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Full-Text Articles in Engineering
Formulation And Aerosol Jet Printing Of Nickel Nanoparticle Ink For High-Temperature Microelectronic Applications And Patterned Graphene Growth, Nicholas Mckibben, Michael Curtis, Olivia Maryon, Mone’T Sawyer, Maryna Lazouskaya, Josh Eixenberger, Zhangxian Deng, David Estrada
Formulation And Aerosol Jet Printing Of Nickel Nanoparticle Ink For High-Temperature Microelectronic Applications And Patterned Graphene Growth, Nicholas Mckibben, Michael Curtis, Olivia Maryon, Mone’T Sawyer, Maryna Lazouskaya, Josh Eixenberger, Zhangxian Deng, David Estrada
Materials Science and Engineering Faculty Publications and Presentations
Aerosol jet printing (AJP) is an advanced manufacturing technique for directly writing nanoparticle inks onto target substrates. It is an emerging reliable, efficient, and environmentally friendly fabrication route for thin film electronics and advanced semiconductor packaging. This fabrication technique is highly regarded for its rapid prototyping, the flexibility of design, and fine feature resolution. Nickel is an attractive high-temperature packaging material due to its electrical conductivity, magnetism, and corrosion resistance. In this work, we synthesized nickel nanoparticles and formulated an AJP ink, which was printed on various material surfaces. Thermal sintering experiments were performed on the samples to explore the …
Oblique Packing And Tunable Excitonic Coupling In Dna-Templated Squaraine Rotaxane Dimer Aggregates, Matthew S. Barclay, Christopher K. Wilson, Simon K. Roy, Olga A. Mass, Azhad U. Chowdhury, Jonathan S. Huff, Daniel B. Turner, Paul H. Davis, Bernard Yurke, William B. Knowlton, Jeunghoon Lee, Ryan D. Pensack
Oblique Packing And Tunable Excitonic Coupling In Dna-Templated Squaraine Rotaxane Dimer Aggregates, Matthew S. Barclay, Christopher K. Wilson, Simon K. Roy, Olga A. Mass, Azhad U. Chowdhury, Jonathan S. Huff, Daniel B. Turner, Paul H. Davis, Bernard Yurke, William B. Knowlton, Jeunghoon Lee, Ryan D. Pensack
Materials Science and Engineering Faculty Publications and Presentations
When molecules are aggregated such that their excited states form delocalized excitons, their spatial arrangement, or packing, can be coarsely controlled by templating and finely controlled by chemical substitution; however, challenges remain in controlling their packing on intermediate length scales. Here, we use an approach based on mechanically interlocked molecules to promote an elusive oblique packing arrangement in a series of three squaraine rotaxane dimers. We template the squaraine rotaxane dimers using DNA and observe two excitonically split bands of near-equal intensity in their absorption spectra – a distinct signature of oblique packing, validated by theoretical modeling of the experimental …
Influence Of Hydrophobicity On Excitonic Coupling In Dna-Templated Indolenine Squaraine Dye Aggregates, Olga A. Mass, Christopher K. Wilson, German Barcenas, Lan Li, Bernard Yurke, William B. Knowlton, Ryan D. Pensack, Jeunghoon Lee
Influence Of Hydrophobicity On Excitonic Coupling In Dna-Templated Indolenine Squaraine Dye Aggregates, Olga A. Mass, Christopher K. Wilson, German Barcenas, Lan Li, Bernard Yurke, William B. Knowlton, Ryan D. Pensack, Jeunghoon Lee
Materials Science and Engineering Faculty Publications and Presentations
Control over the strength of excitonic coupling in molecular dye aggregates is a substantial factor for the development of technologies such as light harvesting, optoelectronics, and quantum computing. According to the molecular exciton model, the strength of excitonic coupling is inversely proportional to the distance between dyes. Covalent DNA templating was proved to be a versatile tool to control dye spacing on a subnanometer scale. To further expand our ability to control photophysical properties of excitons, here, we investigated the influence of dye hydrophobicity on the strength of excitonic coupling in squaraine aggregates covalently templated by DNA Holliday Junction (DNA …
First-Principles Studies Of Substituent Effects On Squaraine Dyes, German Barcenas, Austin Biaggne, Olga A. Mass, Christopher K. Wilson, Ryan D. Pensack, Jeunghoon Lee, William B. Knowlton, Bernard Yurke, Lan Li
First-Principles Studies Of Substituent Effects On Squaraine Dyes, German Barcenas, Austin Biaggne, Olga A. Mass, Christopher K. Wilson, Ryan D. Pensack, Jeunghoon Lee, William B. Knowlton, Bernard Yurke, Lan Li
