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Full-Text Articles in Engineering

Tribocorrosion And Metal Release From Austenitic Stainless Steels 304 And 201 In Simulated Cassava Food Contact, Robert Addai, Temitope E. Olowoyo, Thalia E. Standish, Jeffrey Daniel Henderson, Ubong Eduok, Yolanda Hedberg Jul 2024

Tribocorrosion And Metal Release From Austenitic Stainless Steels 304 And 201 In Simulated Cassava Food Contact, Robert Addai, Temitope E. Olowoyo, Thalia E. Standish, Jeffrey Daniel Henderson, Ubong Eduok, Yolanda Hedberg

Chemistry Publications

Cassava is the third most significant calorie source in the tropics. Its processing has changed from traditional methods to stainless steel processing machines. This study investigated the influence of cassava on metal release from two common stainless steels, ASTM 304 and 201, with and without friction, and on tribocorrosion (multianalytically) of 304. Cassava was relatively corrosive and hindered repassivation of the surface oxide of stainless steel, but it also acted as a lubricant against mechanical friction. The combined action of friction and cassava caused a significant increase in iron, chromium, nickel, and manganese release from the stainless steels (30–35- fold …


Atom Probe Tomography Of Segregation At Grain Boundaries And Gas Bubbles In Neutron Irradiated U-10 Wt% Mo Fuel, Maalavan Arivu, Andrew Hoffman, Mukesh Bachhav, Assel Aitkaliyeva, Yaqiao Wu, Brandon Miller, Dennis Keiser, Jian Gan, Haiming Wen Jun 2024

Atom Probe Tomography Of Segregation At Grain Boundaries And Gas Bubbles In Neutron Irradiated U-10 Wt% Mo Fuel, Maalavan Arivu, Andrew Hoffman, Mukesh Bachhav, Assel Aitkaliyeva, Yaqiao Wu, Brandon Miller, Dennis Keiser, Jian Gan, Haiming Wen

Materials Science and Engineering Faculty Research & Creative Works

During Neutron Irradiation to Fission Densities > 5.2 X 1021 Fiss/cm3, Xe Agglomerates Forming Gas Bubbles of Varying Size within the U-Mo Fuel Matrix. Herein, Segregation of Fission Products to Xe Bubbles and Grain Boundaries (GB) Were Studied using Atom Probe Tomography (APT). Segregation Behavior Was Found to Vary among GBs, Small Bubbles (<10 >Nm), and Larger Bubbles (>10 Nm). Solid Fission Products Were Enriched at GBs and Larger Bubbles, But Not at Small Bubbles. a Denuded Zone Was Identified Adjacent to a > 10 Nm Xe Gas Bubble and a GB.


Comparison Of Pm-Hip To Forged Sa508 Pressure Vessel Steel Under High-Dose Neutron Irradiation, Wen Jiang, Yangyang Zhao, Yu Lu, Yaqiao Wu, David Frazer, Donna P. Guillen, David W. Gandy, Janelle P. Wharry Jun 2024

Comparison Of Pm-Hip To Forged Sa508 Pressure Vessel Steel Under High-Dose Neutron Irradiation, Wen Jiang, Yangyang Zhao, Yu Lu, Yaqiao Wu, David Frazer, Donna P. Guillen, David W. Gandy, Janelle P. Wharry

Materials Science and Engineering Faculty Publications and Presentations

Powder metallurgy with hot isostatic pressing (PM-HIP) is an advanced manufacturing process that is envisioned to replace forging for heavy nuclear components, including the reactor pressure vessel (RPV). But PM-HIP products must at least demonstrate comparable irradiation tolerance than forgings in order to be qualified for nuclear applications. The objective of this study is to directly compare PM-HIP to forged SA508 Grade 3 Class 1 low-alloy RPV steel at two neutron irradiation conditions: ∼0.5–1.0 displacements per atom (dpa) at ∼270 °C and ∼370 °C. PM-HIP SA508 experiences greater irradiation hardening and embrittlement (total elongation) than forged SA508. However, uniform elongation …


Rheological Properties And 3d Printing Behavior Of Pcl And Dmso2 Composites For Bio-Scaffold, Jae-Won Jang, Kyung-Eun Min, Cheolhee Kim, Chien Wern, Sung Yi May 2024

