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Corrosion Inhibitors: Mitigating The Degradation Of Rebar, Jake R. Hughes
Corrosion Inhibitors: Mitigating The Degradation Of Rebar, Jake R. Hughes
Williams Honors College, Honors Research Projects
Our conjecture was twofold: first, that two compounds historically used as food preservatives could act as environmentally friendly inhibitors against rebar corrosion, and second, that molecular properties have a quantifiable influence on inhibition efficiency (%IE). To evaluate the two compounds, cyclic potentiodynamic polarization was used to determine corrosion current density (icorr) and %IE. The “green” inhibitor candidates included sodium metabisulfite and ascorbic acid, which yielded maximum %IE values of -123900% and 91%, respectively. Results indicated that sodium metabisulfite is not a suitable inhibitor, while ascorbic acid showed potential to extend reinforced concrete’s design life without posing health or …
Intergranular And Pitting Corrosion Mechanisms Of Sensitized Aluminum Alloy Aa5083, Clayton Egleston
Intergranular And Pitting Corrosion Mechanisms Of Sensitized Aluminum Alloy Aa5083, Clayton Egleston
Williams Honors College, Honors Research Projects
The motivation and objectives of this project is to examine the mechanisms of intergranular corrosion (IGC) and pitting corrosion of sensitized AA5083. In this regard, different characterization techniques were used, including optical analysis of microstructure, cyclic potentiodynamic polarization with Tafel fitting, electrochemical impedance spectroscopy with electrical equivalent circuit (EEC) fitting, and potentiostatic current transient monitoring. The transition from IGC to pitting corrosion occurs when the grain boundaries become saturated with the β-phase (Mg2Al3). It was found that AA5083 becomes more vulnerable to pitting corrosion as the degree of sensitization increases.