Materials and Minerals

In this study, dioctyl sulfosuccinate-chitosan complex was prepared by a mechanical mixing of aqueous chitosan with sodium dioctyl sulfosuccinate. As a result, hydrophobic chitosan was achieved. Characterizations of the complex were carried out including XRD, TGA, and FT-IR in order to follow changes in the chitosan structure. Thus produced chitosan complex was hydrophobic and anticipated to be compatible with PLA. Solution blending of PLA and hydrophobic chitosan was then conducted. Characterization techniques including XRD and FT-IR were employed to investigate the structure of the polymer blend. FTIR spectra showed that changes in the fingerprint of the chitosan amide band in …


Thermal Analysis Of Fe-Carbide And Fe-C Mixtures, R Tongsri, B Vetayanugul Jul 2010

Thermal Analysis Of Fe-Carbide And Fe-C Mixtures, R Tongsri, B Vetayanugul

Journal of Metals, Materials and Minerals

Differential thermal analysis (DTA) was employed to monitor changes which occurred during heating of Fe-carbide and Fe-C mixtures. The DTA curves showed a relationship between endothermic peaks and phase transformations given in the Fe-C phase diagram. The transformations included (i) magnetic Fe to non-magnetic Fe, (ii) pure α-Fe to pure γ-Fe, (iii) γ + Fe3C → Liquid and (iv) pure γ-Fe to pure δ-Fe. Melting of the Fe-SiC powder compacts when sintered at temperatures higher than 1200°C was revealed and indicated by the endothermic peak of 1230°C. This peak corresponded to the transformation of γ + Fe3C → Liquid. That …


Effects Of Replacing Binder With Powder Space Holder On Properties Of Metal Injection Moulded Foam, U Koikul, A Manonukul, S Suranuntchai Jul 2010

Effects Of Replacing Binder With Powder Space Holder On Properties Of Metal Injection Moulded Foam, U Koikul, A Manonukul, S Suranuntchai

Journal of Metals, Materials and Minerals

Metal foam can be produced using metal injection moulding with powder space holder. In this study, the effects of volume fraction of spacer holder on the foam properties were studied. Spherical poly (methyl methacrylate) (PMMA) particles were used as a space holder material. The 30% volume fraction of stainless steel 316L powder was mixed with varied volume fractions of binder and PMMA. There were five volume fractions of PMMA, namely 30% to 50%, with an increment of 5%. The results showed that the volume fraction of PMMA affected the properties. As the volume fraction of PMMA increased, the number of …


Study Of Covering Conditions For Sintering Of Metal Injection Moulded Commercially Pure Titanium, N Muenya, A Manonukul Jul 2010

Study Of Covering Conditions For Sintering Of Metal Injection Moulded Commercially Pure Titanium, N Muenya, A Manonukul

Journal of Metals, Materials and Minerals

In metal injection moulding process, sintering for some specific materials is different from general materials. Titanium is a material that is not easy to sinter because it is a very reactive metal at high temperature. The high quality of the titanium component is difficult to control, especially so in point of the levels of carbon and oxygen, which have large effects on the mechanical properties. Commercially pure titanium was injected, debinded and sintered at 1150°C and 1250°C in high vacuum without a cover, and with a quartz cover, a mullite cover and an alumina cover, respectively. From the physical and …


Study Of Process Parameters In Conventional Powder Metallurgy Of Silver, S Amaranan, A Manonukul Jul 2010

Study Of Process Parameters In Conventional Powder Metallurgy Of Silver, S Amaranan, A Manonukul

Journal of Metals, Materials and Minerals

Compaction, sintering and physical properties of silver powder were investigated. The silver powder was uniaxially compacted into a cylindrical specimen using compaction pressures of 13.79, 27.58, 41.37 and 55.16 MPa. Compacted parts were sintered at 700, 800 and 900°C in argon atmospheres. In addition, compacted parts were also sintered in vacuum at 900°C. For the sintering temperatures of 700 and 800°C, it was found that the sintered density increased as the compaction pressure increased below 40 MPa, while the sintered density decreased at a compaction pressure above 40 MPa. At the sintering temperature of 900°C, the sintered density decreased with …


Effect Of K2o/Sio2 Ratio On The Crystallization Of Leucite In Silicate-Based Glasses, P Sooksaen, J Boonmee, C Witpathomwong, S Likhitlert Jul 2010

Effect Of K2o/Sio2 Ratio On The Crystallization Of Leucite In Silicate-Based Glasses, P Sooksaen, J Boonmee, C Witpathomwong, S Likhitlert