Rheological Properties And 3d Printing Behavior Of Pcl And Dmso2 Composites For Bio-Scaffold, Jae-Won Jang, Kyung-Eun Min, Cheolhee Kim, Chien Wern, Sung Yi

Mechanical and Materials Engineering Faculty Publications and Presentations

The significance of rheology in the context of bio three-dimensional (3D) printing lies in its impact on the printing behavior, which shapes material flow and the layer-by-layer stacking process. The objective of this study is to evaluate the rheological and printing behaviors of polycaprolactone (PCL) and dimethyl sulfone (DMSO2) composites. The rheological properties were examined using a rotational rheometer, employing a frequency sweep test. Simultaneously, the printing behavior was investigated using a material extrusion 3D printer, encompassing varying printing temperatures and pressures. Across the temperature range of 120–140 °C, both PCL and PCL/DMSO2 composites demonstrated liquid-like behavior, …


Artificial Neural Network-Based Modelling For Yield Strength Prediction Of Austenitic Stainless-Steel Welds, Sukil Park, Cheolhee Kim, Namhyun Kang May 2024

Artificial Neural Network-Based Modelling For Yield Strength Prediction Of Austenitic Stainless-Steel Welds, Sukil Park, Cheolhee Kim, Namhyun Kang

Mechanical and Materials Engineering Faculty Publications and Presentations

This study aimed to develop an artificial neural network (ANN) model for predicting the yield strength of a weld metal composed of austenitic stainless steel and compare its performance with that of conventional multiple regression and machine learning models. The input parameters included the chemical composition of the nine effective elements (C, Si, Mn, P, S, Ni, Cr, Mo, and Cu) and the heat input per unit length. The ANN model (comprising five nodes in one hidden layer), which was constructed and trained using 60 data points, yielded an R2 value of 0.94 and a mean average percent error …


A Computational Investigation Of Wood Selection For Acoustic Guitar, Jonah Osterhus May 2024

A Computational Investigation Of Wood Selection For Acoustic Guitar, Jonah Osterhus

Senior Honors Theses

The acoustic guitar is a stringed instrument, often made of wood, that transduces vibrational energy of steel strings into coupled vibrations of the wood and acoustic pressure waves in the air. Variations in wood selection and instrument geometry have been shown to affect the timbre of the acoustic guitar. Computational methods were utilized to investigate the impact of material properties on acoustic performance. Sitka spruce was deemed the most suitable wood for guitar soundboards due to its acoustic characteristics, strength, and uniform aesthetic. Mahogany was deemed to be the best wood for the back and sides of the guitar body …


Quality Assurance And Quality Control For Reinforced Concrete Inspections, Calvin O. Walters Jr. May 2024

Quality Assurance And Quality Control For Reinforced Concrete Inspections, Calvin O. Walters Jr.

Publications and Research

Ensuring the safety and longevity of structures is paramount in concrete construction projects. Cases like the Big Dig ceiling collapse, which occurred on July 10, 2006, when a concrete ceiling panel measuring 20' x 40' and debris weighing 26 short tons (52,000 lb) fell within Boston's Fort Point Channel Tunnel, underscore this importance (Wald, M. L., 2007). Quality Assurance (QA) and Quality Control (QC) are crucial in mitigating such risks. QA ensures that materials and methods meet predetermined performance, design, and reliability standards specified in contracts and customer arrangements. On the other hand, QC is a strategic process businesses use …


Sliding Markov Decision Processes For Dynamic Task Planning On Uncrewed Aerial Vehicles, Trent Wiens May 2024

Sliding Markov Decision Processes For Dynamic Task Planning On Uncrewed Aerial Vehicles, Trent Wiens

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Mission and flight planning problems for uncrewed aircraft systems (UASs) are typically large and complex in space and computational requirements. With enough time and computing resources, some of these problems may be solvable offline and then executed during flight. In dynamic or uncertain environments, however, the mission may require online adaptation and replanning. In this work, we will discuss methods of creating MDPs for online applications, and a method of using a sliding resolution and receding horizon approach to build and solve Markov Decision Processes (MDPs) in practical planing applications for UASs. In this strategy, called a Sliding Markov Decision …


Development Of A Multi-Use Modular Microfluidic Platform Using 3d Printing, Carson Emeigh May 2024

Development Of A Multi-Use Modular Microfluidic Platform Using 3d Printing, Carson Emeigh