Materials Science and Engineering Faculty Publications and Presentations
Dye molecules that absorb light in the visible region are key components in many applications, including organic photovoltaics, biological fluorescent labeling, super-resolution microscopy, and energy transport. One family of dyes, known as squaraines, has received considerable attention recently due to their favorable electronic and photophysical properties. In addition, these dyes have a strong propensity for aggregation, which results in emergent materials properties, such as exciton delocalization. This will be of benefit in charge separation and energy transport along with fundamental studies in quantum information. Given the high structural tunability of squaraine dyes, it is possible that exciton delocalization could be …
Ball-On-Ring Test Validation For Equibiaxial Flexural Strength Testing Of Engineered Ceramics, Adrianna E. Lupercio, Ehsan Moshkelgosha, Riley C. Winters, Cayden Doyle, Mahmood Mamivand, Andrew T. Nelson, Brian J. Jaques
Ball-On-Ring Test Validation For Equibiaxial Flexural Strength Testing Of Engineered Ceramics, Adrianna E. Lupercio, Ehsan Moshkelgosha, Riley C. Winters, Cayden Doyle, Mahmood Mamivand, Andrew T. Nelson, Brian J. Jaques
Materials Science and Engineering Faculty Publications and Presentations
The validation of a ball-on-ring, equibiaxial flexural strength method to obtain the transverse rupture strength (TRS) of right cylindrical ceramic specimens was performed in this study. Validation of the test method was achieved using commercially available engineered high purity alumina disks and finite element (FE) model analysis. The validated fixture was then used to obtain the TRS and Weibull statistical analysis of MgO-partially stabilized zirconia (MSZ) and Y2O3-partially stabilized zirconia (YSZ) ceramic disks. TRS data for alumina, MSZ, and YSZ agreed with the TRS values reported in the literature. A statistically relevant number of samples (N …
Aerosol Jet Printed Capacitive Strain Gauge For Soft Structural Materials, Kiyo T. Fujimoto, Jennifer K. Watkins, Timothy Phero, Takoda Bingham, Kshama Lakshmi Ranganatha, Benjamin C. Johnson, Zhangxian Deng, Brian Jaques, David Estrada
Aerosol Jet Printed Capacitive Strain Gauge For Soft Structural Materials, Kiyo T. Fujimoto, Jennifer K. Watkins, Timothy Phero, Takoda Bingham, Kshama Lakshmi Ranganatha, Benjamin C. Johnson, Zhangxian Deng, Brian Jaques, David Estrada
Materials Science and Engineering Faculty Publications and Presentations
Soft structural textiles, or softgoods, are used within the space industry for inflatable habitats, parachutes and decelerator systems. Evaluating the safety and structural integrity of these systems occurs through structural health monitoring systems (SHM), which integrate non-invasive/non-destructive testing methods to detect, diagnose, and locate damage. Strain/load monitoring of these systems is limited while utilizing traditional strain gauges as these gauges are typically stiff, operate at low temperatures, and fail when subjected to high strain that is a result of high loading classifying them as unsuitable for SHM of soft structural textiles. For this work, a capacitance based strain gauge (CSG) …
High-Performance Flexible Bismuth Telluride Thin Film From Solution Processed Colloidal Nanoplates, Madhusudan Kongara, Tony Varghese, Karthik Chinnathambi, Jesse Schimpf, Josh Eixenberger, Paul H. Davis, Yaqiao Wu, David Estrada
High-Performance Flexible Bismuth Telluride Thin Film From Solution Processed Colloidal Nanoplates, Madhusudan Kongara, Tony Varghese, Karthik Chinnathambi, Jesse Schimpf, Josh Eixenberger, Paul H. Davis, Yaqiao Wu, David Estrada
Materials Science and Engineering Faculty Publications and Presentations
Thermoelectric generators are an environmentally friendly and reliable solid‐state energy conversion technology. Flexible and low‐cost thermoelectric generators are especially suited to power flexible electronics and sensors using body heat or other ambient heat sources. Bismuth telluride (Bi2Te3) based thermoelectric materials exhibit their best performance near room temperature making them an ideal candidate to power wearable electronics and sensors using body heat. In this report, Bi2Te3 thin films are deposited on a flexible polyimide substrate using low‐cost and scalable manufacturing methods. The synthesized Bi2Te3 nanocrystals have a thickness of 35 ± …
Thermal Transport In Layer-By-Layer Assembled Polycrystalline Graphene Films, David Estrada, Alondra Perez