Journal of Metals, Materials and Minerals

Leucite-based glass-ceramics were prepared by controlled crystallization of suitable glass compositions to give required crystalline phase/s. Three glass batches in the system SiO2 - K2O - NaO2 - Al2O3 - TiO2 - CaO were prepared by varying K2O/SiO2 ratio, then melted and quenched. Glasses were characterized for onset of crystallization temperatures by differential thermal analysis (DTA), and heat treatments were carried out from 850 - 1000°C for 4 hours for controlled crystallization of leucite phase. Physical, chemical and crystal structure characterizations were carried out using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). XRD found …


Adhesion Behavior In Sliding Test Of Austenitic Stainless Steel On Vc Coated By Trd Process, R Piewnim, P Sricharoenchai Jul 2010

Adhesion Behavior In Sliding Test Of Austenitic Stainless Steel On Vc Coated By Trd Process, R Piewnim, P Sricharoenchai

Journal of Metals, Materials and Minerals

Austenitic stainless steel is prone to adhere to tool steels which are used as forming tools. This causes difficulties in the formation of stainless steels.(1) Hard coating on forming tools is a method to diminish adhesion problems. In this work, adhesive behavior of stainless steel was tested against VC coated by thermo-reactive deposition and diffusion (TRD) process. Sliding wear test was conducted under unlubricated condition at room temperature by a ring-on-disc tester. AISI 304 was used as a ring for sliding couple with VC coating layer. DC 53 steel was used as a disc on which VC with a thickness …


Utilization Of Fly Ash From Power Plant For Adsorption Of Hydrocarbon Contamination In Water, J Sasithorn, D Wiwattanadate, S Sangsuk Jul 2010

Utilization Of Fly Ash From Power Plant For Adsorption Of Hydrocarbon Contamination In Water, J Sasithorn, D Wiwattanadate, S Sangsuk

Journal of Metals, Materials and Minerals

Adsorption efficiency of polycyclic aromatic hydrocarbons (PAHs) contamination in water with rice husk fly ash from a power plant was investigated in comparison with coal fly ash and silica from rice husk fly ash, with and without surface treatment. Naphthalene was used as a representative for PAHs, and Cethyltrimethylammoniumbromide (CTAB) was used as surface treating agent for the present study. Various factors, such as shaking rate, shaking time, pH of naphthalene aqueous solution, and adsorbentnaphthalene weight ratio, were investigated to identify the optimum condition for each adsorbent. Upon using 0.3 g adsorbent in 100 ml of 10 mg/l naphthalene solution, …


Effect Of Chitosan's Molecular Weights On Mangosteen Dye Fixation On Cotton Fabric, C Suitcharit, F Awae, W Sengmama, K Srikulkit Jul 2010

Effect Of Chitosan's Molecular Weights On Mangosteen Dye Fixation On Cotton Fabric, C Suitcharit, F Awae, W Sengmama, K Srikulkit

Journal of Metals, Materials and Minerals

The effect of chitosan's molecular weights (Mw) on mangosteen dye fixation on cotton was studied using chitosans with Mw of 226 kDa (CTS-Mw I; native chitosan), 10.8 kDa (CTS-Mw II), and 7.2 kDa (CTS-Mw III). The preparation of chitosan with different Mws was carried out using sodium nitrite in acid media (depolymerization process). The obtained chitosans were applied onto cotton fabric. The effect of chitosan concentrations on fixation and fastness properties of mangosteen dye extract was studied. The results showed that an increase in concentrations of depolymerized chitosans (CTS-Mw II and III) yielded an increase in N% contents. Nonetheless, the …


Pickling Kinetics Of Tertiary Oxide Scale Formed On Hot-Rolled Steel Strip, Y Jatuphaksamphan, N Phinichka, K Prapakorn, M Supradist Jul 2010

Pickling Kinetics Of Tertiary Oxide Scale Formed On Hot-Rolled Steel Strip, Y Jatuphaksamphan, N Phinichka, K Prapakorn, M Supradist

Journal of Metals, Materials and Minerals

During hot rolling process a steel strip covers with oxide scales. These scales have to be removed by acid pickling process. This work focuses on the study of the scale removing rate of a hot-rolled steel strip in order to find an expression explaining the rate of reaction in hydrochloric acid. The study of scale removal is accomplished by utilizing the pickling simulator with different acid concentrations and pickling temperatures. There are two approaches that can be used to find a scale removing rate; the measurement of weight change and the iron concentration change after the pickling process. In this …