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

Microfluidic lab-on-a-chip (LoC) technology has driven numerous innovations due to their ability to perform laboratory-scale experiments on a single chip using microchannels. Although LoC technology has been innovative, it still suffers from limitations related to its fabrication and design flexibility. Typical LoC fabrication, with photolithography, is time consuming, expensive, and inflexible. To overcome the limitations of LoC devices, modular microfluidic platforms have been developed where multiple microfluidic modules, each with a specific function or group of functions, can be combined on a single platform. Modular microfluidics have overcome some of the limitations of LoC devices, but currently, their fabrication is …


Dynamic Impact Testing And Numerical Analysis Of Non-Proprietary Astm F2656-20 M50 Anti-Ram Barrier Components, Weston Kelley May 2024

Dynamic Impact Testing And Numerical Analysis Of Non-Proprietary Astm F2656-20 M50 Anti-Ram Barrier Components, Weston Kelley

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

In a post-9/11 world, hostile actors are using vehicles as weapons to inflict civilian casualties. Pedestrians, vulnerable road users, military personnel, and police may be targeted using a vehicle as a weapon. The United States Department of Defense (DoD) also utilizes Entry Control Facilities (ECFs) which are carefully designed transportation corridors to manage how threat vehicles are able to access military facilities. In 2004, DoD started to upgrade all ECFs using both passive and active barriers. Many anti-ram vehicle barriers were evaluated according to the criteria established in ASTM F2656, but to date few options are available which are (1) …


Quasi-Static And Dynamic Deformation Of Aluminum Matrix Composites Reinforced By Core-Shell Al35ti15cu10mn20cr20 High-Entropy Alloy Particulates, Dezhi Zhu, Tingting Chen, Xiaoqiang Jin, Haiming Wen, Zhiqiang Fu, Shengguan Qu May 2024

Quasi-Static And Dynamic Deformation Of Aluminum Matrix Composites Reinforced By Core-Shell Al35ti15cu10mn20cr20 High-Entropy Alloy Particulates, Dezhi Zhu, Tingting Chen, Xiaoqiang Jin, Haiming Wen, Zhiqiang Fu, Shengguan Qu

Materials Science and Engineering Faculty Research & Creative Works

Core-Shell Structured Particles Are Potential Reinforcement Agents For Metal Matrix Composites. In This Work, Aluminum Matrix Composites Reinforced With Core-Shell Structured Al35Ti15Cu10Mn20Cr20 High-Entropy Alloy (HEA) Particles Were Fabricated By Spark Plasma Sintering (SPS) And High-Temperature Diffusion Post-Treatment. Dynamic Compression Behavior And Adiabatic Shear Failure Mechanism In The Composites Were Investigated By Split Hopkinson Pressure Bar (SHPB), Scanning Electron Microscopy And Transmission Electron Microscopy. Results Showed That The Shell Thickness Of The Core-Shell Particles Ranged From 0.4 To 1.6 Μm, Which Were Formed By Thermal Diffusion Between HEA Core And Aluminum Alloy. The 30 Vol% (Al35Ti15Cu10Mn20Cr20)p/2024Al Composite Showed A High Compressive …


Design And Optimization Of A Novel Monolithic Spring For High-Frequency Press-Pack Sic Fet Modules, Bogac Canbaz May 2024

Design And Optimization Of A Novel Monolithic Spring For High-Frequency Press-Pack Sic Fet Modules, Bogac Canbaz

Department of Electrical and Computer Engineering: Dissertations, Theses, and Student Research

Silicon Carbide (SiC) Field-Effect Transistor (FET) modules lead the way in power electronics, being superior in efficiency and robustness for high-frequency applications. The shift towards SiC from traditional silicon (Si)-based devices is driven by its superior thermal conductivity, higher electric field strength, and operational efficiency at elevated temperatures. These features are critical for the development of next-generation, grid-oriented power converters aimed at enhancing the reliability and sustainability of power systems. This research focuses on high-frequency press-pack (HFPP) SiC FET modules, addressing the primary challenge of miniaturizing SiC FET dies without compromising performance, through an innovative press-contact design essential for increased …


High Temperature Validation Of A Line Heat Source Technique For In-Pile Thermal Conductivity Determination, Katelyn Wada, Allyssa Bateman, Tony Valayil Varghese, Austin Fleming, Brian J. Jaques, David Estrada May 2024