Thermal Transport In Layer-By-Layer Assembled Polycrystalline Graphene Films, David Estrada, Alondra Perez
Materials Science and Engineering Faculty Publications and Presentations
New technologies are emerging which allow us to manipulate and assemble 2-dimensional (2D) building blocks, such as graphene, into synthetic van der Waals (vdW) solids. Assembly of such vdW solids has enabled novel electronic devices and could lead to control over anisotropic thermal properties through tuning of inter-layer coupling and phonon scattering. Here we report the systematic control of heat flow in graphene-based vdW solids assembled in a layer-by-layer (LBL) fashion. In-plane thermal measurements (between 100 K and 400 K) reveal substrate and grain boundary scattering limit thermal transport in vdW solids composed of one to four transferred layers of …
Open-Source Automated Chemical Vapor Deposition System For The Production Of Two-Dimensional Nanomaterials, Lizandra Williams-Godwin, Dale Brown, Richard Livingston, Tyler Webb, Lynn Karriem, Elton Graugnard, David Estrada
Open-Source Automated Chemical Vapor Deposition System For The Production Of Two-Dimensional Nanomaterials, Lizandra Williams-Godwin, Dale Brown, Richard Livingston, Tyler Webb, Lynn Karriem, Elton Graugnard, David Estrada
Materials Science and Engineering Faculty Publications and Presentations
The study of two- dimensional (2D) materials is a rapidly growing area within nanomaterials research. However, the high equipment costs, which include the processing systems necessary for creating these materials, can be a barrier to entry for some researchers interested in studying these novel materials. Such process systems include those used for chemical vapor deposition, a preferred method for making these materials. To address this challenge, this article presents the first open-source design for an automated chemical vapor deposition system that can be built for less than a third of the cost for a comparable commercial system. The materials and …
High-Performance And Flexible Thermoelectric Films By Screen Printing Solution-Processed Nanoplate Crystals, Tony Varghese, Courtney Hollar, Joseph Richardson, Nicholas Kempf, Chao Han, Pasindu Gamarachchi, David Estrada, Yanliang Zhang
High-Performance And Flexible Thermoelectric Films By Screen Printing Solution-Processed Nanoplate Crystals, Tony Varghese, Courtney Hollar, Joseph Richardson, Nicholas Kempf, Chao Han, Pasindu Gamarachchi, David Estrada, Yanliang Zhang
Materials Science and Engineering Faculty Publications and Presentations
Screen printing allows for direct conversion of thermoelectric nanocrystals into flexible energy harvesters and coolers. However, obtaining flexible thermoelectric materials with high figure of merit ZT through printing is an exacting challenge due to the difficulties to synthesize high-performance thermoelectric inks and the poor density and electrical conductivity of the printed films. Here, we demonstrate high-performance flexible films and devices by screen printing bismuth telluride based nanocrystal inks synthesized using a microwave-stimulated wet-chemical method. Thermoelectric films of several tens of microns thickness were screen printed onto a flexible polyimide substrate followed by cold compaction and sintering. The n-type films demonstrate …
Enhancing Precalculus Curricula With E-Learning: Implementation And Assessment, Janet Callahan, Seung Youn Chyung, Joanna Guild, William Clement, Joe Guarino, Doug Bullock, Cheryl Schrader
Enhancing Precalculus Curricula With E-Learning: Implementation And Assessment, Janet Callahan, Seung Youn Chyung, Joanna Guild, William Clement, Joe Guarino, Doug Bullock, Cheryl Schrader
Materials Science and Engineering Faculty Publications and Presentations
During Fall semester of 2007, a semester-long, quasi-experimental study was conducted at Boise State University to investigate the effectiveness of a systematically sequenced and managed, self-paced e-learning activity on improving students’ academic performance and motivation. A total of 125 students enrolled in 3 different sections of a Precalculus class participated in the study. The e-learning activity was implemented in 2 of the 3 sections as a required homework assignment. Students enrolled in one of the 2 selected sections were all engineering majors. The 3rd section was a control group that did not use the e-learning activity. A pre-test, measuring …