High Temperature Validation Of A Line Heat Source Technique For In-Pile Thermal Conductivity Determination, Katelyn Wada, Allyssa Bateman, Tony Valayil Varghese, Austin Fleming, Brian J. Jaques, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

In-pile instrumentation is critical for advancing operations and materials discovery in the nuclear industry. Ensuring optimal performance of sensors in high temperatures is the first step in demonstrating their viability in the harsh in-pile environment. This work demonstrates the high temperature capabilities of a line heat source and measurement technique previously shown to extract thermal conductivity of nuclear fuel sized samples within a laboratory environment at room temperature. This method uses a hybrid AC/DC measurement technique to obtain rapid measurements of the temperature dependent voltage change of a heater wire, which also acts as a resistance thermometer. Once the temperature …


Deep Selenium Donors In Zngep2 Crystals: An Electron Paramagnetic Resonance Study Of A Nonlinear Optical Material, Timothy D. Gustafson, Larry E. Halliburton, Nancy C. Giles, Peter G. Schunemann, Kevin T. Zawilski, J. Jesenovec, Kent L. Averett, Jeremy Slagle Apr 2024

Deep Selenium Donors In Zngep2 Crystals: An Electron Paramagnetic Resonance Study Of A Nonlinear Optical Material, Timothy D. Gustafson, Larry E. Halliburton, Nancy C. Giles, Peter G. Schunemann, Kevin T. Zawilski, J. Jesenovec, Kent L. Averett, Jeremy Slagle

Faculty Publications

Zinc germanium diphosphide (ZnGeP2) is a ternary semiconductor best known for its nonlinear optical properties. A primary application is optical parametric oscillators operating in the mid-infrared region. Controlled donor doping provides a method to minimize the acceptor-related absorption bands that limit the output power of these devices. In the present study, a ZnGeP2 crystal is doped with selenium during growth. Selenium substitutes for phosphorus and serves as a deep donor. Significant concentrations of native defects (zinc vacancies, germanium-on-zinc antisites, and phosphorous vacancies) are also present in the crystal. Electron paramagnetic resonance (EPR) is used to establish the …


Application Of The Immobilized Low-Activity Waste Glass Corrosion Model To The Static Dissolution Of 24 Statistically-Designed Alkali-Borosilicate Waste Glasses, Sebastien N. Kerisit, James J. Neeway, Charmayne E. Lonergan, Benjamin Parruzot, Jarrod V. Crum, Richard C. Daniel, Gary L. Smith, R. Matthew Asmussen Apr 2024

Application Of The Immobilized Low-Activity Waste Glass Corrosion Model To The Static Dissolution Of 24 Statistically-Designed Alkali-Borosilicate Waste Glasses, Sebastien N. Kerisit, James J. Neeway, Charmayne E. Lonergan, Benjamin Parruzot, Jarrod V. Crum, Richard C. Daniel, Gary L. Smith, R. Matthew Asmussen

Materials Science and Engineering Faculty Research & Creative Works

Glass corrosion models that capture the complex mechanisms of the glass-water reaction enable the prediction of nuclear waste glass durability in disposal scenarios. Parameterization of such models is challenging because of the need to capture changes in corrosion behavior with time, reaction conditions, and glass composition. Here, we describe and employ the ILAW (immobilized low-activity waste) glass corrosion model (IGCM) in geochemical simulations of static dissolution tests, at two temperatures (40 °C and 90 °C), for a matrix of 24 enhanced low-activity waste (eLAW) glasses statistically designed to cover a processable composition space defined by 8 major glass components (Al …


Decoding Crystallization Behavior Of Aluminoborosilicate Glasses: From Structural Descriptors To Quantitative Structure – Property Relationship (Qspr) Based Predictive Models, Yingcheng Zhang, Marco Bertani, Alfonso Pedone, Randall E. Youngman, Gregory Tricot, Aditya Kumar, Ashutosh Goel Apr 2024

Decoding Crystallization Behavior Of Aluminoborosilicate Glasses: From Structural Descriptors To Quantitative Structure – Property Relationship (Qspr) Based Predictive Models, Yingcheng Zhang, Marco Bertani, Alfonso Pedone, Randall E. Youngman, Gregory Tricot, Aditya Kumar, Ashutosh Goel

Materials Science and Engineering Faculty Research & Creative Works

Successful decoding of structural descriptors controlling the crystallization in multicomponent functional glasses can pave the way for the transition from the trial-and-error approach and empirical modeling for glass/glass-ceramic composition design toward more rational and scientifically rigorous Quantitative Structure-Property Relationship (QSPR) based models. However, due to the compositional and structural complexity of multicomponent glasses and the longer time and length scales associated with nucleation, the development and validation of QSPR models are still in it's infancy. The work presented in the article is an attempt to leap forward in this pursuit by combining the strengths of experimental and computational materials science …


Synergy Between Ca2+ And High Ionic Field-Strength Cations During The Corrosion Of Alkali Aluminoborosilicate Glasses In Hyper-Alkaline Media, Qianhui Qin, Nicholas Stone-Weiss, Nian Shi, Pinaki Mukherjee, Jinjun Ren, Ashutosh Goel Apr 2024

Synergy Between Ca2+ And High Ionic Field-Strength Cations During The Corrosion Of Alkali Aluminoborosilicate Glasses In Hyper-Alkaline Media, Qianhui Qin, Nicholas Stone-Weiss, Nian Shi, Pinaki Mukherjee, Jinjun Ren, Ashutosh Goel

Michigan Tech Publications, Part 2

One major factor impeding the design of nuclear waste glasses with enhanced waste loadings is our insufficient understanding of their composition–structure–durability relationships, specifically in the environments the waste form is expected to encounter in a geological repository. In particular, the high field-strength cations (HFSCs) are an integral component of most waste streams. However, their impact on the long-term performance of the glassy waste form remains mostly undeciphered. In this context, the present study aims to understand the impact of some HFSCs (i.e., Nb5+, Zr4+, Ti4+, and La3+) on the dissolution behavior of alkali/alkaline-earth aluminoborosilicate-based model nuclear waste glasses in hyper-alkaline …


A Guide To Fifty Years Of Research At Montana Tech: Part 3-Decontamination Of Ratioactively Contaminated Steel By Melt Refining/Slagging Processing, Larry G. Twidwell, Samuel A. Worcester Apr 2024

A Guide To Fifty Years Of Research At Montana Tech: Part 3-Decontamination Of Ratioactively Contaminated Steel By Melt Refining/Slagging Processing, Larry G. Twidwell, Samuel A. Worcester

Metallurgy

This presentation includes a discussion of the research conducted at Montana Tech in the Department of Metallurgical and Materials Engineering. The discussion is focused on Decontamination of Radioactively Contaminated Steel by Melt Refining/Slagging. This presentation is based on the research of Master of Science graduate students, industrial and academic colleagues, at the Montana College of Mineral Science and Technology (which morphed to Montana Tech [1977], then to Montana Tech of The University of Montana [2000], then to Montana Technological University [2019]). The referenced work of each of the graduate students in this presentation is gratefully acknowledged. The following summary presentation …


Safety Evaluation Of Hawaii Dot Modified Type A-1 Flared Buried In Backslope Guardrail End Terminal, Sina Changizian Apr 2024

Safety Evaluation Of Hawaii Dot Modified Type A-1 Flared Buried In Backslope Guardrail End Terminal, Sina Changizian

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

The Hawaii Department of Transportation (HDOT) desired to evaluate the crashworthiness of a guardrail end terminal design in which the upstream guardrail anchorage was connected to a block partially buried in a cut slope, known as a “Buried in Backslope” or BIB design. The HDOT BIB system used an upper W-beam with 8-in. deep blockouts attached to W6x9 steel posts and a lower W-beam rubrail located 3 in. below the upper rail. The system used two horizontal flares: 7.4:1 near the upstream anchor block and a 13:1 flare through the ditch.

Critical impact points (CIPs) were identified and recommended for …


Effect Of Fabrication Parameters On The Ferroelectricity Of Hafnium Zirconium Oxide Films: A Statistical Study, Guillermo A. Salcedo, Ahmad E. Islam, Elizabeth Reichley, Michael Dietz, Christine M. Schubert Kabban, Kevin D. Leedy, Tyson C. Back, Weison Wang, Andrew Green, Timothy S. Wolfe, James M. Sattler Mar 2024

Effect Of Fabrication Parameters On The Ferroelectricity Of Hafnium Zirconium Oxide Films: A Statistical Study, Guillermo A. Salcedo, Ahmad E. Islam, Elizabeth Reichley, Michael Dietz, Christine M. Schubert Kabban, Kevin D. Leedy, Tyson C. Back, Weison Wang, Andrew Green, Timothy S. Wolfe, James M. Sattler

Faculty Publications

Ferroelectricity in hafnium zirconium oxide (Hf1−xZrxO2) and the factors that impact it have been a popular research topic since its discovery in 2011. Although the general trends are known, the interactions between fabrication parameters and their effect on the ferroelectricity of Hf1−xZrxO2 require further investigation. In this paper, we present a statistical study and a model that relates Zr concentration (x), film thickness (tf), and annealing temperature (Ta) with the remanent polarization (Pr) in tungsten (W)-capped Hf1−xZrxO2. …


On The Use Of Machine Learning And Data-Transformation Methods To Predict Hydration Kinetics And Strength Of Alkali-Activated Mine Tailings-Based Binders, Sahil Surehali, Taihao Han, Jie Huang, Aditya Kumar, Narayanan Neithalath Mar 2024

On The Use Of Machine Learning And Data-Transformation Methods To Predict Hydration Kinetics And Strength Of Alkali-Activated Mine Tailings-Based Binders, Sahil Surehali, Taihao Han, Jie Huang, Aditya Kumar, Narayanan Neithalath

Electrical and Computer Engineering Faculty Research & Creative Works

The escalating production of mine tailings (MT), a byproduct of the mining industry, constitutes significant environmental and health hazards, thereby requiring a cost-effective and sustainable solution for its disposal or reuse. This study proposes the use of MT as the primary ingredient (≥70%mass) in binders for construction applications, thereby ensuring their efficient upcycling as well as drastic reduction of environmental impacts associated with the use of ordinary Portland cement (OPC). The early-age hydration kinetics and compressive strength of MT-based binders are evaluated with an emphasis on elucidating the influence of alkali activation parameters and the amount of slag or cement …


Effect Of The Filler Morphology On The Crystallization Behavior And Dielectric Properties Of The Polyvinylidene Fluoride-Based Composite, Suzana Filipović, Nina Obradović, Cole Corlett, William G. Fahrenholtz, Martin Rosenschon, Ekkehard Füglein, Radovan Dojčilović, Dragana Tošić, Jovana Petrović, Antonije Đorđević, Branislav Vlahović, Vladimir B. Pavlović Mar 2024

Effect Of The Filler Morphology On The Crystallization Behavior And Dielectric Properties Of The Polyvinylidene Fluoride-Based Composite, Suzana Filipović, Nina Obradović, Cole Corlett, William G. Fahrenholtz, Martin Rosenschon, Ekkehard Füglein, Radovan Dojčilović, Dragana Tošić, Jovana Petrović, Antonije Đorđević, Branislav Vlahović, Vladimir B. Pavlović

Materials Science and Engineering Faculty Research & Creative Works

Ceramic/polymer composites can be chemically stable, mechanically strong, and flexible, which make them candidates for electric devices, such as pressure or temperature sensors, energy storage or harvesting devices, actuators, and so forth. Depending on the application, various electrical properties are of importance. Polymers usually have low dielectric permittivity, but increased dielectric permittivity can be achieved by the addition of the ceramic fillers with high dielectric constant. With the aim to enhance dielectric properties of the composite without loss of flexibility, 5 wt.% of BaTiO3-Fe2O3 powder was added into a polyvinylidene fluoride matrix. The powder was …


A Phenomenological Thermodynamic Energy Density Function For Ferroelectric Wurtzite Al1−Xscxn Single Crystals, Yijia Gu, Andrew C. Meng, Aiden Ross, Long Qing Chen Mar 2024

A Phenomenological Thermodynamic Energy Density Function For Ferroelectric Wurtzite Al1−Xscxn Single Crystals, Yijia Gu, Andrew C. Meng, Aiden Ross, Long Qing Chen

Materials Science and Engineering Faculty Research & Creative Works

A Landau-Devonshire thermodynamic energy density function for ferroelectric wurtzite aluminum scandium nitride (Al1−xScxN) solid solution is developed. It is parametrized using available experimental and theoretical data, enabling the accurate reproduction of composition-dependent ferroelectric properties, such as spontaneous polarization, dielectric permittivity, and piezoelectric constants, for both bulk and thin films. The maximum concentration of Sc for the wurtzite structure to remain ferroelectric is found to be 61 at. %. A detailed analysis of Al1−xScxN thin films reveals that the ferroelectric phase transition and properties are insensitive to substrate strain. This study lays the foundation for quantitative modeling of novel ferroelectric wurtzite …


Toward Smart And Sustainable Cement Manufacturing Process: Analysis And Optimization Of Cement Clinker Quality Using Thermodynamic And Data-Informed Approaches, Jardel P. Gonçalves, Taihao Han, Gaurav Sant, Narayanan Neithalath, Jie Huang, Aditya Kumar Mar 2024

Toward Smart And Sustainable Cement Manufacturing Process: Analysis And Optimization Of Cement Clinker Quality Using Thermodynamic And Data-Informed Approaches, Jardel P. Gonçalves, Taihao Han, Gaurav Sant, Narayanan Neithalath, Jie Huang, Aditya Kumar

Electrical and Computer Engineering Faculty Research & Creative Works

Cement manufacturing is widely recognized for its harmful impacts on the natural environment. In recent years, efforts have been made to improve the sustainability of cement manufacturing through the use of renewable energy, the capture of CO2 emissions, and partial replacement of cement with supplementary cementitious materials. To further enhance sustainability, optimizing the cement manufacturing process is essential. This can be achieved through the prediction and optimization of clinker phases in relation to chemical compositions of raw materials and manufacturing conditions. Cement clinkers are produced by heating raw materials in kilns, where both raw material compositions and processing conditions …


Corrigendum To "Comparing Structure-Property Evolution For Pm-Hip And Forged Alloy 625 Irradiated With Neutrons To 1dpa" [Mater. Sci. Eng. A (2022) 144058], Caleb Clement, Sowmya Panuganti, Patrick H. Warren, Yangyang Zhao, Yu Lu, Katelyn Wheeler, David Frazer, Donna P. Guillen, David W. Gandy, Janelle P. Wharry Mar 2024

Corrigendum To "Comparing Structure-Property Evolution For Pm-Hip And Forged Alloy 625 Irradiated With Neutrons To 1dpa" [Mater. Sci. Eng. A (2022) 144058], Caleb Clement, Sowmya Panuganti, Patrick H. Warren, Yangyang Zhao, Yu Lu, Katelyn Wheeler, David Frazer, Donna P. Guillen, David W. Gandy, Janelle P. Wharry

Materials Science and Engineering Faculty Publications and Presentations

The authors regret that after publication, they discovered that the dislocation loop number density was undercounted by a factor of 100 for both the PM-HIP and forged specimens. While this does not change the original major conclusions, this necessitates a change in the results presentation (Sections 3.2 and 4.1) and calculated hardening (Table 3, Fig. 5). Corrections to these affected sections are provided in this corrigendum.


A Priori Procedure To Establish Spinodal Decomposition In Alloys, Simon Divilov, Hagen Eckert, Cormac Toher, Rico Friedrich, Adam C. Zettel, Donald W. Brenner, William G. Fahrenholtz, Douglas E. Wolfe, Eva Zurek, Jon Paul Maria, Nico Hotz, Xiomara Campilongo, Stefano Curtarolo Mar 2024

A Priori Procedure To Establish Spinodal Decomposition In Alloys, Simon Divilov, Hagen Eckert, Cormac Toher, Rico Friedrich, Adam C. Zettel, Donald W. Brenner, William G. Fahrenholtz, Douglas E. Wolfe, Eva Zurek, Jon Paul Maria, Nico Hotz, Xiomara Campilongo, Stefano Curtarolo

Materials Science and Engineering Faculty Research & Creative Works

Spinodal decomposition can improve a number of essential properties in materials, especially hardness. Yet, the theoretical prediction of the onset of this phenomenon (e.g., temperature) and its microstructure (e.g., wavelength) often requires input parameters coming from costly and time-consuming experimental efforts, hindering rational materials optimization. Here, we present a procedure where such parameters are not derived from experiments. First, we calculate the spinodal temperature by modeling nucleation in the solid solution while approaching the spinode boundary. Then, we compute the spinodal wavelength self-consistently using a few reasonable approximations. Our results show remarkable agreement with experiments and, for NiRh, the calculated …


The Thermophysical Properties Of Tco2, Hong Zhong, Jason Lonergan, John S. Mccloy, Scott P. Beckman Mar 2024

The Thermophysical Properties Of Tco2, Hong Zhong, Jason Lonergan, John S. Mccloy, Scott P. Beckman

Materials Science and Engineering Faculty Research & Creative Works

Technetium-99 Is A Highly Radioactive Isotope With A Long Half-Life That Is Common In Nuclear Waste. It Volatizes At A Low Temperature, Which Poses A Significant Challenge To The Clean-Up And Containment Processes. Due To Difficulties In Purifying Technetium Compounds, Their Thermophysical Properties Have Not Been Measured Or Calculated. Here, First Principle Methods Are Used Along With The Quasi Quasi-Harmonic Harmonic Approximation To Compute The Debye Temperature, Volumetric Thermal Expansion Coefficient, Bulk Modulus, And Heat Capacity Of Rutile TcO2 For Temperatures Ranging From 0 To 1500 K And Applied Pressures Ranging From 0 To 255 GPa. The Computed Atomic Structures …


A Bayesian Approach For Lifetime Modeling And Prediction With Multi-Type Group-Shared Missing Covariates, Hao Zeng, Xuxue Sun, Kuo Wang, Yuxin Wen, Wujun Si, Mingyang Li Feb 2024

A Bayesian Approach For Lifetime Modeling And Prediction With Multi-Type Group-Shared Missing Covariates, Hao Zeng, Xuxue Sun, Kuo Wang, Yuxin Wen, Wujun Si, Mingyang Li

Engineering Faculty Articles and Research

In the field of reliability engineering, covariate information shared among product units within a specific group (e.g., a manufacturing batch, an operating region), such as operating conditions and design settings, exerts substantial influence on product lifetime prediction. The covariates shared within each group may be missing due to sensing limitations and data privacy issues. The missing covariates shared within the same group commonly encompass a variety of attribute types, such as discrete types, continuous types, or mixed types. Existing studies have mainly considered single-type missing covariates at the individual level, and they have failed to thoroughly investigate the influence of …


The Behavior Of ½⟨111⟩ Screw Dislocations In W–Mo Alloys Analyzed Through Atomistic Simulations, Lucas A. Heaton, Kevin Chu, Adib J. Samin Feb 2024

The Behavior Of ½⟨111⟩ Screw Dislocations In W–Mo Alloys Analyzed Through Atomistic Simulations, Lucas A. Heaton, Kevin Chu, Adib J. Samin

Faculty Publications

Analyzing plastic flow in refractory alloys is relevant to many different commercial and technological applications. In this study, screw dislocation statics and dynamics were studied for various compositions of the body-centered cubic binary alloy tungsten–molybdenum (W–Mo). The core structure did not appear to change for different alloy compositions, consistent with the literature. The pure tungsten and pure molybdenum samples had the lowest plastic flow, while the highest dislocation velocities were observed for equiatomic, W0.5Mo0.5 alloys. In general, dislocation velocities were found to largely align with a well-established dislocation mobility phenomenological model supporting two discrete dislocation mobility regimes, …


Formulation And Aerosol Jet Printing Of Nickel Nanoparticle Ink For High-Temperature Microelectronic Applications And Patterned Graphene Growth, Nicholas Mckibben, Michael Curtis, Olivia Maryon, Mone’T Sawyer, Maryna Lazouskaya, Josh Eixenberger, Zhangxian Deng, David Estrada Feb 2024

Formulation And Aerosol Jet Printing Of Nickel Nanoparticle Ink For High-Temperature Microelectronic Applications And Patterned Graphene Growth, Nicholas Mckibben, Michael Curtis, Olivia Maryon, Mone’T Sawyer, Maryna Lazouskaya, Josh Eixenberger, Zhangxian Deng, David Estrada

Materials Science and Engineering Faculty Publications and Presentations

Aerosol jet printing (AJP) is an advanced manufacturing technique for directly writing nanoparticle inks onto target substrates. It is an emerging reliable, efficient, and environmentally friendly fabrication route for thin film electronics and advanced semiconductor packaging. This fabrication technique is highly regarded for its rapid prototyping, the flexibility of design, and fine feature resolution. Nickel is an attractive high-temperature packaging material due to its electrical conductivity, magnetism, and corrosion resistance. In this work, we synthesized nickel nanoparticles and formulated an AJP ink, which was printed on various material surfaces. Thermal sintering experiments were performed on the samples to explore the …